乳液聚合螺旋半园管夹套反应釜

本文将螺旋半园管夹套反应釜与传统的夹套反应釜进行了对比 ,并介绍了螺旋半园管夹套釜在乳液聚合中的应用     

反应器网络综合优化方法的研究进展

反应器网络综合优化方法在选择反应器类型和反应工艺条件时,比传统的方法表现出了很大的优势。综述了各类反应器网络综合优化方法的基本原理和研究进展,并分析了它们的优缺点。这些方法有基于过程特征的方法,包括可得区法和导数分析法;超结构优化法;目标类方法,包括目标法、构造目标法和构造MINLP法;以及经验推断法和分布参数法等。最后分析了这方面研究的发展趋势。     

Spouted and spout-fluid bed combustors 1: Devolatilization and combustion of coal volatiles

The devolatilization and volatile combustion of a single coal particle in spouted and spout-fluid beds have been studied. The results showed that the flame extinction time increases with the particle diameter, and decreases with the bed temperature. When the bed temperature and the air flow rate were fixed, the operation modes (spouted or spout-fluid bed) showed less effect on the mean flame extinction time. A mathematical model of the spouted bed mode for preignition and postignition periods has also been developed assuming the devolatilization rate to be controlled by heat transfer and multireaction pyrolysis kinetics based on volatile products. Ignition, heat transfer back from the volatile flame to the particle surface, variation in flame temperature, and the hydrodynamics of SB are taken into account. The model predictions, with some adjusting parameters, were in good agreement with experimental results.     

Results of familiarization of and prospects for a procedure for the burning of wastes in a vortical fluidized bed

Problems that have arisen during tune-up of the production line for the thermal processing of solid household waste by the method of burning in a vortical fluidized bed (principally, a new technology for Russia), and means of their solution are presented. Investigative studies are cited. __________ Translated from élektricheskie Stantsii, No. 6, pp. 20–26, August, 2006.     

Modeling the continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor

A model of continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor is developed using phase equilibria assumption and the method of molecular weight moments. The model equations can be simplified into a polynomial system that has 17 equations and 17 unknowns. Solution of the polynomial system gives out almost every aspects of the continuous transesterification process. Molecular weight and polydispersity index, end group ratio of hydroxyl to phenyl carbonate, contents of molecular species, and lost diphenyl carbonate fractions are studied in different operation parameters.     

一种控制盐层段井眼闭合率的钻井液密度新公式

针对钻井过程中钻遇的盐层段井眼蠕变缩径问题,利用弹塑性力学理论,蠕变本构方程采用Heard蠕变方程,在平面应变和均匀地应力假设下,推导出控制井眼收缩的钻井液密度新公式,该公式与前人推导的公式不同。通过理论分析,指出产生差异的根本原因在于蠕变应力差(极坐标下表示的径向应力与切向应力之差)公式的推导上,用有限元法计算结果对理论公式进行检验,证明是可行的。对文中的力学模型采用有限元法建模、求解,利用求解结果对各应力差公式进行验证,得出:根据文中公式计算结果与有限元法计算结果完全一致,而据前人公式计算结果偏离有限元计算值较大,从而间接证明了该钻井液密度新公式的推导更严密,更准确。     

Decomposition of Time Series Dynamic Linear Models

This paper derives the admissible decompositions for a time series dynamic linear model, assuming only that the model is observable. The decompositions depend on factorizations of the characteristic polynomial of the state evolution matrix G into relatively prime factors. This generalizes the method of West (1997 ) which considers one decomposition in the particular case where G is diagonalizable. Conditions are derived for a decomposition to be independent. These results show that no autoregressive process of order d has an independent decomposition for any integer d . Two illustrations of this procedure are discussed in detail.     

Optimization of anodic oxidation and Cu–Cr oxide catalyst preparation on structured aluminum plates processed by electro discharge machining

This paper describes the optimization of three processes applied in fabrication of a microstructured reactor for complete oxidation of volatile organic compounds. The first process involves the optimization of the electro discharge machining (EDM) method to produce a set of microchannels with a high length to diameter ratio of 100, with a standard deviation from the average diameter below 0.2%, and with a surface roughness not higher than 2.0 μm. To satisfy these criteria, fabrication of microchannels must be carried out with two machining passes in the Al51st alloy. Then, the effect of several parameters on the anodization current efficiency with respect to oxide formation was studied. The best process conditions to get a 30 μm porous alumina layer in a 0.4 M oxalic acid electrolyte, were found to be a temperature of 1 °C, an anodic current density of 5 mA/cm², and 23 h oxidation time. At last, the resulting coatings were impregnated with an aqueous solution of copper dichromate followed by drying and calcination at 450 °C to produce active catalysts. The effect of a copper dichromate concentration, number of impregnation cycles (1 or 2), and different after-treatments on catalytic activity and stability in complete oxidation of n-butane were studied. The catalytic activity of the obtained coatings is superior to that of alumina supported pelletized catalysts even at much lower loadings of active metals.     

Spouted bed drying of cork stoppers

The spouted bed is commonly used to dry granular particles as it displays some special characteristics which render it capable of performing cyclic operations, with particles that are very difficult to fluidize under a different type of bed.Information on the characteristic drying rates of cork stoppers is still very limited in the technical and scientific literature, and until now no published data was found on the spouted bed drying of cork stoppers.The characterization of the drying performance of Port wine cork stoppers was carried out in a laboratory scale spouted bed. Characteristic drying curves were determined with 29 mm × 21 mm cork stoppers under several operating conditions. Values for the effective diffusivity were obtained in the range of 1.36 × 10⁻⁹ to 4.44 × 10⁻⁹ m²/s, with the temperature dependence represented by an Arrhenius-type relationship. The activation energy obtained was 28.72 kJ/mol.     

Transient aspects of inner wall temperatures at different spatial positions in fluidized bed evaporators

In this work, the instantaneous data of inner wall temperatures obtained at given axial positions but for different heated tubes or at various axial positions but at the same heated tube in a tube-bank fluidized bed evaporator with a vapor–liquid–solid external natural circulation flow were analyzed by employing linear and nonlinear time series analysis methods, including correlation dimension and Kolmogorov entropy analyses besides time domain, power spectrum and autocorrelation analyses. It is found that nonlinear characteristics of the wall temperature time series vary with spatial position in the evaporator at given operation conditions, and thus the multi-phase flow boiling behavior. However, the signals obtained at given axial position but different heated tubes in the evaporator exhibit more similar nonlinear evolution behavior, and those measured in the same heated tube but at different axial heights in the evaporator undergo more distinct nonlinear dynamic behavior. Multi-scale phenomena in different spatial positions are also found and discussed. These transient aspects of inner wall temperatures are closely related to the average holdup of solid particles and motion of vapor bubbles in vapor–liquid–solid flow. These results can provide some valuable information on the system modeling and controlling from the point of view of nonlinearity.