The Effect of Polymer Optoelectronic Properties on the Performance of Multilayer Hybrid Polymer/TiO2 Solar Cells

We report a study of the effects of polymer optoelectronic properties on the performance of photovoltaic devices consisting of nanocrystalline TiO₂ and a conjugated polymer. Three different poly(2‐methoxy‐5‐(2′‐ethylhexoxy)‐1,4‐phenylenevinylene) (MEH‐PPV)‐based polymers and a fluorene–bithiophene copolymer are compared. We use photoluminescence quenching, time‐of‐flight mobility measurements, and optical spectroscopy to characterize the exciton‐transport, charge‐transport, and light‐harvesting properties, respectively, of the polymers, and correlate these material properties with photovoltaic‐device performance. We find that photocurrent is primarily limited by the photogeneration rate and by the quality of the interfaces, rather than by hole transport in the polymer. We have also studied the photovoltaic performance of these TiO₂/polymer devices as a function of the fabrication route and device design. Including a dip‐coating step before spin‐coating the polymer leads to excellent polymer penetration into highly structured TiO₂ networks, as was confirmed through transient optical measurements of the photoinduced charge‐transfer yield and recombination kinetics. Device performance is further improved for all material combinations studied, by introducing a layer of poly(ethylene dioxythiophene) (PEDOT) doped with poly(styrene sulfonic acid) (PSS) under the top contact. Optimized devices incorporating the additional dip‐coated and PEDOT:PSS layers produced a short‐circuit current density of about 1 mA cm^–2, a fill factor of 0.50, and an open‐circuit voltage of 0.86 V under simulated AM 1.5 illumination (100 mW cm^–2, 1 sun). The corresponding power conversion efficiency under 1 sun was ≥ 0.4 %.     

Head-to-head polymers: 33. Bromination of cis-1,4-polybutadiene to head-to-head poly(vinyl bromide)

Cis-1,4-polybutadiene (PB) in a 0.5% solution of a solvent mixture of dichloromethane and 1,2-dibromoethane or tetrahydrofuran was quantitatively brominated with elemental bromine at 0°C under careful exclusion of oxygen to head-to-head poly(vinyl bromide). Partially brominated PB has a structure of random or block sequences of butadiene units in the polymer depending on the bromination solvent but shows no stereospecificity in the CHBrCHBr-dyads. Partially brominated PB with block structure showed a microphase-separated morphology over a wide range of composition. Microphase separation is less pronounced for the more random structure of butadiene units. I.r and ¹³C n.m.r. spectroscopy of the partially brominated PB was used to follow the progress of the bromination.     

变风量空调系统

介绍了变风量空调系统（VAV系统）的特点、末端装置的型式以及最小送风量的确定方法，指出了VAV系统的研究重点和发展前景。     

Melting and crystallization behaviour of elastoplastic semicrystalline copolymers: poly(ether ester)

The melting and crystallization behaviour of an elastoplastic semi-crystalline poly(etherester) has been studied by differential scanning calorimetry. The shape of the melting endotherm is strongly dependent on heating rate and annealing time and results from the sum of simultaneous melting and crystallization phenomena. Samples prepared by different techniques, i.e. by solvent evaporation or by melt extrusion, behave very differently owing to specific crystal morphologies. By applying the Hoffman-Weeks plot, the equilibrium melting temperature has been extrapolated. The Avrami treatment allows the calculation of the index n and of the rate constant K from the isothermal kinetic data.     

改进的用于半导体器件综合系统的遗传算法

本文对应用于器件综合系统的遗传算法GENOCOP进行了改进.将实数设计空间根据参数的工艺精度影响转换为整型空间,并加入适应性复合算子利用已经得到的点来扩展和开发准可行空间.使其保持有效搜索到可行解的特性的同时,在同等的算法设置下,提高了对可行空间的覆盖率(约2.87倍),可以帮助设计人员更有效的设计可工作的器件.     

场发射显示器支撑墙机械强度的计算与分析

计算了几种不同材料支撑墙在不同承压和允许倾斜角度范围内的应力和形变分布。计算结果表明 ,采用热压氮化硅或氧化锆陶瓷制作的支撑墙具有足够高的机械强度 ,是支撑墙材料的较好选择。     

约束层阻尼夹芯板动态特性分析

本文给出了新的建立约束层阻尼薄板动力学模型的方法。粘弹性材料的本构关系随温度和频率变化,难以对粘弹结构进行动特性分析及控制研究,本文采用GHM方法描述弹性材料的本构关系,将粘弹性材料的动力特性描述与工程上最常用的有限元分析结合起来,建立了悬臂约束层阻尼板的动力学模型,计算了约束层阻尼夹芯悬臂板的模态参数,计算结果同其它方法相比,精度高且更接近于实验结果,同时与ANSYS5.5及NASTRAN70.7的计算结果基本一致,表明本文给出的方法是准确可靠的。     

HAT循环构成热电冷三联产总能系统的可行性分析

对国内外在提高能源利用率方面的研究现状和发展趋势进行了综述，在前人研究的基础上提出以湿空气透平湿空气透平（HAT）循环构成热、电、冷三联产总能系统的能量利用形式，详细分析了构成该系统的相关技术、可行性及需要加以解决的几个问题。     

平纹织物复合材料的弹性模量预测

利用细观力学的代表体积元(RVE)法,预测了平纹织物复合材料的弹性模量。建立了表征RVE形态的数学模型,分析了细观结构与宏观性能之间的关系,编制了从组分材料的弹性性能推测复合材料的弹性性能的预测程序。对理论预测进行了实验验证,理论值与实测值在一定误差范围内能较好吻合,说明此预测方法具有一定的可靠性。     

PLC在葛洲坝大江电厂机组辅助设备控制中的应用

PLC(可编程控制器)在机械工业和电力生产等部门应用广泛。在电力生产部门主要用于集中控制,已有较好的效果。介绍了PLC在葛洲坝水电厂机组辅助设备控制操作功能中的应用回顾及其展望。