Prediction of methane adsorption content in continental coal-bearing shale reservoir using SLD model

Shale gas, as an important unconventional resource, has drawn global attention. It is mainly composed of adsorption gas and free gas. Adsorption gas content could play an important guiding role on both the selection of favorable perspective area and the exploration and exploitation of shale gas resources. In order to accurately measure adsorption gas content, a new approach was established to predict the adsorption isotherm of methane on shale. Based on the simplified local-density (SLD) method, both the adsorption isotherms of illite, illite/smectite mixed-layer, cholorite and type III kerogen and the total shale rock could be well fitted. The fitting results show good coincidences with the true experimental test data, which proves the method is reasonable and dependable and the prediction results are effective and credible. In addition, the good simulation results show that the SLD parameters can reflect the pore structure characteristics and corresponding adsorption characteristics of the shale samples, which can be used for the quantitative characterization of shale pore system.     

Impact assessment of reservoir desiltation measures for downstream riverbed migration in climate change: A case study in northern Taiwan

Typhoon Aere in 2004 induced severe sedimentation and loss of storage capacity of the Shihmen Reservoir in northern Taiwan. The resulting dramatic increase in the turbidity of the water seriously affected the water supply. To effectively maintain the stability of the water supply and maintain the reservoir’s storage capacity, the government of Taiwan began to plan and construct a series of improvement measures, such as a sediment flushing tunnel, the JhongJhuang Bank-Side Reservoir, and the Amuping Desilting Tunnel. However, previous studies only focused on the impact of the sediment flushing tunnel and the Amuping Desilting Tunnel on the downstream riverbed, and did not consider the possibility of increasing sediment discharge after the completion of the JhongJhuang Bank-Side Reservoir. In addition, climate change will cause the intensity of extreme rainfall to increase enormously in the future. That rainfall and extra sediment flushing will challenge the existing flood prevention facilities. Therefore, this study considered that the JhongJhuang Bank-Side Reservoir will increase sediment discharge of the Shihmen Reservoir, and used dynamical downscaling extreme typhoon data of climate change under the RCP 8.5 scenario to explore the flood prevention and riverbed migration of the main channels of the Dahan and Tamsui Rivers in the future. We used the rainfall–runoff model of Hydrologic Modeling System to simulate rainfall and runoff, and used the hydraulic and sediment transport model of CCHE1D to holistically simulate flood events and consequent river scouring and deposition behaviors. Our results showed that the projected peak discharge during the late 21st century (2075 to 2099) will be at least 50% higher than that during the baseline (1979 to 2003) period. In terms of flood prevention, the potential of overbank flooding will increase in the downstream area, and the trend of long-term change in the riverbed will be dominated by degradation (-0.489 ± 0.743 m) in the future. The improvement measures will have a limited impact on riverbed migration (0.011 ± 0.094 m) in the Dahan and Tamsui Rivers. After the operation of the JhongJhuang Bank-Side Reservoir, the Shihmen Reservoir is expected to increase the sediment discharge ratio by 70% during floods, and it will not cause excessive water turbidity that may affect downstream water supply.     

仪器仪表产品脉冲耐压试验要求和保护器件的选择

仪器仪表产品的脉冲耐压试验是产品型式试验、例行试验中的基本内容。通过对GB4793.1标准的整理,归纳了仪器仪表产品的脉冲耐压试验要求。通过对试验方法和设备特性的梳理,总结了特性参数,并介绍了应对脉冲耐压试验可采取的保护器件的类别及选用方法。     

Natural Gas Production

Current data on natural gas production, as well as a breakdown of production by country. Updated on a monthly basis.     

Hydrogen production from thermal decomposition of ammonia-contaminated acid gas using a detailed reaction mechanism

The increase in the production of acid gas consisting of H₂S, CO₂, and associated impurities such as ammonia and hydrocarbons from oil and gas plants and gasification facilities has stimulated the interest in the development of alternative means of acid gas utilization to produce hydrogen and sulfur, simultaneously. The present literature lacks a detailed reaction mechanism that can reliably predict the thermal destruction of NH₃ and its blend with H₂S and CO₂ to facilitate process optimization and commercialization. In this paper, a detailed mechanism of NH₃ pyrolysis is developed and is merged with the reactions of NH₃ oxidation and H₂S/CO₂ thermal decomposition from our previous works. The mechanism is validated successfully using different sets of experimental data on the pyrolysis and oxidation of NH₃, H₂S, and CO₂. The proposed mechanism predicts the experimental data on NH₃ pyrolysis remarkably better than the existing mechanisms in the literature. The mechanism is used to investigate the effects of NH₃ concentration (0–20%) and reactor temperature (1000–1800 K) on the thermal decomposition of H₂S and CO₂. A synergistic effect is observed in the simultaneous decomposition of NH₃ and CO₂, i.e., NH₃ conversion is improved in the presence of CO₂ and the decomposition CO₂ to CO is enhanced in the presence of NH₃. The presence of H₂S suppressed NH₃ conversion, while the conversion of H₂S remained unchanged with increasing NH₃ concentration at temperature below 1400 K due to the low conversion of NH₃ (up to 18%). At temperature above 1400 K, NH₃ conversion increased rapidly and it triggered a decrease in H₂S conversion as well as the yields of H₂ and S₂. The major reactions involved in the decomposition of H₂S, CO₂, and NH₃ and the production of major products such as H₂, S₂, and CO are identified. The detailed reaction mechanism can facilitate the design and optimization of acid gas thermal decomposition to produce hydrogen and sulfur, simultaneously.     

致密油藏注天然气提高采收率研究现状

随着我国石油需求量不断增加,致密油藏的开发也愈发重要。如何高效开发致密油藏是一项重点难点,其中致密油藏注天然气提高采收率是一个极具潜力的研究方向。因此,本文着重介绍以天然气作为能量补充介质在国内外的研究现状和应用现状,并且从两相特征等方面总结了理论研究中的一些机理,对致密油藏注天然气提高采收率的发展前景进行了一定的展望。     

Occurrence and distribution of dibenzofurans and benzo[b]naphthofurans in the crude oils from the Northern and offshore Niger Delta basin,Nigeria

The occurrence and distributions of dibenzofurans (DBFs) and benzo[b]naphthofurans were investigated in crude oils from Niger Delta, Nigeria, by gas chromatography-mass spectrometry-mass spectrometry. The distribution of DBFs was characterized by the predominance of C₂-dibenzofurans. 4-Methyldibenzofuran was the most abundant among the methyldibenzofurans isomers while dimethyldibenzofuran-2 (DMDBF-2), ethyldibenzofuran-1, DMDBF-3, and DMDBF-6 occurred in higher amounts when compared with other DMDBFs. Among the benzonaphthofurans, the abundance of benzo[b]naphtho[2,1-d]furan was higher than other isomers. The DBFs distributions in the oils were not affected by source facies and depositional environments. However, the DBFs concentrations increased with increasing maturity in oils from ADL and MJO oilfields.     

Predicting the thermodynamics of aluminum dross denitrification of flue gas

Existing alumina extraction and material production methods result in the formation of harmful ammonia gas or ammonia water originating from aluminum nitride (AlN) in dross. Therefore, in this study, aluminum dross was used as a denitration reagent to eliminate nitrogen oxides in flue gas and AlN in dross. Based on the proposed scheme, thermodynamic calculations were performed to investigate the denitrification effect and reduction of aluminum dross in flue gas. The results show that equilibrium concentrations of NO, NO₂, and HF in the flue gas were influenced mainly by temperature; their concentrations increased with an increase in the temperature, reaching 4.4 × 10⁻²⁰, 1.7 × 10⁻³⁸, and 7.0 × 10⁻⁸ g/m³, respectively, at 923 K. The Gibbs free energy corresponding to the reaction of CO₂ with Al/AlN in aluminum dross was −377/–120 kJ/mol. HF, originating from the reaction of NaF and water vapor, maintained an extremely low concentration of 6.99 × 10⁻⁸ g/m³ at 923 K. These results indicate that aluminum dross processing may clean the flue gas and increase the calorific value while eliminating the hazards of AlN. The results obtained herein will provide theoretical guidance toward new avenues of aluminum dross utilization.