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41.
水合肼生产中氧化反应的研究和应用   总被引:1,自引:1,他引:1  
付永宽 《氯碱工业》2004,(12):27-30,34
分析了尿素法生产水合肼的氧化反应历程及影响因素,改进了反应器,并找到了最佳的工艺控制条件:①控制n(尿素):n(次氯酸钠)=(1.05~1.10):1,各原料的消耗较低,总经济效益佳;②采用-5℃冷冻盐水移走尿素、次氯酸钠混合段内氯化反应放出的热量,控制物料混合终点温度在15~30℃;③采用列管式加热器,将氯化反应与水解反应在不同的设备中进行,水合肼的收率提高到83%~85%;④采用列管式加热器代替双夹套反应器,提高了加热强度,生产能力大,1套合成反应器可生产1万t/a80%的水合肼。  相似文献   
42.
The degradation of p-nitrotoluene by O2/H2O2 process in a bubble contact column was investigated.Effects of the molar ratio of hydrogen peroxide to ozone, pH value and t-butanol on the oxidation process were discussed. It was found that the proper H2 O2/O3 molar ratio for the degradation of p-nitrotoluene was around O. 6, different pH values and the presence of t-butanol highly influenced the removal efficiency of p-nitrotoluene. 5-metbyl-2-nitrophenol, 2-methy1-5-nitrophenol, (4-nitrophenyl) methanol, 5-(hydroxymethyl) -2-nitro phenol, acetic acid, 2-methylpropanc diacid and 2-(hydroxylmethyl) propane diacid were identified as degradation intermediates and products through GC-MS. Radical reaction mechanism and degradation pathway were proposed based on the results of experiments. It is deduced that the benzene ring of p-nitrotoluene can be only destroyed by hydroxyl radicals through a polyhydrexy intermediate pathway. Then unstable polybydroxy intermediates can be oxidized to different acids with low molecular weight rapidly.  相似文献   
43.
Moderate or intense low oxygen dilution(MILD)combustion plays a significant role in the mitigation of combustion-generated pollutants and greenhouse gases whilst meeting thermal efficiency needs.However,due to the lack of the fundamental knowledge on this combustion,there is a misconception that MILD combustion should be established by high preheating of the air,which has limited its application.Our research and development on this combustion has been performed for several years. We have found that the requ...  相似文献   
44.
Cobalt and iron phenylthiosubstituted phthalocyanines have been deposited on Au electrode surfaces through the self-assembled monolayer (SAM) technique. The so formed layers were studied using voltammetric and impedance techniques. These SAMs blocked a number of Faradic processes and electrocatalyzed the oxidation of nitrite. The electrocatalytic parameters of the cobalt and iron phenylthiosubstituted phthalocyanines deposited on Au electrodes in nitrite solution were studied. Nitrite overpotentials which are lower than ever reported were obtained in this work for the iron phenylthiosubstituted phthalocyanines with very high stability.  相似文献   
45.
Phenomena called surface explosions have been reported for decomposition reactions on single crystals, and have been identified by the use of desorption methods. In particular, in TPD, they are manifested by extremely narrow peaks (as little as 3 K in width) and a desorption rate which increases with time in isothermal experiments. In this paper we report such observations for acetate species on Rh single crystals, but extend this to show for the first time that such effects are not restricted to single crystal/UHV experiments, but can also be found on a Rh/Al2O3 catalyst under ambient pressure conditions. These reactions can be classified as second order autocatalytic surface processes, where free surface Rh sites are an essential component of the reaction. It is shown that coadsorbed adatoms are also essential for such explosions to be seen and their role is proposed to be that of a template layer acting to order the acetate in self-poisoning configurations.  相似文献   
46.
We have studied the potential electrocatalytic activity towards the oxidation of NADH of several oxidation products of guanine and its derivative guanosine-5′-monophosphate (5′-GMP) on pyrolytic graphite electrodes (PGE). The distribution of products generated strongly depends on the experimental conditions. Our investigations focused on the oxidation products that are adsorbed on the electrode surface, are redox active and, exhibited electrocatalytic activity toward the oxidation of NADH. These compounds were electrochemically and kinetically characterized in terms of dependence of the formal potential on pH and electron transfer rate constant (ks). The voltammetric and catalytic behavior of both guanine and 5′-GMP oxidation products was compared with that of other guanine derivatives we have previously studied. Some mechanistic aspects concerning the generation of the catalysts are also discussed.  相似文献   
47.
MC(Mid-Century)催化氧化过程的研究进展   总被引:2,自引:0,他引:2  
成有为  王丽军  谢刚  李希 《化工进展》2005,24(8):837-840
介绍了MC催化氧化过程规律;从催化荆体系的改进、新型溶剂体系的开发、反应器构型和配套设施的改进、富氧氧化技术的开发等方面综述了近年来MC技术的发展;探讨了MC液相催化氧化技术应用范围的拓展以及MC液相催化氧化过程的发展方向。  相似文献   
48.
Reaction-bonded Si3N4 (RBSN) made from high-purity Si powder is unusually resistant to degradation caused by exposures to air for up to 50 h at temperatures up to 1400°C. The weight gain during oxidation of this SiH4-originating RBSN is approximately 10 times less than conventional RBSN. Contrary to normally observed strength degradations, room-temperature strengths of this high-purity, oxidized RBSN (avg = 435 MPa, max. = 668 MPa) remained at their unusually high, as-processed levels after 1000° and 1400°C oxidizing exposures. Fracture toughness values were unaffected by oxidation ( K IC= 2.3 to 2.4 MPa · m1/2). This superior oxidation resistance results from the high purity and the small diameter pore channels (0.01 to 0.06 μm) achieved in this SiH4-originating RBSN.  相似文献   
49.
SiC coatings on the surface of C-C were produced by either silicone resin impregnation/ pyrolysis or reaction sintering. Cycles of resin impregnation/pyrolysis produced an SiC coating, on the walls of fine open pores, which was effective in reducing the oxidation rate of C-C and in shifting the transition temperature to a higher value. Unless it is pre-coated with a pyrocarbon layer before sintering, plain reaction sintered SiC has oxidation behaviors similar to those of the above-mentioned SiC. The dense pyrocarbon film deposition on the surface of C-C could form a better SiC film than others. The carbon film homogenized the surface of C-C and a dense SiC film was established. The oxidation of the coated C-C can be modelled by a set of “oxidation resistors” in series and/or in parallel, with each resistor corresponding to an oxidation element. The controlling mechanism can be resolved from the activation energy. A combined resistant layer, consisting of resin impregnation, pyrocarbon film and reaction sintering SiC, showed the best oxidation resistance of any single-layer coated C-C composite.  相似文献   
50.
The effect of the temperature of gas phase CO upon the kinetics of the oxygen titration reaction: COg +Oa CO2,g, has been studied. It is found that the reaction's rate is independant of CO gas temperature between 300 and 623 K. The activation energy (6.5 kcal/mole), dependence upon CO pressure (first-order), and independence upon oxygen coverage for 0.1 o 0.4 are all independant of the CO gas phase temperature. This result rules out any Eley-Rideal type mechanism whereby CO reacts directly from the gas phase with an oxygen adatom without first being accommodated to the surface temperature in an absorbed state. The result is instead interpretable in terms of a Langmuir-Hinshelwood mechanism.Camille and Henry Dreyfus Foundation Teacher-Scholar Fellowship.  相似文献   
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