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磷氮阻燃腈纶结构性能及阻燃机理研究 总被引:5,自引:0,他引:5
研究了含磷酸二氢铵和脲复合阻燃剂的共混阻燃腈纶的结构和性能。研究表明,在纤维成形加工过程中,部分阻燃剂聚合生成聚磷酸铵和聚脲,阻燃剂以微粒状均匀分散并包埋在纤维内部;阻燃剂的加入使纤维高序区大分子间等距离排列的规整性和片状结构单元等距离平行排列的程度降低,热稳定性亦略有下降;但纤维的宏形态结构及物理机械性能没有明显变化;磷氮阻燃腈纶具有良好的阻燃性和阻燃耐久性,经碱洗20次、水洗30次后,阻燃剂的磷和氮的保留率分别高达82.9%和89.5%,纤维的LOI值仍在26%以上。 相似文献
23.
Bradley James C.; Richards W.Graham 《Protein engineering, design & selection : PEDS》1994,7(7):859-862
Model structures for the pore of the potassium channels Shakerand ROMK1 are predicted. The models arise from computer simulationsand suggest reasons for the striking selectivity of these channelsfor K+ and the blocking of ROMK1 by internal Mg2+. The modelledstructure of the Shaker pore is supported by mutagenesis data.The mutagenesis experiments indicate the side chains responsiblefor binding to blocking agents [tetraethylammonium (TEA) andcharybdotoxin (CTX)] and the model has these side chains suitablyoriented for binding. An aromatic K+ binding site part way downthe pore is also predicted by the Shaker pore model. 相似文献
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The evolution of the amorphous structure of starch was characterized during the drying process by real‐time X‐ray wide‐angle scattering. The X‐ray diffractograms of injection‐molded starch show two superposed, rather broad, scattering maxima indicative of noncrystalline structures. The location of the two peaks has been associated to disordered starch single helices. A third maximum that arises upon drying the material in vacuum is associated to the scattering emerging from regions containing double helices. A model for the starch network is proposed, assuming a primary and a secondary component. The wider, temperature stable component appearing first, is correlated to the entanglement network of the melt. The narrower network component, which is created later, at lower temperature (secondary network), is explained by the formation of double helix regions that densify the wider primary network. The secondary network is increased strongly by the drying process. X‐ray experiments performed during the penetration of water, provoking a higher molecular mobility, reveal a better‐packed helical structure that becomes the precursor of a double helix crystalline formation. When temperature increases, the secondary network is dissolved and water molecules arrange themselves in better‐organized crystals as strongly bound crystal water. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1880–1886, 2006 相似文献
26.
The catalytic activities of WCI6Ph4Sn, MoCl5Ph4Sn and tetrabenzyltitanium were examined in the polymerization of acetylene. The structure, morphology and electrical conductivity of the doped and non doped polyacetylene were also studied. 相似文献
27.
The effect of the platinum particle size was investigated for the catalytic oxidative dehydrogenation of aqueous ethanol to ethanal at a temperature of 303 K, an ethanol concentration of 260 mol m–3, a partial oxygen pressure 60 kPa, a pH of 9, and an ethanal and ethanoate concentration of 20 mol m–3. A particle size effect on the turnover frequency was observed but only for particle sizes smaller than 2 nm. Hence, the reaction shows a limited structure sensitivity. 相似文献
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Bio-cryptography is an emerging security technology which combines cryptography with biometrics. A good bio-cryptosystem is required to protect the privacy of the relevant biometric data as well as achieving high recognition accuracy. Fingerprints have been widely used in bio-cryptosystem design. However, fingerprint uncertainty caused by distortion and rotation during the image capturing process makes it difficult to achieve a high recognition rate in most bio-cryptographic systems. Moreover, most existing bio-cryptosystems rely on the accurate detection of singular points for fingerprint image pre-alignment, which is very hard to achieve, and the image rotation transformation during the alignment process can cause significant singular point deviation and minutiae changes. In this paper, by taking full advantage of local Voronoi neighbor structures (VNSs), e.g. local structural stability and distortion insensitivity, we propose an alignment-free bio-cryptosystem based on fixed-length bit-string representations extracted from modified VNSs, which are rotation- and translation-invariant and distortion robust. The proposed alignment-free bio-cryptosystem is able to provide strong security while achieving good recognition performance. Experimental results in comparison with most existing alignment-free bio-cryptosystems using the publicly-available databases show the validity of the proposed scheme. 相似文献
30.
A review of analytical modeling of particulate reinforcement is made as a prelude to the problem of microstructural inhomogeneity in nanocomposite materials. Noting the inevitability of dispersion nonuniformity, and variations in agglomerate morphology and filler‐matrix interaction, the need to question the application of such models to novel materials arises. Employing the mechanical properties of alumina/epoxy nanocomposites, with known dispersion characteristics, an evaluation of the predictive capability of various models for Young's modulus, strength, and failure strain is made. Comparison between models is accompanied by a discussion of the parameters used in the fitting of macroscopic behavior to microstructural features. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 869–879, 2005 相似文献