Use of postconsumer polyethylene in blends with polyamide 6: Effects of the extrusion method and the compatibilizer

Blends of polyamide and high‐density polyethylene show adequate properties for a large range of applications: they are used for the production of filaments, containers, and molding resins. The effect of the addition of 2 wt % of a compatibilizer, maleic anhydride grafted polyethylene, to the blend was studied and compared to the use of postconsumer polyethylene. The samples were extruded with single‐ and twin‐screw extruders with 25, 50, or 75 wt % f polyethylene, and the test specimens, molded by injection, were characterized by stress–strain tests, thermal properties, and morphologies. Processing the blends with postconsumer polyethylene in both extruders improved the mechanical properties in comparison to the blends processed with high‐density polyethylene and the compatibilizer. The morphologies of these blends showed that there was a decrease in the domain size of the disperse phase with the use of the compatibilizer or postconsumer polyethylene. The results indicate that for this blend, postconsumer polyethylene substituted, with advantages, for the necessity of a compatibilizer and the use of the high‐density polyethylene. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008.     

Studies on jute–asphalt composites

The tensile properties of jute make it a suitable raw material for asphalt overlay (A/O) fabric. In this study, the thermal stability of jute under conditions of asphalt overlaying process was investigated and the compatibility of jute with asphalt was assessed through experimentation on jute–asphalt composites under mechanical and hygral loads. Fourier transform infra red (FTIR) spectroscopic study revealed probable chemical bonding between jute and asphalt. The test for ascertaining the capability of asphalt encasement for protecting jute against biodegradation under enzymatic attack was found positive. A 6‐month hygral treatment, of the jute–asphalt composite, showed significant increase in modulus of the material. The results indicate that although the strength of jute deteriorates by about 10% under asphalt overlaying condition, the overall tensile behavior of jute fabric–asphalt composite material is considerably superior to that of the pure jute fabric, even under biological and extended hygral loading conditions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Engineering extruded collagen fibers for biomedical applications

Extruded collagen fibers constitute a promising biomimetic scaffold for tissue engineering applications. In this study, we compared the structural, thermal, and mechanical properties of fibers produced from either NaCl or poly(ethylene glycol) with a number-average molecular weight of 8000 (PEG 8K), the only two coagents that have been used in the fabrication process. As novel, we report the fabrication of fibers with properties similar to native or synthetic fibers using other coagents. NaCl derived fibers were characterized by higher thermal stability (p < 0.026), stress (p < 0.001), and modulus (p < 0.0025) values than PEG 8K, whereas the latter yielded more extendable fibers (p < 0.012). Poly(ethylene glycol)s with number-average molecular weights of 200 and 1000 produced fibers with similar mechanical properties (p > 0.05) that were thinner (p < 0.033), stiffer (p < 0.022), and less extendable (p < 0.0002) than those of PEG 8K. Poly(vinyl alcohol) (PVA) with a number-average average molecular weight of 9–10,000 and PEG 8K yielded fibers with similar diameters and stress-at-break values (p > 0.05); however, the poly(ethylene glycol) derived fibers were more extendable (p < 0.0003), whereas the PVA fibers were stiffer (p < 0.029). Gum-arabic- and soluble-starch-derived fibers were of similar tensile strength, extendibility, and stiffness (p > 0.05). In this in vitro study, the thickest (p < 0.011) and the weakest (p < 0.0066) fibers were produced in the presence of sodium sulfate. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Evaluation of improvement of physical and mechanical properties of bamboo fibers due to alkali treatment

Bamboo strips treated with caustic solutions of different concentrations, e.g., 5%, 10%, 15%, 20%, 25%, and 50%, were subjected to mechanical testing giving stresses on tensile strength, percent elongation at break, flexural strength, flexural modulus, and toughness. The change in average density was ?15%, and the weight loss value shows a maximum of 21.94% at 50% alkali treatment. The mechanical properties of bamboo strips increase steadily with increasing concentration of caustic soda, showing a comparable increased value at 15 and 20%, and then exhibiting a gradual fall. The percent elongation at break corroborates these observations showing a continuous decreasing trend. The properties under investigation exhibit a clear transition in between 15 and 20% alkali concentration. The morphology of strips was studied by scanning electron microscope and polarizing light microscope. The crystal structure of both untreated and treated strips was compared by XRD analysis. In both cases, the breakdown of the crystal structures of the cellulose fibers and the recrystallization or reorientation of the degraded chains that are devoid of hemicellulose are quite apparent. However, at a very high concentration (to the extent of 25%) the breakdown of structure predominates much more over the reorientation or recrystallization. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis,extraction, and adsorption properties of calix[4]arene‐poly(ethylene‐glycol) crosslinked polymer

Novel calix[4]arene‐poly(ethylene glycol) crosslinked polymer (CCP) has been synthesized by the polycondensation reaction between a p‐tert‐butylcalix[4]arene derivative and dihydroxyl capped poly(ethylene glycol) (DHPEG, M_n = 1000) catalyzed by neodymium tosylate. The hydrogel, consisted of 66.9% water and 33.1% CCP, can selectively extract aromatic organic molecules from aqueous solution according to the diameter of the guest molecules, which infers that the diameter of the calix[4]arene cavity is about 5.4 Å and the conformation of calix[4]arene units altered from cone conformation to 1,3‐alternate conformation during the polycondensation reaction. Furthermore, CCP can also adsorb naphthalene from gas phase, showing much higher capacity than active carbon does, which may have some potential applications in the field of separation and environment protection. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Measuring interdiffusion at an interface between two elastomers with tapping-mode and contact-resonance atomic force microscopy imaging

Despite the common use of tapping-mode atomic force microscopy to image composites or polymer blends, very few studies have focused on the measurement of the interdiffusion at an interface between two polymers in contact. In this study, we show how to assess the interphase between two polymers with two methods. First, stable and robust tapping conditions are established, and the problem of the phase contrast is discussed. Second, a contact-resonance method is presented: the tip in contact with the sample is electrostatically excited at its resonance frequency by a self-controlled oscillator. The gain and frequency images allow us to measure the interdiffusion width. Both methods (using high and weak mechanical solicitation) give the same assessment of the interdiffusion width. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and thermomechanical characterization of polyurethane elastomers extended with α,ω‐alkane diols

A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, ¹H‐NMR, and ¹³C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Pultruded fibre reinforced polyurethane composites II. Effect of processing parameters on mechanical and thermal properties

This paper presents a novel process for the fabrication of pultruded polyurethane (PU) composites. The effects of the processing parameters on the mechanical properties (flexural strength and flexural modulus, etc.) and thermal properties (HDT) of the fibre reinforced PU composites by pultrusion have been studied. The processing parameters investigated include pulling rate (in-line speed), die temperature, filler type and content, and post-cure time and temperature. Results show that the composites possessed various optimum pulling rates at different die temperatures. On the basis of the DSC diagram, the swelling ratio, the mechanical properties and the thermal properties of composites, the optimum die temperature can be determined. It is found that the mechanical and thermal properties increase with filler content for various types of filler. The mechanical and thermal properties increase at a suitable post-cure temperature and time. Furthermore, the properties which decreased due to the degradation of composite materials for a long post-cure time will be discussed.     

浸胶工艺对Nomex蜂窝性能的影响

本文研究了浸胶工艺对Ｎｏｍｅｘ蜂窝性能的影响，分析探讨了提高Ｎｏｍｅｘ蜂窝性能及外观质量的途径。研究结果表明：采取新的浸胶工艺制作的Ｎｏｍｅｘ蜂窝，各项性能全面达到法国宇航材料标准。