Properties of Co-doped N-type FeSi2 processed by mechanical alloying

Iron-silicide was produced with a mechanical alloying process and consolidated through vacuum hot pressing. The as-milled powders were of metastable state and fully transformed into the ß-FeSi₂ phase through subsequent isothermal annealing. The as-consolidated iron silicides consisted of an untransformed mixture of α-Fe₂Si₅ and ?-FeSi phases and a partially transformed β-FeSi₂ phase was found in the low density compact. Isothermal annealing was carried out to induce transformation into a thermoelectric semiconducting β-FeSi₂ phase. The transformation behavior of the β-FeSi₂ was investigated utilizing DTA, SEM, and XRD analyses. Isothermal annealing at 830°C in vacuum led to a thermoelectric semiconducting β-FeSi₂ phase transformation, but some residual metallic α and ?-phases were unavoidable even after 96 hours of annealing. The iron silicide microstructures were investigated using SEM and TEM. The mechanical and thermoelectric properties of the β-FeSi₂ materials before and after isothermal annealing are characterized in this study.     

THE INFLUENCE OF ENVIRONMENT ON FATIGUE AND FRACTURE OF IRON ALUMINIDES

ＴＨＥＩＮＦＬＵＥＮＣＥＯＦＥＮＶＩＲＯＮＭＥＮＴＯＮＦＡＴＩＧＵＥＡＮＤＦＲＡＣＴＵＲＥＯＦＩＲＯＮＡＬＵＭＩＮＩＤＥＳＳＴＯＬＯＦＦ，Ｎ．Ｓ．ａｎｄＡＬＶＥＮ，Ｄ．Ａ．（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｅｒｉａｌｓＥｎｇｉｎｅｅｒｉｎｇＲｅｎｓｓｅ...     

热压变形对灰口铸铁石墨形态的影响

研究了灰口铸铁(HTl50)在900℃大压下量塑性变形后石墨的分布形态，结果表明：随着压下量的增加，石墨片逐渐趋于平行分布；变形过程中发生了碳的回溶，同时伴随着石墨片的断裂；石墨片体积分数及片间距随压下量的增加而逐渐减少。     

锰对低铬白口铸铁组织及硬度的影响

系统研究了Ｍｎ对水平连铸低铬白口铸铁铸态及正火态组织和硬度的影响。结果表明，Ｍｎ＞２．０％之后对组织有较大影响，由于出现（Ｍ＋Ａ）组成物，使基体硬度显著提高，这将大大改善了低铬白口铸铁中碳化物与基体硬度的相对关系。试验证实，Ｍｎ＞３％之后明显改善硬度分布均匀性。还讨论了使低铬锰白口铸铁具有最佳综合性能的合理含Ｍｎ量范围     

高铁三水铝石型铝土矿的烧结特性

以Al2O3含量为26.35%,总Fe含量为31.22%,铝硅比为3.17的某高铁三水铝石型铝土矿为原料,研究了碱度、焦粉用量、混合料水分等对烧结矿质量指标的影响。结果表明:烧结矿碱度增加时,其转鼓强度和成品率下降,烧结矿自粉化程度加重;焦粉用量增加时,烧结矿转鼓强度和成品率提高;当混合料水分为9.0%、焦粉用量为8.0%、烧结矿碱度为4时,烧结矿转鼓强度为69.1%,成品率为81.2%,垂直烧结速度为30 mm/min,利用系数为1.2 t/(h.m2);烧结矿碱度为4时,样品存放2天粉化率为5%,烧结矿平均粒度由22.2 mm减小到21.9 mm,延长存放时间,烧结矿自粉化率增大,平均粒度显著减小。该烧结矿的冶金性能能基本满足高炉冶炼的要求。     

金属型铸造高铬白口铸铁磨球的复合变质处理研究

研究了复合变质处理对金属型铸造的高铬格白口铸铁磨球组织及性能的影响。结果表明，采用ＲＥ、Ｂ、Ｖ、Ｔｉ元素复合变质处理，可有效细化磨球结晶组织，改善碳化物的形态与分布，并显著提高冲击韧性和耐磨性能。     

利用"正火液"作为高铬铸铁磨球淬火介质的生产实践

高铬铸铁件在没有添加贵重元素的条件下,利用"正火液"配入适量的水作为淬火介质进行了试验和生产.实践证明,产品在热处理淬火时从未发生炸裂现象,同时完全达到了要求的力学性能指标.生产的锤头其使用寿命为高锰钢的6～8倍,为低铬白口铸铁的4～6倍.     

灰铁铸件牌号要求与熔炼配料选择

由于铸件壁厚对其性能有明显影响，牌号要求相同、壁厚不同的灰铁铸件必须采用不同的成分和配料。介绍不同灰铁铸件牌号标准的对照，并用生产实例说明如何根据图纸牌号要求、铸件结构和使用性能要求选择化学成分控制标准和熔炼配料。     

铁矿石冶金性能实验方法的改进

在不影响实验结果的前提下，对铁矿石的还原度实验方法进行改进。改进后每个实验时间缩短3～4．5h，且大大降低了实验成本。     

Preparation and mechanical properties of Fe_3Al/Al_2O_3 nano-/micro-composite

1　INTRODUCTIONAlumina(Al2 O3)ceramicsareoftenconsideredforstructuralapplications,duetotheirpropertiesofhighhardness ,chemicalandwearresistanceandgoodmechanicalpropertiesatroomandhightemperature .Thewellknownlimitationfortheseceramics ,how ever ,istheverylowtoughness .Recentstudieshaveshownsignificantimprovementsinmechanicalprop erties ,includingtoughness ,byaddingductilesecondphaseparticles ,suchasNi,Al,MoandCu[14 ] .Anincreaseof 80 % 333%inthefracturetoughnesshasbeenreportedforAl2 O3…