Electrophoretic mobilities of dissolved polyelectrolyte charging agent and suspended non-colloidal titanium during electrophoretic deposition

Coarse (≤20 μm) titanium particles were deposited on low-carbon steel substrates by cathodic electrophoretic deposition (EPD) with ethanol as suspension medium and poly(diallyldimethylammonium chloride) (PDADMAC) as polymeric charging agent. Preliminary data on the electrophoretic mobilities and electrical conductivities on the suspensions of these soft particles as well as the solutions themselves as a function of PDADMAC level were used as the basis for the investigation of the EPD parameters in terms of the deposition yield as a function of five experimental parameters: (a) PDADMAC addition level, (b) solids loading, (c) deposition time, (d) applied voltage, and (e) electrode separation. These data were supported by particle sizing by laser diffraction and deposit surface morphology by scanning electron microscopy (SEM). The preceding data demonstrated that Ti particles of ∼1-12 μm size, electrosterically modified by the PDADMAC charging agent, acted effectively as colloidal particles during EPD. Owing to the non-colloidal nature of the particles and the stabilization of the Ti particles by electrosteric forces, the relevance of the zeta potential is questionable, so the more fundamental parameter of electrophoretic mobility was used. A key finding from the present work is the importance of assessing the electrophoretic mobilities of both the suspensions and solutions since the latter, which normally is overlooked, plays a critical role in the ability to interpret the results meaningfully. Further, algebraic uncoupling of these data plus determination of the deposit yield as a function of charging agent addition allow discrimination between the three main mechanistic stages of the electrokinetics of the process, which are: (1) surface saturation; (2) compression of the diffuse layer, growth of polymer-rich layer, and/or competition between the mobility of Ti and PDADMAC; and (3) little or no decrease in electrophoretic mobility of Ti, establishment of polymer-rich layer, and/or dominance of the mobility of the PDADMAC over that of Ti.     

3-丙酰氨基-N,N-二丙酸甲酯基苯胺的合成研究

用无水三氯化铝作催化剂在较低温度下将3-氨基丙酰苯胺和丙烯酸甲酯转化为3-丙酰氨基-N,N-二丙酸甲酯基苯胺,其产品收率达到89%,纯度高于92%。     

Polycrystalline behavior analysis of pure magnesium by the homogenization method

In this study, mechanical behaviors of pure magnesium polycrystals are numerically investigated. The homogenization method, which combines the crystal and macroscopic scales, is introduced to include the effect of crystalline scale behaviors. The polycrystal plasticity model modified for pure magnesium, in which twinning is considered as asymmetric slip-like deformation, is utilized as a constitutive equation. Within this framework, numerical convergence analyses are conducted, and a representative volume element to present realistic deformation of pure magnesium is investigated. Second, polycrystalline behaviors of pure magnesium are investigated. The present approach is shown to reproduce the typical phenomena induced by crystalline scale structure in pure magnesium: nonuniform strain distribution, asymmetric crystal lattice orientation, strength differential effect, and strongly anisotropic initial and subsequent yield surfaces.     

镁合金激光焊的研究现状及发展趋势

镁合金具有质轻、环保等特性,被誉为21世纪绿色工程材料,在汽车、摩托车、航天航空等领域有着广泛的应用前景,但焊接问题已经成为制约其应用的关键。和其他熔焊方法相比,激光焊具有焊缝熔深大、接头性能优良等特点,是镁合金焊接的理想方法之一。目前,两类典型的工业激光器,即CO2和Nd…YAG激光器都已用于镁合金焊接的研究。系统分析了镁合金激光焊的工艺方法、焊接材料、接头性能(主要为力学性能与腐蚀性能)以及冶金缺陷(主要有气孔和裂纹),综述了近年来国内外镁合金激光焊接的研究现状,并对镁合金激光焊研究及应用的发展趋势进行了展望。     

HPLC法测定复方托吡卡胺滴眼液中苯扎氯铵的含量

目的：建立超高效液相色谱法测定复方托吡卡胺滴眼液中苯扎氯铵的含量测定方法。方法：色谱柱为Alltech Alltima -CN（250cm ×4．6mm ,5μm）,流动相为0．1mol?L -1醋酸钠溶液（用冰醋酸调节pH值至5．0）-乙腈（60：40）,检测波长254nm ,流速为2．0ml?min -1,柱温30℃,进样体积50μL。结果：苯扎氯铵在0．02至0．5mg?mL -1浓度范围内线性关系良好（r＝0．9999）;平均回收率为98．91％,RSD＝0．44％（n＝9）。结论：该方法准确、简便、快速、可靠,能有效控制复方托吡卡胺滴眼液中苯扎氯铵的含量。     

镁合金往复挤压过程的有限元模拟

运用刚粘塑性有限元法对AZ31镁合金3道次往复挤压过程进行热力耦合数值模拟,模拟分析往复挤压过程的变形规律。结果表明:往复挤压过程中,大变形区主要集中在从动冲头一侧的紧缩区中贴近凹模内壁的区域以及细颈区中贴近凹模内壁的区域;随着挤压道次的增加,变形体的累积应变明显增大;细颈区中贴近凹模内壁处以及细颈区与主动冲头一侧紧缩区的交界处应力较大;温度场分布以细颈区为中心,从高到低在变形体形成温度梯度。     

半连铸工艺对AZ31镁合金铸锭组织的影响

用传统的半连续铸造工艺制备90 mm AZ31镁合金圆柱铸锭,利用光学显微镜(OM)和扫描电镜(SEM)观察并分析不同二次冷却水量和抽坯速度对显微组织的影响规律。结果表明:铸锭内存在大量一次及较发达的二次枝晶;随着冷却水量的增加,冷却速度增大,铸锭组织逐渐变得细小均匀;当冷却水量为58 L/min时达到极值,此后组织不再明显变化。拉坯速度的变化对组织影响不大。且受二次冷却水单向导热的影响,试样的纵截面存在粗大的蔷薇状枝晶和尺寸较长的柱状晶。由于结晶器的相对高度较大,铸锭由内到外的组织有增大趋势。     

通信电源用电缆及其通信行业标准

本文重点解读通信电源用交联聚烯烃绝缘电缆通信行业标准的主要内容,介绍了交联聚烯烃绝缘的技术特点.评述了聚氯乙烯（PVC）绝缘电缆在环保和安全方面存在的不足.通过比较说明了交联聚烯烃绝缘电缆相对于PVC绝缘电缆和非交联的无卤低烟阻燃聚烯烃绝缘电缆所具有的优势.本文还介绍了低压电缆制造技术,特别是交联工艺路线、电缆料添加剂及电缆料配混技术进展等方面的内容,对未来通信电源用电缆的发展以及标准修改内容提出了建议.     

OMVPE growth of P-type GaN using solution Cp2Mg

Bis(cyclopentadienyl)magnesium (Cp₂Mg) is a common source for p-type doping in GaN and AlInGaP materials. It is a white crystalline solid with very low vapor pressure, leading to transport problems similar to solid trimethyindium (TMI). Some of these problems can be alleviated by a newly developed source-solution magnesocene, Cp₂Mg, dissolved in a solvent that is essentially nonvolatile. In this paper, we report the growth and comparative results of Mg-doped GaN grown by OMVPE using solid and solution Cp₂Mg. Using both sources, we optimized parameters to obtain high-quality GaN growth with hole concentrations up to 1 10¹⁸/cm³.