Influences of zinc oxide and an organic additive on the electrochemical behavior of pure aluminum in an alkaline solution

The corrosion behavior of pure aluminum in inhibited and uninhibited 4 MKOH was investigated by means of hydrogen collection, polarization curve measurement and electrochemical impedance spectroscopy (EIS). The results showed that the corrosion of pure aluminum was greatly inhibited by the addition of ZnO and dimethyl amine epoxy propane (designated as DE). EIS and EDAX analyses revealed that ZnO produces its effect by depositing on the aluminum surface, which increases the overpotential of hydrogen evolution. It was also found that the addition of DE could greatly improve the deposition of zinc layers.     

酸性镀锡液的新进展

从近几年美国发明专利的角度扼要综述酸性镀锡液的新进展。说明酸性镀锡液由氟硼酸盐型发展为烷基磺酸盐型的改进过程。列出参考文献９篇。     

Diffusion of lignin macromolecules within the fibre walls of kraft pulp. Part I: Determination of the diffusion coefficient under alkaline conditions

The intrinsic rate of diffusion of soluble lignin from fibre walls to bulk liquor has never been determined previously because of experimental difficulties; for example, the diffusion rate determined in a stirred cell is affected by the mechanical action of stirring. In our work, the intrinsic rate of diffusion of lignin macromolecules from the fibre walls of a softwood kraft pulp was determined under alkaline conditions using a displacement cell which eliminated external heat and mass transfer resistances and pulp fibre disturbances. The effects of such experimental conditions as pulp bed height and liquid flow rate were studied. The diffusion rate can be described by a diffusion model for a hollow cylinder with a very wide range of diffusion coefficients. The diffusion rate increased with increasing pH. Our results provide a new understanding of the lignin diffusion process in fibre walls, which is affected by the size of lignin molecules and the pores, and by the electrostatic interactions between intrafibre pore walls and lignin.     

GRAPHICAL SOLUTION OF MULTISTAGE FLUIDIZED BED HEAT EXCHANGER

The design of multistage fluidized beds for heat exchange necessitates the solution of the mass and energy balance equations combined with the equilibrium relations for each stage. This paper presents a novel way of applying well known methodology to a different technology, one where it has not been widely applied.

In the present work a McCabe-Thiele type of graphical approach is presented for both counter-current and cross-current contacting multiple fluidized beds. The necessary equations for a multistage calciner are developed and the application of the proposed method is demonstrated. Generalized fluidized bed efficiency for counter-current and cross-current multiple fluidized bed is presented.     

工业纯铝在模拟海水中的电化学腐蚀行为

为研究铝在海水中的腐蚀过程,采用电化学阻抗谱、浸泡试验、扫描电子显微镜研究工业纯铝在模拟海水中的腐蚀行为.结果表明:铝在模拟海水中发生点蚀的区域为富含Fe的晶间化合物处,点蚀半径随时间的增加而扩大.铝在模拟海水中的溶解曲线分为4个区间:活性溶解区、过渡区、过钝化区、钝化区.铝在模拟海水中,极化电位为过钝化区时,转移电阻R t随着电位的升高而变小,铝发生严重的点蚀;而极化电位为钝化区时,铝的转移电阻R t随着电位的升高基本不变,铝的溶解行为受到抑制.工业纯铝在模拟海水中发生点蚀的电位区间是-0.45～-0.65 V,钝化电位区间为-0.75～-0.85 V.     

型钢翼缘狗骨式削弱在型钢混凝土节点的作用

为了防止地震时型钢混凝土节点核心区发生剪切破坏以及梁柱连接焊缝发生脆性断裂,提出对型钢混凝土节点核心区附近梁端型钢的上、下翼缘采取狗骨式削弱,并系统研究翼缘削弱对提高型钢混凝土节点抗震性能的作用.研究表明,由于在梁端型钢翼缘采取狗骨式削弱,不仅能够将塑性铰控制在梁型钢削弱的位置,从而有效地降低了节点核心区所受的剪力以及梁柱连接焊缝的应力;而且能够改善节点塑性铰区的转动能力和抗剪性能,提高节点的延性和耗能能力.     

双洞口配筋砌块砌体框支墙梁试验

为研究双洞口配筋砌块砌体框支墙梁地震前后的受力模式,在拟动力子试验前后进行了底层框架配筋砌块短肢砌体剪力墙结构三层足尺模型的竖向力静载试验.试验结果表明:托梁与上部墙体表现出良好的协同工作能力,其工作模式为拉杆拱.通过对其在拟动力试验前后的受力模式进行了比较,可知带洞口配筋砌块砌体框支墙梁结构体系在墙体受到一定损伤时,并不会使墙梁的受力机理发生明显改变.     

CFRP加固钢筋混凝土梁滞后应变计算方法

为了系统研究从零负载状态到满负载状态各个阶段CFRP片材加固梁滞后应变的计算方法,在充分考虑加固梁不同负载状态及受压区混凝土非线性本构关系的基础上,分别建立了不同负载贴片加固梁考虑混凝土抗拉作用时的滞后应变计算公式及不考虑混凝土抗拉作用时的简化计算公式.试验数据和对比分析结果表明:"考虑混凝土抗拉作用"公式的计算结果与试验数据吻合良好,计算误差<8%,明显优于现有文献的计算方法;"不考虑受拉区混凝土抗拉作用"公式的计算结果在混凝土开裂前和试验值相差较大,但对已裂加固梁的计算误差与"考虑混凝土抗拉作用"公式的计算误差接近.为简化计算,对未裂和已裂混凝土梁贴片加固时的滞后应变可分别采用"换算截面"公式和"不考虑混凝土抗拉作用"公式进行计算,两种简化方法的误差均不会超过10%.