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21.
楼兴泽 《上海第二工业大学学报》1992,9(1):1-8
本文证明了一族闭曲线C(t),t∈I,称变闭曲线,在光滑性条件下,具有正交参数u,即当C(t)表为(?)=(?)(u,t)时,有(?)·(?)≡0.接着,文中提出了一种“降维法”,即用一族平行平面将空间曲面截成平面变曲线,并讨论其若干整体性质. 相似文献
22.
Fusae Nakanishi 《Polymer International》1992,27(3):237-241
Preparation of photoreactive Langmuir-Blodgett (LB) films was carried out using polymers/oligomers prepared from long-chain dialkyl esters of di-and tetra-olefins and having cyclobutane rings in the main chain. These polymers/oligomers formed stable monolayers on a water surface when mixed with arachidic acid. These monolayers could be deposited onto a substrate successfully forming Y-type films. The oligomer LB films were polymerized on irradiation. The polymer LB films showed a photo-reversible process between polymers and oligomers, depending on wavelength of the irradiating light. On the basis of spectral data and molecular weight change, this behaviour was found to be caused by cleavage and formation of cyclobutane rings. 相似文献
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In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl− Clad + e) is followed by a slower surface combination reaction (2Clad → Cl2), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved. 相似文献
25.
This study provides experimental evidence for proton and hydrogen formation caused by the anodic electropolymerization of cyclohexyl benzene (CHB), which is a popular electrolyte additive for overcharge protection of lithium-ion batteries (LIBs). It is found that considerable H2 evolution is observed in overcharged LiCoO2/graphite cells, especially when CHB is included as an electrolyte additive. In order to confirm the proton generation during the CHB oxidation, Pt/Pt-rotating ring disc electrode (RRDE) measurements are performed in 1 M Li(C2F5SO2)2N ethylene carbonate/ethyl methyl carbonate (1/2, v/v) solutions with and without CHB. The cathodic ring current is intimately correlated to the anodic disc current, and the cathodic reaction at the ring is determined to be the reduction of the proton. The proton generation efficiency during the CHB oxidation is as high as 90%. Proton liberation is also observed during the anodic decomposition of the electrolyte solvents, although it occurs in a much less stoichiometric way compared with that during the CHB oxidation. 相似文献
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介绍了如何使用PLC和数字变频调速技术 ,对传统环锭捻线机进行技术改造 ,使锭速、捻度和卷绕成形变换实现数字化柔性控制 ,扩大了工艺参数的变化范围 ,使整个捻线加工车间实现信息化管理成为可能。 相似文献
28.
讨论了固定床反应器阻力降快速升高的原因,介绍了用轴径向技术解决这一问题的原理及优点,及其在铁铬系变换催化剂和钴钼系耐硫变换催化剂反应器中的实际应用。 相似文献
29.
在行骨骼活检时,穿刺针的选择非常重要,甚至直接影响着活检的成功与否。笔者根据多次实践,应用环锯和Ackerman钻取外替代传统的活检方法取得了较好的效果。 相似文献
30.
提出了WDM环形网络的几种保护方案,分析了利用1:1环路配置方式进行WDM光环形网络保护的实现方法,简单介绍APS在环保护中的应用。 相似文献