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31.
Theoretical analyses for the single fibre pull-out and push-out models under monotonic loading are given which are based on a shear-lag analysis in a fracture mechanics approach considering non-constant friction at the debonded interface as a result of fibre Poisson contraction (or expansion). The solutions allow the determination of typical fibre/matrix interfacial properties such as the interfacial fracture toughness, Gic, the coefficient of friction, μ, and the residual clamping stress, q0. Under cyclic loading the interfacial properties are expected to degrade as a result of repetitive abrasion, and a power law function is assumed between μ and the number of elapsed cycles, N. However, Gic is assumed to be unaffected and a fracture mechanics based debond criterion is derived for the relationship between the external applied stress, the debond length and the reduced friction coefficient for both fibre pull-out and fibre push-out. In addition, the relative displacements between the free fibre end and the matrix top are obtained for cyclic fatigue when the fibre is loaded and unloaded. A relationship obtained for the protrusion (or intrusion) length in fibre pull-out (or push-out) experiments allows the severity of the interface frictional degradation to be evaluated and characterised. Similarities and differences in the frictional degradation behaviour between fibre pull-out and push-out are also identified. 相似文献
32.
A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the Tm and Tc of microPCMs were in the range of 29.8–31.0oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006 相似文献
33.
A series of short fibre reinforced styrene butadiene rubber (SBR) composites were prepared by incorporating sisal fibres of
different lengths and different concentrations. The vulcanization behaviour and the properties of the vulcanizates were measured
by the relevant ASTM procedures. The processing characteristics such as green strength and mill shrinkage were improved by
the addition of fibres. The properties like tensile strength, tear strength, moduli at 10% and 20% elongations were found
to be maximum for composites containing longitudinally oriented fibres of length 6 mm. Mixes containing 35 phr loading of
fibres and bonding agent showed better mechanical performance than others. The failure behaviour of tensile and tear specimens
have been analysed by scanning electron microscopy techniques.
Paper presented at the poster session of MRSI AGM VI, Kharagpur, 1995 相似文献
34.
Morphology of intermetallic compounds formed between lead-free Sn-Zn based solders and Cu substrates
The morphologies of intermetallic compounds formed between Sn-Zn based solders and Cu substrates were investigated in this
study. The investigated solders were Sn-9Zn, Sn-8.55Zn-0.45Al, and Sn-8.55Zn-0.45Al-0.5Ag. The experimental results indicated
that the Sn-9Zn solder formed Cu5Zn8 and CuZn5 compounds on the Cu substrate, while the Al-containing solders formed the Al4.2Cu3.2Zn0.7 compound. The addition of Ag to the Sn-8.55Zn-0.45Al solder resulted in the formation of the AgZn3 compound at the interface between the Al4.2Cu3.2Zn0.7 compound and the solder. Furthermore, it was found that the cooling rate of the specimen after soldering had an effect on
the quantity of AgZn3 compound formed at the interface. The AgZn3 compound formed with an air-cooling condition exhibited a rougher surface and larger size than with a water-quenched condition.
It was believed that the formation of the AgZn3 compound at the interface occurs through heterogenous nucleation during solidification. 相似文献
35.
非接触型光外差轮廓仪 总被引:1,自引:0,他引:1
本文介绍一种纳米级非接触型高精度光外差轮廓仪,它是基于普通光路的光外差干涉仪。工件表面被两束有微小频差的激光束所照射,其中一束经聚焦后用作测量光探针来扫描工件表面,另一束则用作参考光束。两束光经表面反射后产生干涉。测量信号和参考信号的相位差与表面的微不平值成正比。仪器的横向分辨率为2μm,高度分辨率为1 nm,它不需要对试样作大范围的调整,且可用试样自身作参考面。信号经光电转换后由微型计算机进行处理,它能快速完成测量、计算、显示及打印出各种参数和曲线。 相似文献
36.
Interfacial polycondensation of diphenolic acid (DPA) and isophthaloyl chloride (IPC) in various solvent/water systems was investigated with tetrabutyl ammonium chloride as a phase transfer catalyst. It was found that a large mass of capsules were formed at the beginning of the reaction for all solvents examined but the capsule morphology and reaction results depended on the solvents. It is believed that the capsule shells make up of the reaction zone and a mechanism of the interfacial polycondensation is proposed accordingly. The effect of the solvents on the reaction was interpreted from the interaction between the polymer and the solvent according to the mechanism. The reaction conditions were optimized, and poly(DPA-IPC) with high intrinsic viscosity was prepared in high yield under the optimal condition. It is an amorphous polymer with glass transition temperature of about 160°C. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
37.
Specular X-ray reflectivity from SiO2 thin films prepared on silicon substrates by plasma-enhanced chemical vapor deposition showed the films to have a characteristic width of the decay in density at the free surface of 17 Å, to be about three-quarters the density of -quartz, and to have an interfacial layer at the silicon interface that was of the order of 100 Å wide and less dense than the bulk of the film. After chemical-mechanical polishing the characteristic width of the decay in density at the free surface was reduced to 10 Å; furthermore, the near-surface region to a depth of 30 Å had a greater density than the as-deposited film. Off-specular reflectivity confirmed that the decrease in characteristic width at the free surface was due to reduced roughness upon polishing and also revealed that the lateral correlation length in the limit of long wavelengths was the same for both polished and unpolished samples. The compression of the near-surface region during polishing is believed to enhance the dissolution of SiO2 into the slurry which is necessary to achieve smooth surfaces. 相似文献
38.
Dielectric properties andI–V characteristics of solution-gas interface-formed PbS thin-film capacitors (Al/PbS/Al) of various thicknesses have been studied
in the frequency range 10-106 Hz at various temperatures (300–443 K). Current-voltage (I–V) characteristics show space-charge-limited conduction. Dielectric constant (ε) increases with increasing film thickness and temperature and decreases with increase of frequency. The loss factor (tanδ) peaks observed in tanδ vs frequency and tanδ vs temperature reveal relaxation effect from dipolar orientation. These maxima shift to higher-temperature region with increasing
frequency. The large increase in capacitance (C) and dielectric constant (ε) towards low-frequency (f) region indicates the possibility of an interfacial polarization mechanism in this region. 相似文献
39.
R. van Tijum 《Surface & coatings technology》2007,201(8):4633-4639
This paper concentrates on revealing the local deformation as a function of applied strain in a polymer coating supported by a plastically deforming and roughening metal substrate. To this end in-situ birefringence microscopy measurements have been executed. The measurements are performed in reflection and an alternative unwrapping scheme for the optical path difference is proposed. From the characterization of PET (polyethylene terephthalate) coated stainless steel it is concluded that strain localization appears below the macroscopic strain at yield and that the surface roughness of the substrate is the driving force of the localization. 相似文献
40.
电镀锡机组软熔导电辊脱锡技术研究 总被引:3,自引:0,他引:3
粘锡是电镀锡机组软熔导电辊失效的主要原因,应用化学方法脱锡是延长导电辊寿命的重要途径.开发了氢氧化钠(钾)为主要组成,并加入适量亚铅酸钠(钾)和硝酸(亚硝酸)钠配制而成脱锡剂,当脱锡剂温度为40~80℃,导电辊表面温度为40~70℃时,对粘锡导电辊具有很好的脱锡效果.粘锡导电辊脱锡后的表面粗糙度可以恢复到4.0μm以上,导电辊使用寿命提高80%,降低导电辊修复成本90%,并大幅度减少导电辊更换时间,提高电镀锡机组生产作业率. 相似文献