凝胶成型法制备加氢催化剂载体的研究与工业化生产

采用凝胶成型法制备加氢催化剂载体，并进行了工业放大试验。通过BET、NH3-TPD、H2-TPR等表征手段及实际的加氢反应性能评价对凝胶成型法制备的载体及加氢催化剂与常规方法进行对比分析，结果表明，采用凝胶成型法所制得的载体及催化剂均具有较高的孔体积和比表面积、较低的堆密度，其机械强度可满足工业要求，总酸量及中强酸酸量得到提升，催化剂活性组分与载体强结合力得到削弱，金属利用率提高，应用性能明显优于传统方法制备的加氢催化剂载体。通过该方法完成了加氢催化剂载体的工业生产，所生产的载体应用于天津院THDS-3加氢精制催化剂取得了良好的工业应用效果。     

基于数字机顶盒的电子选单的设计和实现

基于CATV和PSTN的VOD多媒体数字机顶盒，提出了几种实现双向通信以完成电子节目指南的设计方案，对各种方案的优缺点进行了详细的讨论，并介绍了所采用方案的实现方法。     

Nitric oxide reduction and carbon monoxide oxidation over carbon-supported copper-chromium catalysts

Carbon supported copper-chromium catalysts are shown to be very active for both the reduction of nitric oxide with carbon monoxide and the oxidation of carbon monoxide with oxygen. Mixed copper-chromium oxide active phases have good activity in the simultaneous removal of nitric oxide and carbon monoxide from exhaust gases. The influence of several catalyst variables has been investigated. The activity per volume of catalyst increases with increasing loading, while the intrinsic activity shows a maximum around C/M=100−50. An optimum catalyst for nitric oxide reduction and carbon monoxide oxidation has a copper/chromium ratio of 2/1. The apparent activation energy for the carbon monoxide oxidation over carbon supported copper-chromium catalysts is 77 kJ/mol, suggesting that the Cu---O bond rupture is the rate-limiting process. The reduction of nitric oxide takes place at higher temperatures. Since all catalysts have a low selectivity for molecular nitrogen formation at lower temperatures, the dissociation of nitric oxide is probably rate determining, resulting in a slightly reduced catalyst system. In an excess of carbon monoxide the reaction is first-order in nitric oxide and zero-order in carbon monoxide. Moisture inhibits the reaction by reversible competitive adsorption, whereas carbon dioxide does not. Oxygen completely inhibits the reduction of nitric oxide due to the more rapid reoxidation of the catalytic sites compared to nitric oxide. Therefore, the reduction of nitric oxide takes place only when all oxygen has been converted and, hence, is shifted to higher temperatures. As a possible consequence, the production of nitrous oxide is reduced. Nitric oxide and molecular oxygen react preferentially with carbon monoxide, so, in an excess of oxidizing component, gasification of the carbon support occurs at higher temperatures after carbon monoxide has been completely consumed.     

无油润滑压缩机活塞环和支承环设计

通过对填充聚四氟乙烯材料活塞环及带卸荷槽结构支承环的研究 ,确定了活塞及活塞环结构 ,建立了带卸荷槽支承环的力学分析模型 ,并将其结果用于结构尺寸的确定。在压缩机工艺指标不变的情况下 ,用该方法设计的活塞环和支承环性能优良。     

The influence of the fabrication process on the buckling of thin-walled steel box sections

Steel box sections are usually fabricated from flat plates which are welded at the corners. The welding process can introduce residual stresses and geometric imperfections into the sections which can influence their strength. For some thin-walled sections, large periodic geometric imperfections have been observed in manufactured sections. Subsequent investigations have indicated that the imperfections are in fact buckling deformations i.e. the box section has buckled due to welding residual stresses prior to any application of external load. The welding procedure and the behaviour of the box sections under load has been modelled using a finite element analysis that accounts for both geometric and material non-linearities. Tests have been carried out on box sections with a range of width to thickness ratios for the plate elements. Modelling has been shown to give good correlation with the test results. The conditions for buckling to take place as a result of the welding process have been established. A design method has been proposed.     

深基坑支护结构计算的有限元方法

针对软土地基的特性，本文提出了考虑土体抗力释放与结构模型随施工过程改变的新杆系有限元法，并 编制了求解支护结构内力与变形的计算程序，通过对事例分析．计算结果与实际情况非常吻合，证明了该方法的合理 性。     

Information systems and uncertainty: a conspiracy of misplaced confidence

Abstract. Information technology is becoming an increasingly important factor in contemporary management. Information systems are being set up in business explicitly to accommodate the new opportunities of this technology, and these are having a lasting effect on managerial practice. The full implications of this technology-driven development have not been appreciated by organizations, which in absorbing technological systems, are tolerating a great drain on their resources.
The efficacy of computers is predicated on the acceptance of some very specific perspectives. A growing discontent and disappointment with their limited achievements is our reason for advocating a different point of view. We will discuss how a shift in perspective, particularly in respect to the perception of uncertainty, will affect thinking and practice in the field of management support systems. We will render our view of the application of computerized decision support systems (DSS), and especially, we will focus on the beliefs and assumptions that have shaped this technology thus far. To this end we will discuss the concept of uncertainty, by juxtaposing current thinking and practice with our understanding of the context of its application. Finally, we will place our understanding of uncertainty in a managerial context and explain the implications this would have for strategists.     

Pruning Redundant Alarm Correlation Patterns

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化工软测量技术研究进展

详细说明了软测量技术的含义以及软测量系统的组成。在此基础上，介绍了软测量技术中基于机理分析建模、应用状态观测器建模、应用统计分析建模、神经元网络、模糊技术、以及支持向量机的智能建模等软测量建模理论方法和最新研究成果，之后介绍了小波分析、推断控制算法在软测量数据处理中的应用，最后介绍了基于虚拟仪器开发平台的软测量系统实现技术。     

Immobilization and activation of vanadium(III) and titanium(III) single‐site catalysts for ethylene polymerization using MgCl2‐based supports

Significant increases in the activity of vanadium(III) amidinate catalysts for ethylene polymerization have been obtained by immobilization on a MgCl₂‐based support prepared by reaction of AlEt₃ with a MgCl₂/ethanol adduct. Catalyst immobilization and activation on this type of support prevents the rapid decay in activity observed under homogeneous polymerization conditions with unsupported catalysts. Stable polymerization activity is also observed with analogous titanium(III) complexes. Polyethylene with narrow molecular weight distribution and spherical particle morphology is obtained without reactor fouling. Copyright © 2005 Society of Chemical Industry