橡胶密炼机混炼工艺瞬时功率控制法

橡胶密炼机混炼工艺瞬时功率控制法的理论由３部分组成：橡胶混炼过程的机理、密炼机流理论和混炼过程功率曲线与能量控制法不同，瞬时功率控制法实质上是控制混炼过程中胶料的粘度，确保混炼工艺过程保持最佳状态。因而瞬时功能控制法可监控生产过程，为密炼机混炼工艺的智能控制奠定了基础。     

Polynitroalcohols obtained through nitro aldol reaction between nitro oligomers and C1‐C2‐aldehydes

Polynitroalcohols (PNA) were obtained by A_N‐reaction of nitro oligomers from ground waste rubbers (NO‐GWR) with C₁‐C₂‐aldehydes in presence of organic bases triethanolamine, triethylamine and cyclopropylamine. The A_N‐reaction was studied at temperatures from 30 to 50°C, time 4 h, and NO‐GWR : aldehyde = 1 : 0.5/2.0 mass ratios in the solution. PNA were characterized by elemental analyses, such as ¹H NMR spectra, IR spectroscopy—baseline method with internal standard and thermal analyses. The quantitative functional composition of PNA (%NO₂, %C?O, and %OH groups) was proved to be similar to the composition of PNA obtained from model butadiene–styrene nitro oligomer (BSNO). It was concluded that NO‐GWR could replace NO based on elastomers in nitro aldol reaction with formaldehyde and acetaldehyde. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3241–3250, 2006     

CR／MMA乳液接枝共聚物的研制

用乳液接枝共聚法制备ＣＲ／ＭＭＡ共聚物，讨论ＣＲ乳液、引发剂、接枝温度、ＭＭＡ用量对接枝共聚转化率，接枝ＭＭＡ含量、ＭＭＡ接枝效率和粘接性能的影响，用红外光谱对接枝共聚物进行表征，该共聚物具有较好的粘接性能。     

镍系聚丁二烯橡胶生产技术进展

介绍了近几年国内外镍系顺丁橡胶生产技术的进展情况，内容涉及分子量调节技术、催化剂配置技术、节能降耗的气相聚合、本体聚合工艺及橡胶后处理过程中使用的热泵技术、螺杆挤压工艺，同时也对国内外顺丁橡胶新型防老剂的使用情况及其新品种的开发进行了简要介绍。     

聚丙烯改性技术进展

介绍了近年来聚丙烯改性技术研究方面的进展．研究内容包括用结晶成核剂对聚丙烯的晶型进行设计，用橡胶、矿物填料等对聚丙烯进行改性．     

Effect of ground rubber powder and devulcanizates on the properties of natural rubber compounds

Ground rubber powder (GRP) and devulcanized rubber (Dev.R) waste through a continuous shear‐flow reaction were used as fillers for virgin natural rubber. A Horikx plot and the gel fraction proved that both main‐chain scission and crosslink scission occurred during the devulcanization. The cure characteristics, swelling behavior, crosslink density, and mechanical properties were studied. GRP and Dev.R, generated from passenger car and light truck tires, showed applicable mechanical properties in the new rubber compounds, and the compounds containing Dev.R demonstrated better properties than those containing GRP. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 208–217, 2005     

沥青聚氨酯防水涂料的发展概述

简要介绍了沥青聚氨酯防水涂料的现状、配方设计、性能及应用,并探讨了沥青与聚氨酯的相容性问题。     

环氧氯丙烷下游产品生产现状及市场前景

论述了环氧氯丙烷的主要下游产品环氧树脂、合成甘油、氯醇橡胶等的生产现状、市场前景等,指出:我国氯碱行业应该重视这些环氧氯丙烷下游精细化工产品的开发,以促进我国环氧氯丙烷的发展。     

补强剂和共混工艺对PA/PVC/NBR三元共混弹性体性能的影响

在选择三元共聚尼龙（PA）、聚氯乙烯（PVC）、丁腈橡胶（NBR）为主体材料，制备PA／PVC／NBR（10／30／60）三元共混弹性体的工作基础上，进一步探讨了填料品种和用量，共混温度，加料顺序等因素PA／PVC／NBR三元共混弹性体的影响。试验结果表明：在PA／PVC／NBR（10／30／60）共混体系中，补强型填料的补强效果优于非补强型的填料，6种填料补强效果依次是：快压出炭黑＞半补强炭黑＞白炭黑＞活性重质，CaCO3＞陶土＞滑石粉，快压出炭黑的适宜用量是20－50份。在制备PA／PVC／NBR三元共混物时，适宜的共混温度是122－140℃，并且采用二段法混工艺制得的共混物性能优于采用一段法共混工艺。     

In vivo aging of gutta‐percha dental cone

Gutta‐percha cone is the most widely used material for root canal filling. The in vivo aging of this cone focus on the degradation of its main organic component, trans‐1,4‐polyisoprene, was studied. Aged cones (25 samples) from 2 to 30 years of root canal filling were extracted from different patients in the occasion of retreatment by mechanical way. The information about the aging time was given by the patients. Gel‐permeation chromatography (GPC) and infrared spectroscopy (FTIR) were the analytical techniques used. Polyisoprene degrades with time of aging, but in a slow process. Decrease in polymer molar mass from 5.7 × 10⁵ to 1.7 × 10⁵ g/mol was observed in polyisoprene from cone after 30 years of root canal filling and inside a noninfected tooth. In tooth with caries and periodontal infection, the decrease in molar mass is higher (4.6 × 10⁴ g/mol in cone with 10 years of aging). The production of carbonyl and hydroxyl groups in the aged material indicates that the process is oxidative, even in closed teeth. In these cases, the oxygen could be provided from tissue fluid. The degradation mechanism is complex and depends on many factors, besides time of root canal filling. The dental problem caused by the aging could be the production and migration of cytotoxic substances to periodontal ligament and the reduction on the canal sealing property due to the polymer weight loss. Both of them could contribute to the root canal treatment failure. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100:4082–4088, 2006