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91.
《Current Opinion in Solid State & Materials Science》2016,20(5):247-256
The important class of grain boundary (GB) complexions includes the few nanometer thick layers having composition which strongly differs from that of the abutting grains. Such GB complexions are frequently called intergranular films (IGFs) and can be observed close to the lines of wetting, prewetting and premelting complexion transitions in the bulk phase diagrams. In the majority of systems, the direct transition between complete and partial GB wetting takes place (by changing temperature, pressure, etc.). However, in certain conditions the so-called pseudopartial (or pseudoincomplete, or frustrated complete) GB wetting appears in a phase diagram between complete and partial wetting. In case of pseudopartial GB wetting, the thin GB layer of a complexion (IGF or 2-D interfacial phase) can coexist with large droplets (or particles) of the wetting phase with a non-zero dihedral (contact) angle. Thus, such IGFs can be observed in the two-phase (or multiphase) fields of bulk phase diagrams, in the broad intervals of concentrations, temperature and/or pressure. The IGFs driven by the pseudopartial GB wetting can drastically modify the properties of polycrystals. In this review, we discuss this phenomenon for the technologically important Fe–Nd–B-based hard magnetic alloys, WC–Co cemented carbides and Al-based light alloys. 相似文献
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93.
Fang Liang Jorge Lehr Lisa Danielczak Richard Leask Anne-Marie Kietzig 《International journal of molecular sciences》2014,15(8):13681-13696
Nature shows many examples of surfaces with extraordinary wettability, which can often be associated with particular air-trapping surface patterns. Here, robust non-wetting surfaces have been created by femtosecond laser ablation of polytetrafluoroethylene (PTFE). The laser-created surface structure resembles a forest of entangled fibers, which support structural superhydrophobicity even when the surface chemistry is changed by gold coating. SEM analysis showed that the degree of entanglement of hairs and the depth of the forest pattern correlates positively with accumulated laser fluence and can thus be influenced by altering various laser process parameters. The resulting fibrous surfaces exhibit a tremendous decrease in wettability compared to smooth PTFE surfaces; droplets impacting the virgin or gold coated PTFE forest do not wet the surface but bounce off. Exploratory bioadhesion experiments showed that the surfaces are truly air-trapping and do not support cell adhesion. Therewith, the created surfaces successfully mimic biological surfaces such as insect wings with robust anti-wetting behavior and potential for antiadhesive applications. In addition, the fabrication can be carried out in one process step, and our results clearly show the insensitivity of the resulting non-wetting behavior to variations in the process parameters, both of which make it a strong candidate for industrial applications. 相似文献
94.
96.
Cardamom supplementation improves inflammatory and oxidative stress biomarkers in hyperlipidemic,overweight, and obese pre‐diabetic women: a randomized double‐blind clinical trial 下载免费PDF全文
97.
Mass loss and flammability of insulation materials used in sandwich panels during the pre‐flashover phase of fire 下载免费PDF全文
A.W. Giunta d'Albani L.L. de Kluiver A.C.J. de Korte R.A.P. van Herpen R. Weewer H.J.H. Brouwers 《火与材料》2017,41(6):779-796
Nowadays, buildings contain more and more synthetic insulation materials in order to meet the increasing energy‐performance demands. These synthetic insulation materials have a different response to fire. In this study, the mass loss and flammability limits of different sandwich panels and their cores (polyurethane (PUR), polyisocyanurate (PIR) and stone wool) are studied separately by using a specially designed furnace. Expanded polystyrene and extruded polystyrene are tested on their cores only. The research has shown that the actual mass loss of synthetic and stone wool‐based cores is comparable up to 300 °C. From 300 °C onwards, the mass loss of PUR panels is significant higher. The mass losses up to 350 °C are 7%, 29% and 83% for stone wool, PIR and PUR respectively, for the influenced area. Furthermore, delamination can be observed at exposure to temperatures above 250 °C for the synthetic and 350 °C for the mineral wool panels. Delamination occurs due to the degradation of the resin between core and metal panels and the gasification of the (PUR) core. The lower flammability limits have been established experimentally at 9.2% m/m (PUR) and 3.1% m/m (PS). For PUR, an upper limit of 74% was found. For PIR and mineral wool, no flammability limits could be established. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
98.
提出PX型正压防爆电气控制柜的设计与调试,可供从事本专业人员设计调试PX型正压防爆控制柜借鉴与参考。 相似文献
99.
《Ceramics International》2022,48(2):1898-1907
AlN ceramic was successfully wetted and then joined with nonactive Sn9Zn eutectic solder assisted by ultrasonication in air. The effect of ultrasonic time on the formation of joint was studied. Results indicated that the defect-free joint can be obtained at an ultrasonic time of 5 s. Two regions, namely, AlN/Sn (s,_s) and AlN/Zn (s,_s), were found in the bonding interface. Zn and O accumulated in the AlN/Sn (s,_s) interface. An amorphous and nanocrystalline layer of ZnO formed in the hard-wet AlN surface. And Zn (s,_s) directly bonded with AlN. The low temperature and fast bonding of the AlN was attributed to the high pressure and temperature caused by cavitation effect. The shear strength of the joint increased from 10.6 MPa to 30.7 MPa when the ultrasonic treatment time increased from 5 s to 150 s. With the prolongation of ultrasonic time, more AlN ceramic particles entered the solder and acted as the reinforcing phase. 相似文献
100.
Giang T. Nguyen Ei L. Chan Takuya Tsuji Toshitsugu Tanaka Kimiaki Washino 《Advanced Powder Technology》2021,32(5):1410-1425
In this work, a resolved CFD–DEM coupling model for the simulation of gas-liquid-solid flows is developed: the interface capturing method based on the colour function is employed for fluids (i.e. a gas and liquid) whilst Discrete Element Method (DEM) is used for particles. The Volume Penalisation (VP) method is adopted to consider the hydrodynamic interactions between fluids and particles along with the Immersed Free Surface (IFS) method, which artificially extends the gas-liquid interface into the interior of the particle to account for the wettability. The unique point of the proposed model is that the thickness of the gas-liquid interface can be controlled by using both interface compression and diffuse interface techniques simultaneously. From the simulation results, it is presented that the accurate evaluation of the surface tension force as well as the capillary force can be achieved by appropriately controlling the interface thickness. Moreover, the major two methods in the literature to calculate the capillary force are compared in this work. The validity of the proposed model is presented for both static and dynamic cases. The behaviour of two colliding particles with a dynamic liquid bridge is then simulated to demonstrate the applicability of the proposed model to a complex three-phase system. 相似文献