Gelation mechanism of agarose and κ-carrageenan solutions estimated in terms of concentration fluctuation

The gelation mechanism of agarose and κ-carrageenan aqueous solutions was investigated by using polarized light scattering and X-ray diffraction techniques in terms of the liquid-liquid phase separation. When an incident beam of He-Ne gas laser was directed to the gel prepared by quenching the agarose solution, the logarithm of scattered intensity increased linearly in the initial stage and tended to deviate from this linear relationship in the latter stage. If the linear increase in the initial stage could be analyzed within the framework of the linear theory of spinodal decomposition proposed by Cahn, the phase diagram indicated that the gelation is attributed to the phase separation due to the concentration fluctuation of solution. Furthermore, in the later stage showing the deviation of the linear relationship, light scattering under Hv polarization condition showed a X-type pattern indicating the existence of optically anisotropic rods, the optical axes being parallel or perpendicular with respect to the rod axis. In spite of the existence of the rods, no crystallites were confirmed by the corresponding X-ray diffraction and DSC measurements. For κ-carrageenan solutions, the logarithm of scattered intensity against time showed a constant value. This indicated that the gelation of κ-carrageenan solutions is independent of liquid-liquid phase separation but is due to the rapid formation of cross-linking points. Accordingly it turns out that the small difference of chemical structure between agarose and κ-carrageenan causes quite different gelation mechanism.     

GH871 合金的蠕变断裂机制

对采用AIM+ESR和VIM+ESR工艺冶炼的GH871合金在650 ℃的蠕变性能及特征的研究表明,与用AIM+ESR工艺冶炼的GH871合金相比,用VIM+ESR工艺冶炼的GH871合金在蠕变断裂过程中裂纹萌生的形式(包括裂纹形状及形成时间)和裂纹扩展至裂纹连接所需的时间均表现出明显韧化的特征.     

Mechanism for the Peritectic Reaction and Growth of Aligned Grains in YBa2Cu3O6+x

It is experimentally observed that the peritectic reaction, 211 + liquid → 123, can be driven essentially to completion in 1 h at an undercooling of only ∽30°C. The kinetic data, together with the observed microstructures, are inconsistent with the normal mechanism of the peritectic reaction. It is proposed that the mechanism of the reaction involves dissolution of 211 particles into the liquid and precipitation of solid 123. The aligned grain structure is explained through sympathetic nucleation of new 123 grains on existing grains.     

n-Al2O3/Ni复合镀层的组织与滑动磨损性能研究

用电刷镀技术制得了镍基n-Al2O3复合镀层，并对镀层的滑动磨损性能进行了试验研究。纳米复合镀层的表面形貌比较细腻，镀层中纳米粒子分布均匀，与基质金属结合紧密。镀层显微硬度达到HV700，比快速镍镀层提高约40％。滑动磨损试验结果表明，随着纳米粒子含量的增大，镀层的耐磨性提高，摩擦系数也呈增大趋势；但当镀层中n-Al2O3粒子的超过2.56%(质量分数）时，镀层的耐磨性显著下降。纳米复合镀层的磨损机制以疲劳磨损为主，而快速镍底层以粘着磨损为主。     

石灰竖窑工作衬砖蚀损机理的探讨

阐述了石灰竖窑的预热带、煅烧带和冷却带工作衬砖蚀损机理，并讨论了如何根据耐火砖性能和石灰竖窑不同区域的蚀损机理，选择耐火材料。     

乙醇电氧化的研究进展

简要地叙述了国内外乙醇电催化氧化的研究进展，着重介绍不同电极材料对乙醇电氧化的影响及目前所提山的机理，并对其可能的研究方向提出了建议。     

修井机多桥间转向传动机构的设计

对于大型修井机采用的重型底盘,多桥转向系统是底盘开发中的关键技术之一。在分析目前修井机采用的转向传动结构(方案1)存在问题的基础上,参照军用车底盘的应用案例又提出了2种方案,经对比分析,确定了最佳的传动机构新方案,并根据多桥转向理论和四连杆机构的几何关系对该机构进行了参数确定。通过实际应用,证明该转向传动布置方案具有传动误差小、不产生附加转向、现场调节安装方便、易于组织生产等特点。     

坡沟系统侵蚀产沙及其耦合关系研究

利用变坡度坡沟系统模型和人工模拟降雨试验,定量研究了不同降雨强度下的坡沟系统产流产沙过程,揭示了坡面沟道侵蚀产沙耦合特征。结果表明:坡沟系统累积径流量和累积产沙量与降雨时间呈显著的幂函数关系,随着降雨时间的增大而增大。梁峁坡面来水径流量与沟坡净侵蚀量之间呈幂函数关系,梁峁坡面来水含沙量与沟坡净侵蚀量之间呈反线性相关。从水力学角度对坡沟系统单位水流功率与单宽输沙率的关系进行了分析,得出试验条件下的临界单位水流功率值为0.0043m/s,输沙率随单位水流功率的增大而增大。     

牙轮钻头的岩屑破碎机理及可钻性的分形法

为满足优质高速钻井的要求,需要对岩石可钻性做出快捷、精确的判断。利用分形几何理论,研究了钻井过程中牙轮钻头的破岩机理以及岩屑的等破碎概率问题;依据Bond裂纹学说,提出了一种以井底返出的岩屑为对象的岩石可钻性测试方法,并建立了岩石可钻性极值和岩屑分形维数的关系模型。室内实验表明:微钻头岩石可钻性级值与破碎岩屑分形维数存在明显的相关性,由此制定了一个基于岩屑粒度分布分形维数表示的岩石可钻性预测指标。经现场检验,分形法确定岩石可钻性级值具有较高的精度。这表明钻井过程中上返岩屑的分形维数能反映岩石可钻性程度,可以用分形维数衡量岩石可钻性大小。     

Silver electrodeposition from air and water-stable ionic liquid: An environmentally friendly alternative to cyanide baths

The influence of temperature on the kinetics and the morphology of silver deposits obtained from an air and water-stable ionic liquid (the 1-butyl-3-methyl imidazolium tetrafluoroborate) was studied by means of cyclic voltammetry and chronoamperometry. The nucleation and growth mechanisms have been investigated and the effect of temperature evaluated up to 200 °C. Dense, pure and very thin (about 0.3 μm) silver coatings, with decorative properties, have been obtained on commercial copper electrodes at different temperatures. The characterization of the deposits morphology has been performed by visual investigation and SEM microscopy. Data about thickness were acquired by Calotest® measurements. The deposits result constituted by pure silver as determined by combination of EDX microanalysis and Auger Electron Spectroscopy (AES). The deposition method promises to be a new, environmentally friendly, method for silver electrodeposition which is the reason for the absence of cyanide and volatile toxic solvents in the electroplating bath.