知识信息化对知识生产活动的负面影响

信息化时代凸显了信息在知识发展中的重要地位,知识只有转化为信息,才能方便地进行传播、处理和使用。但知识信息化的过程也会给知识生产活动带来一些消极影响,主要表现在：知识发展片面化可能导致知识生产缺乏创新的源动力;知识生产操作化使知识生产偏离事物的本来面目,不但可靠性难以保证,而且也很难产生重大的原始型创新,甚至还可能成为一种智力游戏和技术表演,背离了知识生产的本质;知识生产主体的异化使主体逐渐为信息所控制,也会对知识生产产生一些不利的影响。     

负氢离子释放剂对2-甲基-2-丁烯氢转移反应的影响

负氢离子转移反应是氢转移反应的基元反应,促进负氢离子转移反应可以强化选择性氢转移反应。在反应温度510 ℃、剂/油质量比5、质量空速12 h^-1、N₂气氛条件下,分别考察了四氢萘和十氢萘作为负氢离子释放剂对2-甲基-2-丁烯氢转移反应的影响。结果表明：四氢萘和十氢萘均能有效地促进2-甲基-2-丁烯发生选择性氢转移反应,产物中C₅烯烃产率由52.95%最低分别降至37.83%和17.03%,异戊烷产率由17.80%最高分别增加至42.98%和54.58%,焦炭产率由5.28%最低分别降至3.11%和2.85%;且十氢萘比四氢萘具有更好的供氢能力,相同含量的十氢萘对于产物中烯烃产率的降低幅度、异构烷烃产率和选择性的增加幅度的影响均比四氢萘更大,对焦炭产率的抑制作用更强。在含烯烃汽油中分别加入质量分数10%四氢萘和十氢萘后,烯烃产率由11.20%分别降低至5.48%和4.01%;同时能够很好地抑制焦炭的生成,尤其加入十氢萘后焦炭产率由5.30%降到2.82%。     

牵引变电所群贯通供电系统负序补偿模型及控制策略

针对牵引变电所群贯通供电系统存在的三相电压不平衡问题,提出一种基于三相变压器与静止无功发生器(SVG)的负序集中补偿方案及控制策略.首先,根据牵引变压器的功率变换关系及不同的负荷情况,推导了2种模式下补偿装置对牵引负荷的补偿功率通用表达式.根据中国的电能质量标准,提出了以负序满意补偿为目标的双限值补偿方案,方案包括了模式选择方法、SVG容量配置方法及SVG运行方法.根据补偿方案,设计了带有模式判别的SVG双闭环补偿控制策略.然后,采用牵引变电所实测数据对补偿方案进行验证,证明了方案具有良好的补偿效果,与全补偿方案相比,所提方案需要的装置容量更小.最后,通过仿真证明了控制策略对负序补偿的有效性和较快的响应速度.     

Negative ion etching of Al−Si−Cu by employing a magnetic filter in halogen plasmas

Al etching was studied employing negative ions generated in downstream Cl₂ plasma. The Al etch rate by the alternate irradiation of positive and negative ions was two times higher than that by usual positive ions. In order to etch the Al film practically on an insulator covered electrode coupled with RF power, reduction of the negative self bias voltage (Vdc) was examined using a magnetic filter which traps electrons. The reason for the high etching reactivity is that the dominant negative ions F in SF₆ and Cl⁻ in Cl₂ plasmas are atomically very similar to the radicals. Addition of SF₆ and H₂ to a Cl₂/BCl₃ mixture reduced Vdc significantly. However, fluorine and hydrogen atoms inhibited Al etching in spite of sufficient ion energy.     

Thermal expansion anomaly and spontaneous magnetostriction of Dy2AlFe14Mn2 compound

The structure and magnetic properties of Dy₂AlFe₁₄Mn₂ compound were investigated by X-ray diffractometry and magnetization measurements. Dy₂AlFe₁₄Mn₂ compound has a hexagonal Th₂Ni₁₇-type structure. Zero thermal expansion and negative thermal expansion were found in Dy₂AlFe₁₄Mn₂ compound in the temperature range from 184 to 264 K, and from 264 to 383 K, respectively, by X-ray dilatometry. The spontaneous magnetostrictive deformations from 104 to 400 K were calculated. The results show that the spontaneous volume magnetostrictive deformation increases firstly with increasing temperature, and then decreases with further increasing temperature.     

卷绕铅酸电池泡沫铅负极电化学行为的研究

以泡沫铅作为负极集流体制备了卷绕VRLA电池.采用计时电流法、循环伏安曲线、电化学阻抗谱和充放电实验研究了泡沫铅负极的电化学行为,结果表明泡沫铅负极的真实表面积比铅箔负极的大,因此泡沫铅负极具有较低的过电势,并且不论是在怎样的放电状态下,泡沫铅负极的电化学反应电阻较小;与铅箔负极相比,在10、5和2小时率放电状态下,泡沫铅负极的质量比容量分别增加25.9%,30.0%和48.2%.此外,SEM观察显示,泡沫铅负极表面活性物质为更加细小的晶体颗粒和具有更高的孔率.     

铝箔表面油斑和油粘的控制

介绍了铝箔表面产生油斑和油粘的原因。定期更换新的轧制油和严格控制添加剂的含量，制定合适的退火工艺，控制分切过程中的卷取张力和压平辊压力，在轧机出口侧加装挡油的辅助装置等措施是减少油班和油粘的有效措施。     

Performance of positive and negative electrodes in amorphous manganese oxide supercapacitor

Using potassium permanganate and acetic manganese as the reactants, amorphous manganese oxide was prepared with mechanochemical method. XRD was used for microstructure characterization, while cyclic voltammetry and constant current charge-discharge were used for electrochemical performance testing. The positive electrode （PE） and negative electrode （NE） were investigated respectively in amorphous manganese oxide supercapacitor, aiming to find their different performances in charging-discharging. The results show that the crystalline structure is destroyed in both the PE and NE material during charge-discharge process. Thereinto, the NE suffers a bit more seriously. When cycling, the PE potential scope diminishes while the NE potential scope enlarges. The increased inner resistance makes the NE curves almost bended to be a right angle, but not the PE curves. The cell＇s equivalent series resistance （ESR） is more dependent on the NE, and the capacitance is mainly determined by the rapid descent of the NE potential range. The capacitances of the NE are highly rate-dependent, decreasing from 121.3 to 53.1 F/g, by 56.2%, over the range of 5-25 mV/s. However, the PE appears to be weakly dependent and its capacitance is only dropped by 22.1%.     

HfO2膜料中的杂质对薄膜损伤及性能的影响

通过对HfO2膜料中杂质元素的分析，找出了影响薄膜性能的主要杂质元素。结果表明：金属元素、吸收性介质元素的存在对薄膜的损毁有很大负面影响；在紫外波段，Zr元素含量大的薄膜吸收较大；并且提出负离子元素在膜料蒸发过程中形成气源中心，产生喷溅，从而使薄膜的损伤阈值降低。