染料分散剂新原料-高沸醇木质素的研制

采用1，4-丁二醇水溶液为溶剂的高沸醇溶剂法，从松木，杉木，稻草等原料制备纤维素与高沸醇木质素。使用上述原料，在70%-90%1，4-丁二醇水溶液中添加少量催化剂。并在190℃-220℃条件下蒸煮1-3小时后，分离反应产物，得到固体纤维素与高沸醇木质素-丁二醇溶液，不溶于水的高沸醇木质素通过加水沉淀的方法。从反应后的液体混合物中分离。高沸醇木质素具有较高的反应活性。灰分含量很低。适于制备新型染料分散剂，有广泛应用前景。     

现有合成氨厂建设8万吨/年硫酸钾及4万吨/年纯碱装置的可行性

本文试图论述现有合成氨厂改变产品结构,采取以生产化肥为主,联产化工产品。通过对钾芒硝法工艺及联碱工艺技术路线的选择,技术经济分析,以期提高化肥厂的经济效益。     

精密注塑件的生产稳定性探讨

针对精密注塑件的生产,介绍了设计,成型精密注塑件的基本要求,探讨了原材料,注塑机,电压,环境温湿度及模具积垢等因素对生产精密注塑件稳定性的影响,研究了评估工艺参数敏感性的试验方法和获得稳定工艺的手段;说明了统计过程控制（SPC）的基本原理,以及如何利用控制图和工序能力指数CP,CPK来评估,预测工序能力,确保工序确定性。     

两种基于个体偏好集结的多属性群决策共识方法

针对多属性群决策中的共识问题, 提出两种使群体达成共识的方法. 假设群体决策的结果以从个体偏好通过集结得到的群体偏好为基础, 在使用算术加权集结算子和几何加权集结算子的条件下, 分别设计相应的共识达成算法, 并对算法的收敛性进行分析. 与已有方法相比, 所提出算法能够体现决策个体的差异和决策个体对群体的影响. 通过某市政图书馆空调系统安装方案的选择表明了所提出方法的合理性和可行性.

     

Electrochemical formation of AlN in molten LiCl-KCl-Li3N systems

Electrochemical formation of aluminum nitride was investigated in molten LiCl-KCl-Li₃N systems at 723 K. When Al was anodically polarized at 1.0 V (versus Li⁺/Li), oxidation of nitride ions proceeded to form adsorbed nitrogen atoms, which reacted with the surface to form AlN film. The obtained nitrided film had a thickness of sub-micron order. The obtained nitrided layer consisted of two regions; the outer layer involving AlN and aluminum oxynitride and the inner layer involving metallic Al and AlN. When Al electrode was anodically polarized at 2.0 V, anodic dissolution of Al electrode occurred to give aluminum ions, which reacted with nitride ions in the melt to produce AlN particles (1-5 μm of diameter) of wurtzite structure.     

一种改进型离散Hopfield学习算法

针对离散Hopfield 神经网络(DHNN) 的权值设计问题, 提出一种改进型学习算法, 并在DHNN动力学分析的基础上设计该学习算法. 利用矩阵分解的方法(MD) 得到正交矩阵, 并采用得到的正交矩阵直接计算DHNN的权值矩阵. 通过该学习算法得到的权值矩阵, 可以很好地存储训练样本的信息, 使测试样本收敛到稳定点. 该学习算法不需要进行分块计算, 减少了计算步骤和计算量, 降低了网络的迭代次数, 从而提高了网络运行速度. 最后, 将该学习算法应用于水质评价, 验证了其有效性和可行性.     

多周期多原料的供应链网络成本优化及其混合遗传算法

建立并求解一个基于成本最小的供应链网络模型.与以往研究不同,在该模型中生产一种产品需要至少两种原料,每种原料都可以由备选供应商提供.根据模型的特点,用0、1代表对原材料供应商、工厂和分销中心的选择情况,以MATLAB 7.6为平台,运用Sheffield大学的遗传算法工具箱,将遗传算法与线性规划算法相结合,实现了模型的求解.算例结果表明,给出的染色体编码方案正确,混合遗传算法有效,能解决多周期、多原料的供应链网络成本优化问题.还探讨了需求和距离变化,以及需求随机时对最优成本和最优个体的影响.研究表明,需求变化的影响大于距离变化的影响,需求随机对最优成本和最优个体的影响不大.     

合成氨双甲精制工艺副产双甲燃料应用实践

总结了合成氨双甲精制新工艺的实际应用情况，着重阐述其工艺流程，设备，工艺指标，安全，特点，效益。旨在从实践的角度察看其理论的成熟性与合理性，促进双甲工艺在八成氨生产中的广泛应用，创造更好的社会效益和与经济效益。     

Hydrodenitrogenation and Hydrodesulphurization of Heavy Gas Oil Using NiMo/Al2O3 Catalyst Containing Phosphorus: Experimental and Kinetic Studies

In this work, a systematic study has been conducted to optimize the process conditions and to evaluate kinetic parameters for hydrodenitrogenation (HDN) and hydrodesulphurization (HDS) of heavy gas oil derived from Athabasca bitumen using NiMo/Al₂O₃ catalysts containing phosphorus (P). In the catalyst, the concentration of phosphorus was maintained at 2.7 wt%. Experiments were performed in a tickle‐bed reactor at the temperature, pressure and liquid hourly space velocity (LHSV) of 340‐420°C, 6.1‐10.2 MPa and 0.5‐2 h^?1, respectively. H₂ flow rate and catalyst weight were maintained constant at 50 mL/min and 4 g, respectively in all cases. Statistical analysis of all experimental data was carried out using ANOVA to optimize the process conditions for HDN and HDS reactions. Kinetic studies for HDN and HDS reactions were studied within the temperature range of 340‐400°C using the power law model as well as the Langmuir‐Hinshelhood model. The power law model showed that HDN and HDS of heavy gas oil follow first order kinetics. The activation energies for HDN and HDS reactions from the power law and Langmuir‐Hinshelwood models were 94 and 96 kJ/mol and 113 and 137 kJ/mol, respectively.     

Retaining and attracting users in social networking services: An empirical investigation of cyber migration

Users are the most critical strategic resource of any online social networking service (SNS). This paper offers strategic recommendations for SNS providers based on an empirical study exploring why users switch from a primary SNS to others. We first identify important characteristics that combine to distinguish SNSs from conventional information systems, then develop a “cyber migration” research model that includes push, pull and mooring factors which influence user intention to switch from one SNS to another. Findings from a field survey of 180 users reveal four significant factors that promote switching: dissatisfaction with socialization support, dissatisfaction with entertainment value, continuity cost, and peer influence. Strategies grounded in these factors are suggested for SNS providers to better attract and retain users.