铜互连中SiCOF/a-C∶F双层低介电常数薄膜的制备和表征(英文)

用等离子体化学气相淀积系统制备了一种新颖的SiCOF/a-C∶F双层低介电常数介质薄膜,并用红外光谱表征了该薄膜的化学结构.通过测量介质的折射率发现该薄膜长时间暴露在空气中,其光频介电常数几乎不变.然而,随退火温度的增加,其光频介电常数则会减小.基于实验结果讨论了几种可能的机理.二次离子质谱分析表明在Al/a-C∶F/Si结构中F和C很容易扩散到Al中,但在Al/SiCOF/a-C∶F/Si结构中,则没有发现C的扩散,说明SiCOF充当了C扩散的阻挡层.分析还发现在SiCOF和a-C∶F之间没有明显的界面层.     

Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006     

纳米技术及其在新材料领域中的应用与展望

本文对作为21世纪高新技术之一的纳米技术进行了阐述,并对其在新材料中的应用进行了阐述和展望。     

化学镀工艺在微电子材料中的研究和应用

简要综述了化学镀工艺在微电子材料中的应用,讨论了影响化学镀镍、铜、锡、钴和贵金属等的主要因素,阐述了化学镀微电子材料的特性、存在问题及研究动态。     

湿H2S环境中金属材料腐蚀的研究

介绍了在湿H2S环境中金属材料的腐蚀试验标准、方法和手段并重点强调了在H2S试验过程中常遇到的一些问题的处理方法.最后,指出了应加强H2S腐蚀的基础性和系统性研究的研究方向.     

Preparation and properties of transparent cellulose hydrogels

Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a water‐miscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020–3025, 2003     

The Perception of a Colored Translucent Sheet on a Background

Metelli's theory of the perception of translucency models the effective reflectance of a translucent sheet on a background as a partitive mixture of the color of the sheet and the color of the background. In the achromatic case, the usable (that is, scale-invariant) rules governing the apparent reflectances are the same as those that would emerge from the Kubelka-Munk theory. For chromatic translucency, the relationships are more complex, but a set of rules still emerge from the partitive-mixture theory that are invariant to tradeoffs between illuminant and reflectances. This column sets forth the rules in the hopes that they will have graphical applications, both on computer VDUs and in hardcopy.     

用屏蔽暂堵技术封堵水平井裂缝性漏层

克拉玛依油田HW702水平井的大斜度段和水平段,将穿越纵向裂缝发育的二叠系佳木河组储层。为安全钻进和保护油层,用超细碳酸钙和磺化沥青复配后加入复合离子钻井液中成屏蔽暂堵的堵漏钻井液。室内用岩心试验,屏蔽暂堵后渗透率可降为0,暂堵深度小于3cm,可用酸化和射孔解堵。现场使用效果也很好,使HW702水平井顺利完钻,并获得工业油气流。     

反应烧结法制备MgAlON的合成机理及烧结行为的研究

通过对以Al2 O3、MgO和AlN为起始原料 ,在氮气气氛中反应烧结合成MgAlON材料合成机理的研究发现 :在 12 0 0℃以前 ,MgO与Al2 O3反应生成镁铝尖晶石 ,此后 ,随着温度的升高 ,Al2O3不断向所形成的尖晶石中固溶 ;在 130 0℃以前 ,AlN基本上不参与反应 ,而在更高的温度下 ,AlN开始向尖晶石中固溶形成MgAlON ,约在 15 5 0℃时形成单一的MgAlON相。用热膨胀仪检测了试样的线变化率随温度和时间的变化 ,用最小二乘法回归分析了试样线变化率的实验数据 ,并根据烧结理论对MgAlON材料烧结初期的动力学进行了探讨。结果表明 ,MgAlON材料烧结初期的烧结机理以体积扩散为主     

对未来我国覆铜板业技术发展的战略与任务的探讨

对未来十年我国覆铜板业技术发展的战略与技术开发重点任务进行了探讨。