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81.
Amorphous anodic titania, stabilised by incorporation of silicon species, is shown to grow to high voltages on sputter-deposited, single-phase Ti-Si alloys during anodizing at a constant current density in ammonium pentaborate electrolyte. The films comprise two main layers, with silicon species confined to the inner layers. An amorphous-to-crystalline transition occurs at ∼60 V on the Ti-6 at.% Si alloy, while the transition is suppressed to voltages above 140 V on alloys with 12 and 26 at.% silicon. The crystalline oxide, nucleated at a depth of ∼40% of the film thickness, is associated with the presence of a precursor of crystalline oxide in the pre-existing air-formed oxide. The modified structure of the air-formed oxide due to increased incorporation of silicon species suppresses the amorphous-to-crystalline transition until the onset of dielectric breakdown. The transport numbers of cations and anions during growth of the anodic oxides are independent of the concentration of silicon species in the inner layer, despite the marked change in the field strength. 相似文献
82.
83.
Shoko Yoshikawa Toshitaka Ota Robert Newnham Ahmed Amin 《Journal of the American Ceramic Society》1990,73(2):263-267
Composite materials composed of randomly dispersed semiconducting ceramic particles in an insulating polymer matrix show a pronounced change in resistivity with pressure. Different amounts of iron oxide (Fe3 O4 ) powder and antimony-doped tin oxide (SnO2 :Sb) powder were dispersed in an epoxy polymer matrix to form pressure-sensitive composites. In each family of materials, an insulator-to-semiconductor transition is observed in agreement with percolation theory. Composites within a certain range of filler content showed substantial piezoresistive effect under both uniaxial and hydrostatic pressure in which sensitivity is controlled by the choice of filler material and the volume fraction. The effect of temperature on the piezoresistance effect was also examined. Piezoresistors made from Fe3 O4 composites showed larger temperature changes than those filled with Sb-doped SnO2 . 相似文献
84.
Ammoxidation of toluene over the perovskites YBa2Cu3O6.1, YBa2Cu2CoO6.7 and YBaCuCoO4.9 was investigated at 400 °C. At low partial pressures of O2 benzonitrile was selectively formed, while CO2 was the main product at high pressures of O2. Systematic differences in activity were observed for the three phases and are related to the crystal contents of Cu and Co. At low O2 pressures, Cu-sites are active for nitrile formation, while Co-sites give CO2. At high O2 pressures, the activity for CO2 of Cu-sites increases more than that of Co-sites due to filling of near-surface oxygen vacancies. 相似文献
85.
电石渣在环氧丙烷生产中的循环利用 总被引:1,自引:0,他引:1
总结了电石渣生产环氧丙烷工艺中的设计与应用。运行情况表明,该工艺具有明显的经济效益和社会效益。 相似文献
86.
Composites consisting of a fine-grained, polycrystalline zinc oxide matrix and <10 vol% coarse, rigid silicon carbide inclusions were prepared by the same mixing procedure and then compacted to produce samples with matrix densities of 0.45 and 0.68 of the theoretical. The samples were sintered under identical temperature profiles in separate experiments that employed either a constant rate of heating of 4°C/min or near isothermal heating at 735°C. The ratio of the densification rate of the composite matrix to the densification rate of the unreinforced zinc oxide was found to be independent of the initial matrix density. This ratio increased significantly with temperature in the constant-heating-rate experiments but was relatively constant in the isothermal experiments. The results indicate that microstructural coarsening may be an important mechanism for explaining the reduced sinterability of polycrystalline matrix composites. 相似文献
87.
Results are reported on the influence of composition and molecular mass of components on the isothermal growth rate of spherulites, on the overall kinetic rate constant, on the primary nucleation and on the thermal behaviour of poly(ethylene oxide)/poly(methyl methacrylate) blends. The growth rate of PEO spherulites as well as the observed equilibrium melting temperatures decrease, for a given Tc or ΔT, with the increase of PMMA content.Such observations are interpreted by assuming that the polymers are compatible in the undercooled melt, at least in the range of crystallization temperatures investigated. Thermodynamic quantities such as the surface free energy of folding σe and the Flory-Huggins parameter χ12 have been obtained by studying the dependence of the radial growth rate G and of the overall kinetic rate constant K from temperature and composition and the dependence of the equilibrium melting temperature depression ΔTm upon composition, respectively. 相似文献
88.
X.Y.?Wang J.M.?WangEmail author H.B.?Shao J.Q.?Zhang C.N.?Cao 《Journal of Applied Electrochemistry》2005,35(2):213-216
The corrosion behavior of pure aluminum in inhibited and uninhibited 4 MKOH was investigated by means of hydrogen collection, polarization curve measurement and electrochemical impedance spectroscopy (EIS). The results showed that the corrosion of pure aluminum was greatly inhibited by the addition of ZnO and dimethyl amine epoxy propane (designated as DE). EIS and EDAX analyses revealed that ZnO produces its effect by depositing on the aluminum surface, which increases the overpotential of hydrogen evolution. It was also found that the addition of DE could greatly improve the deposition of zinc layers. 相似文献
89.
侧链为亚乙氧基结构的EVOH梳型聚合物的合成 总被引:1,自引:0,他引:1
以乙烯-乙烯醇共聚物(EVOH)为原料,制备了一种主链为疏水的聚乙烯链段,侧链具有亚乙氧基结构的多羟基梳形聚合物,用元素分析法、凝胶渗透色谱法、核磁共振谱法对其进行了结构表征;用热重分析法和示差扫描量热法对其热学性能进行了表征。结果表明,接枝后产物的玻璃化转变温度在-52--40℃之间,熔点在55~600℃之间,由于侧链的引入破坏了EVOH的结晶,因此梳形聚合物的热分解温度比EVOH降低了约20℃。 相似文献
90.
研究了题示表面活性剂对涤纶和丙纶的抗静电性能,探讨了不同结构的脂肪族氧化胺的抗静电效果和环境湿度、上油量对其抗静电性的影响。认为:氧化胺在低湿(30%RH)条件下也能保持良好的抗静电作用;二甲基十二烷基氧化胺在同类物中的抗静电性最佳(比电阻为0.95×10~8Ω);氧化胺作丙纶油剂的抗静电组分,可提高丙纶的加工性能和成品质量;氧化胺在纤维上的上油量(0.06%)相当低时也显示了较好的抗静电作用。 相似文献