天然气空气绝热转化制合成气催化剂研究

制备了天然气空气绝热转化催化剂,采用固定床反应器进行稳定性评价试验,对反应前后的催化剂进行了分析表征。结果说明,天然气和空气绝热转化反应放热形成的高温对催化剂有烧结作用,使催化剂晶体结构发生了变化,起活性作用的金属镍和氧化铝载体转化为镍铝尖晶石结构的物质。进一步的试验表明,在1050～1300℃的温度可以把催化剂的晶体结构改变。     

Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology

The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm² membrane area show the potential for industrial application.     

高抗挤厚壁套管的性能及应用效果评价

中原油田套管损坏的主要原因是现有套管强度不够,无法抵抗盐膏层段的巨大外挤力。开发了TP130TT型高抗挤厚壁套管,其强度能很好地抵抗盐膏层巨大外挤力。实验室试验表明,各项性能指标达到了设计要求,现场使用取得了很好的效果,解决了中原油田盐膏层段套管强度不足的难题。     

重复压裂气井产能模拟研究

由于重复压裂气井原有裂缝的失效程度难以评价。导致重复压裂气井的产能预测常常有很大的误差。为此，根据重复压裂气井的压前产量和舍水率，拟合了原有裂缝的有效率，在考虑新裂缝和原有裂缝共同作用的情况下，建立了气、水两相平面二维的裂缝-油藏数学模型，通过对模型的数值求解，对重复压裂气井进行了产能评价。研究表明，在考虑新、老裂缝共同作用下的产能评价方法，能更为准确地预测重复压裂后的生产动态情况，对压裂时机的确定、压后经济效益的预测都具有重要的指导意义。     

基于MATLAB的风能自校正自调整PID模糊控制器仿真研究

为了提高风力发电系统综合系统性能,在传统风力发电技术的基础上,对变速风力发电机组的自校正自调整PID模糊控制进行了详细的分析和研究,从而利用模糊控制和PID控制相结合的技术,取得了很好的效果。从MATLAB仿真结果看出系统精度及效率很高而稳态误差较小,鲁棒性较好。     

甲基叔戊基醚合成反应的热力学分析

利用戊烯与甲醇合成甲基叔戊基醚(TAME)反应的热力学平衡实验数据, 选择不同的混合活度模型,分别计算得到了该反应体系的平衡常数,并与理论计算得到的平衡常数相比较,筛选出了适合该反应体系的活度计算模型.     

Implicit Leadership Theories in Applied Settings: Factor Structure, Generalizability, and Stability Over Time.

The present empirical investigation had a 3-fold purpose: (a) to cross-validate L. R. Offermann, J. K. Kennedy, and P. W. Wirtz's (1994) scale of Implicit Leadership Theories (ILTs) in several organizational settings and to further provide a shorter scale of ILTs in organizations; (b) to assess the generalizability of ILTs across different employee groups, and (c) to evaluate ILTs' change over time. Two independent samples were used for the scale validation (N1 = 500 and N2 = 439). A 6-factor structure (Sensitivity, Intelligence, Dedication, Dynamism, Tyranny, and Masculinity) was found to most accurately represent ELTs in organizational settings. Regarding the generalizability of ILTs, although the 6-factor structure was consistent across different employee groups, there was only partial support for total factorial invariance. Finally, evaluation of gamma, beta, and alpha change provided support for ILTs' stability over time. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

城市规划中的水资源承载力计算——以惠州市为例

探讨水资源承载力综合评估和多目标计算理论在城市规划中的应用。运用灰色多层次综合评估模型对惠州市水资源承载力进行定性的综合评价,应用多目标规划理论对城市经济发展规划不同方案下的惠州市水资源承载力作了定量计算。     

双波长稳频CO_2激光模糊控制系统的建模与优化

报导一种模糊逻辑控制系统的建模与优化方法。以此方法设计的模糊逻辑控制器，用于双波长稳频ＣＯ２激光器的控制得到令人满意的结果。     

基于模糊数的发射装置模糊可靠性分析

鱼雷发射装置的可靠性直接关系到潜艇武器系统的整体作战效能。考虑到可靠性分析中影响因素的模糊性,本文引入模糊数的概念,对潜艇鱼雷发射装置的可靠性进行分析,并基于模糊数的运算法则,给出了串联系统模糊可靠度的计算方法。