稀土钙钛矿催化剂制备方法的研究进展

稀土钙钛矿超微粉体的常规制备方法主要有机械混合法、化学共沉淀法、溶胶-凝胶法以及微乳液法等等。本文总结了以上各种方法的制备过程、特点以及在工艺优化方面国内外所取得的研究进展,并从机理上探讨了上述工艺对稀土钙钛矿催化剂相关性能的影响。     

Elastic-plastic fracture mechanics assessment of test data for circumferential cracked pipes

This paper presents experimental validation of two reference stress based methods for circumferential cracked pipes. One is the R6 method where the reference stress is defined by the plastic limit load. The other is the enhanced reference stress method, recently proposed by the authors, where the reference stress is defined by the optimised reference load. Using 38 published pipe test data, the predicted maximum instability loads according to both methods are compared with the experimental ones for pipes with circumferential through-thickness cracks and with part circumferential surface cracks. It is found that the R6 method gives conservative estimates of the maximum loads for all cases. Ratios of the experimental maximum load to the predicted load range from 0.54 to 0.98. On the other hand, the proposed method gives overall closer maximum loads than R6, compared to the experimental data. However, for part through-thickness surface cracks, the estimated loads were slightly non-conservative for four cases, and possible reasons are fully discussed.     

船用锚链钢M20Mn冷弯断裂原因分析

通过化学成分测试和金相组织分析，认为M20Mn试样冷弯断裂的主要原因是圆钢存在严重的热轧带状组织和表面增碳。采取选择合适的浇注温度和注速、在浇注过程中避免保护渣污染钢液、控制终轧温度等预防措施，消除了M20Mn冷弯断裂缺陷。     

热风炉系统振动管路的流体力学行为分析

管内的一些流体流动行为是引起管路系统振动的重要原因之一。针对钢铁工业高炉热风炉大型设备在运转过程中的振动问题，应用流体力学相关理论重点分析了热风炉周围管路结构的流体力学行为，指出了弯管中二次流旋涡和收缩扩散管段边界层分离旋涡流动是诱发管路振动的机理，从而会给工程设计一些有益的启发。     

周铣加工表面形貌仿真新算法

考虑主轴偏心，基于周铣过程中刀具切削刃上任意点与工件相对运动的轨迹方程和周铣过程几何特征，构造出可以求解周铣加工表面上任意一点形貌高度值的三维表面形貌仿真算法，并给出了相应的仿真算例。该算法无需对刀齿进行微段离散，并且不依赖于工件网格划分，加工表面上任意一点形貌高度值的计算次数等于刀具齿数，具有通用性好、运算速度快、结果准确度高的特点。     

Surface Alloying of Nitrogen to Improve Corrosion Resistance of Steels and Stainless Steels

It is well known that the addition of nitrogen to steels and stainless steels enhances the passivity and localized corrosion resistance, in addition to improving the mechanical properties. Selective alloying of surfaces of steels and stainless steels with nitrogen could also enhance the corrosion resistance and improve the mechanical properties without affecting the bulk properties. Techniques like ion implantation, laser alloying, nitriding, etc. can be effectively used to introduce very high levels of nitrogen. In addition, these techniques can also produce modified surfaces with novel microstructures to further improve the properties. The surface alloying methods also provide an opportunity to selectively nitrogenate the surface of finished components in order to obtain better properties. The review highlights the techniques, modifications and the properties obtained further.     

A theory of pad conditioning for chemical-mechanical polishing

Statistical models are presented to describe the evolution of the surface roughness of polishing pads during the pad-conditioning process in chemical-mechanical polishing. The models describe the evolution of the surface-height probability-density function of solid pads during fixed height or fixed cut-rate conditioning. An integral equation is derived for the effect of conditioning on a foamed pad in terms of a model for a solid pad. The models that combine wear and conditioning are then discussed for both solid and foamed pads. Models include the dependence of the surface roughness on the shape and density of the cutting tips used in the conditioner and on other operating parameters. Good agreement is found between the model, Monte Carlo simulations and with experimental data.     

Variations of stress intensity factor of a semi-elliptical surface crack subjected to mixed mode loading

Maximum stress intensity factors of a surface crack usually appear at the deepest point of the crack, or a certain point along crack front near the free surface depending on the aspect ratio of the crack. However, generally it has been difficult to obtain smooth distributions of stress intensity factors along the crack front accurately due to the effect of corner point singularity. It is known that the stress singularity at a corner point where the front of 3 D cracks intersect free surface is depend on Poisson's ratio and different from the one of ordinary crack. In this paper, a singular integral equation method is applied to calculate the stress intensity factor along crack front of a 3-D semi-elliptical surface crack in a semi-infinite body under mixed mode loading. The body force method is used to formulate the problem as a system of singular integral equations with singularities of the form r ⁻³ using the stress field induced by a force doublet in a semi-infinite body as fundamental solution. In the numerical calculation, unknown body force densities are approximated by using fundamental density functions and polynomials. The results show that the present method yields smooth variations of mixed modes stress intensity factors along the crack front accurately. Distributions of stress intensity factors are indicated in tables and figures with varying the elliptical shape and Poisson's ratio.     

Oxidation behaviour of the near α-titanium alloy IMI 834

Oxidation behaviour of the near α-titanium alloy IMI 834 was investigated over a range of temperatures, from 600–800°C, in air. Specimens were solution-treated in the α + β and β phase fields for 1 h and 1/2 h, respectively and cooled in air to room temperature. The solution treated samples were subjected to stabilization treatment at 700°C for 2 h, followed by cooling in air. Oxidation behaviour of these samples was studied from 600–800°C in air, for 50 h. The morphology of the scales formed was examined by SEM and the phases present in the scales were characterized by X-ray diffraction. While there was little oxidation at 600°C, the rate of oxidation increased at higher temperatures. In general, the rate of oxidation was found to be more in the α + β treated condition than that in the β treated one. The results are discussed in terms of the characteristics of the oxide film formed under different conditions.     

Viscosity and Surface Tension of Saturated <Emphasis Type="Italic">n</Emphasis>-Pentane

Light scattering by thermally excited capillary waves on liquid surfaces or interfaces can be used for the investigation of viscoelastic properties of fluids. In this work, the simultaneous determination of surface tension and liquid kinematic viscosity of n-pentane by surface light scattering (SLS) on a gas–liquid interface was carried out. The experiments are based on a heterodyne detection scheme and signal analysis by photon correlation spectroscopy (PCS). Measurements were performed under saturation conditions over a wide temperature range from about 233 to 363 K. For the whole temperature range the total uncertainty of the liquid kinematic viscosity and surface tension is estimated to be better than 1.0 and 1.2, respectively. The results obtained corroborate the reliability of the SLS technique for the determination of thermophysical properties.