Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

Aperture-Adjustable and Repairable Metal-Based MOFs Catalysis Membrane for Water Purification

Precise adjustment of the pore size, damage repair, and efficient cleaning is all challenges for the wider application of inorganic membranes. This study reports a simple strategy of combining dry-wet spinning and electrosynthesis to fabricate stainless-steel metal–organic framework composite membranes characterized by customizable pore sizes, targeted reparability, and high catalytic activity for membrane cleaning. The membrane pore size can be precisely customized in the range of 14–212 nm at nanoscale, and damaged membranes can be repaired by targeted treatment in 120 s. In addition, advanced oxidation processes can be used to quickly clean the membrane and achieve 98% flux recovery. The synergistic actions of the membrane matrix and the selective layer increase the adsorption energy of active sites to oxidant, shorten the electron transfer cycle, and enhance the overall catalytic performance. This study can provide a new direction for the development of advanced membranes for water purification and high-efficiency membrane cleaning methods.     

Alternating pressure control system for hydraulic robots

Hydraulics is a promising technology for robots. However, traditional hydraulic infrastructures are often large and power-inefficient, with large power sources that hinder mobility. In contrast, electro-hydrostatic actuators are relatively power efficient, but their cost and weight can be excessive in systems with a higher number of degrees of freedom. In this paper, we propose a new alternating pressure control system for hydraulic systems with a higher number of degrees of freedom based on an alternating pressure source system. In this system, the valves open and close in synchronization with a pump with sensor feedback, allowing either pressure or position in each actuator to be controlled independently. With the proposed system, a centralized pump can be used with simplified tubing and simple on–off valves. Moreover, we developed a dynamic duty ratio system that improves performance and reduces pump utilization time. The experimental results confirmed that both the position and pressure of each actuator can be controlled in parallel on a multi-degree-of-freedom system.     

电力有源滤波器控制器的研究与仿真分析

建立了包括有源电力滤波器（ＡＰＦ）在内的公共连接点（ＰＣＣ）的数学模型;针对实际控制器计算过程中的时间延迟,提出对负载电流值进行预测的两种算法,对逆变器的开关元件提出一种新型脉宽调制（ＰＷＭ）控制方案,并采用电力电子仿真软件包进行了仿真验证。     

0.618法最优确定盘状摆动凸轮机构的最小基圆半径

在满足机构许用压力角条件下,采用０．６１８法最优确定盘状摆动凸轮机械的最小基圆半径。     

基于网络状态参数估计的主动队列管理PI改进算法

作为一种重要的主动队列管理手段,PI控制器算法通过积分嚣的引入有效地消除了队列长度控制的稳态误差,在提高网络吞吐的同时缩短了排队时延.但是PI控制器不能根据网络状态变化而自动调整控制参数,故当网络流量变化时PI控制器的收敛速度很慢.基于TCP-AQM系统模型,对经过中间节点的活动连接数、平均往返时间和前向链路容量等3个参数进行估计.通过计算击中概率的倒数,估计出活动流数;通过计算单位时间的数据包数,估计出网络容量;通过往返时延、活动流数、网络容量以及丢包概率在稳态时的关系式,估算出平均往返时延.在此基础上,提出了对网络状态变化自适应调整控制参数改进的快速收敛PI算法——FCPI算法.仿真结果表明,该算法有效提高了算法的收敛速度,并且鲁棒性好,易于实现,适用于未来高速网络的路由器.     

基于先验信息的运动物体分割与跟踪

提出一种基于先验信息的运动物体分割与跟踪算法。该算法假设帧间运动物体颜色直方图和大小等信息是相对不变的,利用动态规划思想最小化当前帧目标物体颜色直方图和大小与已知目标物体颜色直方图和大小信息的差距,从而找到较准确的目标物体轮廓。与梯度向量流算法相比,该算法对初始轮廓的鲁棒性较好,能在复杂的背景中找到物体轮廓。     

基于兴趣和信任评价的P2P语义社区模型

针对大规模网络中P2P信息共享面临的资源定位问题和“搭便车”现象,在考虑节点语义相似度、信任度和活跃强度的基础上,提出一种语义社区构建方法,提高P2P资源组织的结构性和定位准确性。建立基于信任评价的语义社区动态调整机制,以减少或消除“搭便车”的节点。     

基于C—V模型的目标检测与提取

在目标检测与提取中,传统的蛇模型和基于活动轮廓的局部区域检测方法受到初始条件或者自身的收敛性约束的影响,不仅时间花费多,而且不具备鲁棒性。本文提出一种基于C V模型的变分水平集的目标检测与提取方法,通过大量实验验证,在花费时间和鲁棒性上得到了显著的改善。