从铅阳极泥处理后的渣料中综合回收有价金属的生产实践

叙述了从铅阳极泥回收金银后的渣料中综合回收有价金属的生产实践。根据渣料性质，将火法和湿法工艺相互结合，使渣料中的锑、铋、金、银、铅、铜得以较彻底的分离和回收。     

穿壁焊极柱合金探索

本文对起动用铅酸蓄电池穿壁焊极柱用合金配方进行了探索 ,并得到了良好的应用效果     

大尺寸氟化铅晶体的生长

描述了不用高真空条件，在通常的Ｂｒｉｄｇｍａｎ－Ｓｔｏｃｋｂａｒｇｅｒ炉中，用高温下的反应方法，消除了原料及生长炉内残存的Ｏ＾２－及ＯＨ＾－，生长出优质，大尺寸的β－ＰｂＦ２晶体。在晶体生长时，出现的主要问题是在晶体中的针状结构及开裂，但可通过控制条件来解决。     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

On‐Line Detection Of State‐Of‐Charge In Lead Acid Battery Using Radial Basis Function Neural Network

To realize a stable supply of electric power in an automobile, an accurate and reliable detection method of SOC (state‐of‐charge) in a lead acid battery is required. However the dynamics of the battery is very complicated. The characteristics of the battery greatly change due to its degradation. Moreover a automobile has many driving patterns, which are unknown beforehand. Thus it is not easy to detect the SOC analytically. In this paper, to overcome this problem, a new on‐line SOC detection method with a radial basis function neural network is proposed. In order to increase the detection accuracy of degraded batteries, physical values related to the degradation degree are used as input signal in the neural network. The detection accuracies for different sized batteries and various degradation states are investigated.     

醋酸铅在离子液体中溶解机理的研究

通过[bmim]Cl和Pb(OAc)2混合反应后析出PbCl2沉淀,制备得到溶解有醋酸铅的离子液体[bmim]OAc。实验发现,即使使用过量的醋酸铅,PbCl2仍然不能沉淀完全,这表明离子液体中的Pb2+离子并不是以游离形式存在的,而是以配位的形式存在,并且由离子液体包裹着。因此,醋酸铅在离子液体[bmim]OAc中的溶解度得到增加,平均溶解度达到1 1mmol/ml,最大溶解度达到3 0mmol/ml。     

阀控式铅酸蓄电池的维护

对阀控式铅酸式蓄电池的维护工作进行了初步探讨。     

Implicit integration and consistent tangent modulus of a time‐dependent non‐unified constitutive model

This paper describes the implicit integration and consistent tangent modulus of an inelastic constitutive model with transient and steady strain rates, both of which are time‐ and temperature‐dependent; the transient rate is influenced by the evolution of back stress decomposed into parts, while the steady rate depends only on applied stress and temperature. Such a non‐unified model is useful for high‐temperature structural analysis and is practical owing to the ease in determining material constants. The implicit integration is shown to result in two scalar‐valued coupled equations, and the consistent tangent modulus is derived in a quite versatile form by introducing a set of fourth‐rank constitutive parameters into the discretized evolution rule of back stress. The constitutive model is, then, implemented in a finite element program and applied to a lead‐free solder joint analysis. It is demonstrated that the implicit integration is very accurate if the multilinear kinematic hardening model of Ohno and Wang is employed, and that the consistent tangent modulus certainly affords quadratic convergence to the Newton–Raphson iteration in solving nodal force equilibrium equations. Copyright © 2003 John Wiley & Sons, Ltd.     

进一步降低钼精矿中铜、铅含量的生产实践

分析了钼精矿Cu、Pb含量高的主要原因 ,通过实施一系列措施 ,达到了降低钼精矿中Cu、Pb含量的目的     

Influence of pencil lead hardness on voltammetric response of graphite reinforcement carbon electrodes

This work studied the voltammetric response of graphite reinforcement electrodes made of different pencil lead hardness. The studies showed that harder graphite leads, regardless of their manufacturer, are more appropriate as electrode material for voltammetric purposes due to their higher peak currents, increasing sensitivity and reproducibility, with ΔEp closer to the theoretical value for a reversible system.