Optimization of metal-based multilayers for transparent heat mirrors

Multilayer calculations by conventional matrix methods for dielectricum/noble metal/dielectricum systems on glass have been performed. The aim has been to maximize the integrated parameters for solar transmission, T_sol, and transmission of visible light, T_eye We have found that Ag is superior for maximizing the transmittance over the narrow visible wavelength range owing to the low internal absorptance. When solar energy transmission is considered multilayers based on Au are the best choice for metal film thicknesses above 15 nm. For thinner films, Ag is still to be preferred.     

Open‐cycle OTEC systems with freshwater product: Effects of noncondensable gases on performance of condenser

An open‐cycle ocean thermal energy conversion (OC‐OTEC) system is one of the energy conversion methods used to generate electricity from ocean thermal energy. For the OC‐OTEC system, steam evaporated from the surface seawater due to flash evaporation drives the turbine. At that time, dissolved gas such as air is introduced into the low‐pressure system (OC‐OTEC system) as the noncondensable gas, which degrades the performance of condensation heat transfer. In this paper, a small‐scale OC‐OTEC experimental unit experimentally investigates the effect of noncondensable gas on the heat transfer performance in a condenser. The experimental results are discussed in comparison with theoretical estimation by the Sparrow–in method. It is shown that the condensation is occupied by heat and mass transfer near a condensation surface and that the condensation efficiency is affected by exhaust quantity of noncondensable gas at a relatively high concentration ratio of condensable gas. © 2005 Wiley Periodicals, Inc. Electr Eng Jpn, 154(1): 29–35, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20179     

From hospital to municipal cogeneration systems: an Italian case study

A mixed integer linear programming model combined with a more traditional design by scenarios is proposed to optimize facilities size and operation mode of a municipal energy system involving significant civil centres and a hospital. Moving from the need of a new heat and power station for the local hospital due to the construction of new pavilions, the opportunity of involving other centres in the neighbourhood in a distributed cogeneration system is analysed, increasing system complexity step by step. Smaller cogeneration units tailored to hospital needs are rewarding ventures with relatively low risks but, in a country whose traditional power generation systems heavily rely on fossil fuels and where energy policy and market conditions can make it profitable to sell surplus power, district heating systems foster the installation of larger cogenerators and lead thereby to higher profits and to better performance as for primary energy savings and greenhouse gases emission reduction. Copyright © 2006 John Wiley & Sons, Ltd.     

A load dispatch method using fractional programming and semidefinite programming

This paper describes a load dispatch method which minimizes power cost—[fuel cost]/[electric output]—for a power system with thermal plants and energy storage facilities. The proposed method employs fractional programming to convert a minimization problem with fractional objective function to a series of quadratic minimization problems, and semidefinite programming to solve converted problems. The method provides the optimum time‐dependent power output/input and storage level of energy storage facilities as well as time‐dependent power output of thermal plants. The method has been applied to a power system with five thermal plants, two energy storage facilities of various performances, and five load demands. The optimum load scheme of four time mesh points is obtained for the thermal plants and energy storage facilities. The fractional programming successfully converges the optimal scheme through a few iterations. The semidefinite programming deals with a variable matrix of 164 dimensions, and 185 inequality constraints. © 2001 Scripta Technica, Electr Eng Jpn, 138(2): 49–58, 2002     

Application of SiC-Si functionally gradient material to thermoelectric energy conversion device

Because of its high–temperature chemical stability, SiC ceramic is a promising material for high-temperature device applications such as thermoelectric energy converters. However, the electrical conductivity of SiC ceramic is too low for it to be used as a thermoelectric energy converter at the cold junction. Therefore, we propose a SiC-Si functionally gradient material (FGM) in order to improve the electrical conductivity of the SiC ceramic at the cold junction. An SiC rod was fired in a temperature gradient furnace. One end of the SiC rod was maintained at 2473 K and the other end was maintained at 1973 K for 30 min. After firing, the porous SiC edge fired at 1973 K was dipped into molten Si in order to infiltrate molten Si into the porous SiC. The microstructure of the FGM is classified into three regions: the SiC-Si composite material; the porous SiC ceramic; and the densified SiC ceramic. The electrical conductivity, the Seebeck coefficient and the thermal conductivity for each region of SiC-Si FGM was measured at 300 K; a figure of merit was calculated. The figure of merit of the SiC-Si FGM at the cold junction, at room temperature, was 10⁸ times higher than that of a nongradient SiC ceramic.     

On the specific reactivity of platinum segregated layers on Pt80X20 (111) (X= Ni,Co, Fe) alloys

The influence of alloying of Pt with 20 at.% of Ni, Co and Fe has been studied in the hydrogenation of 1,3 butadiene. Iron induces the more important modifications, with both higher activity and selectivity. The results are discussed in terms of the surface segregation, the local order in surface and the electronic properties measured by photoemission of core levels.     

An economic and environmental assessment of biomass utilization in lignite‐fired power plants of Greece

The environmental and socio‐economic impacts of biomass utilization by co‐firing with brown coal in an existing thermoelectric unit in Greece or through its pure combustion in a new plant were studied and evaluated in this work. The 125 MW_e lignite‐fired power plant in Ptolemais Power Station (Western Macedonia) was used as reference system. The environmental benefits of the alternative biomass exploitation options were quantified based on the life cycle assessment methodology, as established by SETAC, while the BIOSEM technique was used to carry out socio‐economic calculations. The obtained results showed clear environmental benefits of both biomass utilization alternatives in comparison with the reference system. In addition, co‐firing biomass with lignite in an existing unit outperforms the combustion of biomass exclusively in a new plant, since it exhibits a better environmental performance and it is a low risk investment with immediate benefits. A biomass combustion unit requires a considerably higher capital investment and its benefits are more evident in the long run. Copyright © 2005 John Wiley & Sons, Ltd.     

Assessment of the energy and exergy utilization efficiencies in the Turkish agricultural sector

This study deals with evaluating the energy and exergy utilization efficiencies in the Turkish agricultural sector over a 12‐year period from 1990 to 2001. In the energy and exergy analyses, two main energy sources, namely fuels and electricity, are taken into consideration, while the sectoral energy and exergy efficiencies are compared for this period. These main energy sources include diesel for tractors and other vehicles, and electricity for pumps. Overall energy utilization efficiencies are obtained to vary between 29.1 and 41.1%, while overall exergy utilization efficiencies are found to range from 27.9 to 37.4% in the analysed years, respectively. It may be concluded that the present technique proposed here may be used as a useful tool in analysing and evaluating the energy and exergy utilization efficiencies, identifying energy efficiency and/or energy conservation opportunities and dictating the energy strategies of countries. Copyright © 2005 John Wiley & Sons, Ltd.     

The analysis of solvation in ionic liquids and organic solvents using the Abraham linear free energy relationship

The contentions made in an earlier paper [J Chem Technol Biotechnol 80 : 133–137 (2005)] that the coefficients of the Abraham solvation equation do not provide meaningful information on the molecular properties of ionic liquid solvents is refuted. The objections noted in the earlier paper disappear when the solvation equation model is correctly applied to the experimental data. It is further shown that the coefficients of the Abraham solvation equations can be used to characterize ionic liquids and can be used to select solvents for the solubility of gaseous solutes. Copyright © 2006 Society of Chemical Industry