基于模板热压法制备超疏水柱状结构表面

超疏水表面材料在生产生活中具有重要的应用价值,其制备的关键在于构建合适的表面微结构。以多孔阳极氧化铝表面为模板,高密度聚乙烯为压印热塑材料,进行常压工况下的热压印,制备出三维柱状结构表面,表面形貌规整有序,通过调节模板结构参数实现对柱状结构尺寸的精确调控。测试结果显示,制备的不同微结构尺寸的柱状结构表面接触角均在150°以上,具有优异的超疏水性能。     

Ultrasound assisted in situ emulsion polymerization for polymer nanocomposite: A review

This review covers an ultrasound assisted synthesis of polymer nanocomposites using in situ emulsion polymerization. First of all, surface modification of core nanoparticles with a coupling agent and surfactant has been employed for the synthesis of core–shell polymer nanocomposites. In addition to application of ultrasound for the synthesis of core–shell polymer nanocomposites, due to its influential efficiency, sonochemistry has been extensively used not only as an aid of dispersion for inorganic nanoparticles and organo-clay, but also acts as an initiator to enhance polymerization rate for synthesis of polymer nanocomposites. In situ emulsion polymerization of hydrophobic monomers, such as methyl methacrylate, butyl acrylate, aniline, vinyl monomers and styrene, using surfactant and water soluble initiator were carried out for a synthesis of core–shell polymer nanocomposite. This technique assists in preparation of stable and finely dispersed polymer nanocomposite with the loading of inorganic particles up to 5 wt.%. Recent developments in the preparation of core–shell polymer nanocomposites using an ultrasound assisted method with their physical characteristics such as morphology, thermal, and rheological properties and their potential engineering applications have been discussed in this review.     

Inorganic microencapsulated core/shell structure of Al–Si alloy micro-particles with silane coupling agent

Al–Si eutectic alloy is a kind of ideal high temperature phase change materials (PCMs) because of its high latent heat and good heat transfer performance. However, it is difficult for Al–Si alloy to be safely applied because of its causticity and incompatibility. In this paper, an inorganic Al–Si/Al₂O₃ micro-particles core/shell structure was prepared by the sol–gel process with the modification of silane coupling agent. The direct evidence for the forming of the dense and stable α-Al₂O₃ shell layer, whose thickness is about 3–5 μm, is presented by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). In terms of the analyses of Fourier transform infrared (FT-IR) and thermogravimetry (TG), it is apparent that the silane coupling agent is successfully grafted on the surface of Al–Si alloy micro-particles, which promotes the condensation between boehmite sols and silanol groups. The latent heat of the encapsulated Al–Si alloy was 307.21 kJ/kg and decreased during the process of microencapsulation. The reasons for the reduction of the latent heat are the excess alumina sols and the depletion of Al–Si alloy.     

电子行业用聚酯热熔胶的制备及其性能研究

以玻璃化转变温度较低的共聚酯制备了聚酯热熔胶。研究结果表明:聚酯热熔胶对丙烯腈-丁二烯-苯乙烯共聚物(ABS)、聚碳酸酯(PC)等极性塑料与金属材料具有良好的粘接性能,稳定后的剥离强度大于100N/25mm;同时,具有良好的耐老化性能及粘接持久性。聚酯热熔胶可取代国外产品用于电子行业用极性聚合物与金属材料粘接。     

Synthesis,microstructure and mechanical properties of Cr2AlC/Al2O3 in situ composites by reactive hot pressing

Al₂O₃ particle-reinforced Cr₂AlC in situ composites were successfully fabricated from powder mixtures of Cr₃C₂, Cr, Al, and Cr₂O₃ by a reactive hot-pressing method at 1400 °C. A possible synthesis mechanism was proposed to explain the formation of the composites in which Al₂O₃ was formed by the aluminothermic reaction between Al and Cr₂O₃, meanwhile, Cr₃C₂, Al, together with Cr reacted to form Cr₂AlC in a shortened reaction route. The effect of Al₂O₃ addition on the microstructure and mechanical properties of Cr₂AlC/Al₂O₃ composites was investigated. The results indicated that the as-sintered products consisted of Cr₂AlC matrix and Al₂O₃ reinforcement, and the in situ formed fine Al₂O₃ particles dispersed at the matrix grain boundaries. The flexural strength and Vickers hardness of the composites increased gradually with increasing Al₂O₃ content. But the fracture toughness peaked at 6.0 MPa m^1/2 when the Al₂O₃ content reached 11 vol.%. The strengthening and toughening mechanism was also discussed.     

热水锅炉给水除氧方式的研究

阐述了锅炉及供热系统给水除氧的重要性,对常用锅炉给水除氧方法进行简要分析总结,在选择锅炉给水除氧方式时,应结合各种除氧方式的特点,采用适合本供热系统的最佳除氧方式。     

球罐基础沉降差对支柱稳定性影响的分析处理

介绍了球罐安装中可能出现的球罐支柱失稳问题。对1台5000 m3球罐的基础沉降差对支柱稳定性的影响进行了计算分析,并提出了一些增强球罐支柱稳定性的措施。     

THE s-VERSION OF FINITE ELEMENT METHOD FOR LAMINATED COMPOSITES

The s-version of the finite element method is developed for laminated plates and shells. By this technique the global domain is idealized using 2-D Equivalent Single Layer model. The regions where ESL model errs badly in capturing localized phenomena are superimposed by a stack of 3-D elements. Assumed strain formulation and selective polynomial order escalation in the two models, as well as fast iterative procedures, are employed to maintain a high level of computational efficiency.     

镁合金板材冲压性能与冲压工艺研究进展

镁合金板材冲压件在笔记本电脑、手机、数码相机等电子产品和交通工具上将有极大的应用前景,近年来逐渐成为国内外关注的焦点之一.从镁合金板材的材料特点值、工艺试验、板材冲压性能的改善及二次成形等方面综述了其最新研究进展,并提出了进一步的研究方向.     

研究单壁碳纳米管杨氏模量的一种能量方法

本文利用能量方法研究了单壁碳纳米管(single-walled carbon nanotubes, SWCNT)的杨氏模量.文中,首先采用分子力学理论得出了受轴向载荷作用下单壁碳纳米管的总势能;然后通过总势能与相应薄圆柱壳的应变能比较,推导出了单壁碳纳米管杨氏模量的计算公式.另外,从一系列碳纳米管杨氏模量的计算发现,本文研究结果与现有研究结果比较一致.