Unperturbed dimension of poly(4-acetoxystyrene) measured in good and theta solvents

In order to obtain the additional data concerning the unperturbed dimension of poly-4-substituted styrene, light scattering measurements are performed on the twenty-two fractions with molecular weight of (0.91–352)·10⁴ of poly(4-acetoxystyrene) in dioxan at 25°C, from which the molecular weight obtained was found easily to be evaluated with the gel permeation chromatography using THF. Phase separation experiments for this polymer indicate that the theta state is attained in isopropyl acetate at 19.7°C and butyl acetate at 26.8°C. By making viscosity measurements at that state, the value of K_Θ is directly evaluated as 5.4·10^?4 dl g^?1. The limiting viscosity number is also obtained in good solvents, THF and dioxan, at 25°C and constants of the Mark-Houwink-Sakurada equation in each solvent are determined. Further, approximately the same K_Θ as above is obtained from these data with the Stockmayer-Fixman plot. The calculated value of steric factor, 2.37, on this polymer may be plausible, compared with those of polyvinylaromatic derivatives.     

纺丝组件漏浆原因分析

通过对纺丝组件工艺对比调试,分析了纺丝组件消耗材料对纺丝组件漏浆的影响,指出了纺丝组件漏浆的主要影响因素。     

螺旋焊管内涂层涂敷挥发份的清除

针对大口径螺旋焊管内涂层涂敷作业时，钢管内残留的涂料挥发份如何清除的问题，介绍了一种自行设计制造的内涂层涂敷挥发份吹除装置。     

广州抽水蓄能电站厂区消防设计述评

广州抽水蓄能电站是我国第一座高水头，大容量的抽水蓄能电站，该电站按无人值班设计，为此对火灾探测和消防报警以在动灭火系统的自动化程序和可靠性比常规电站有更高的要求，本文重点介绍法国CEGELEG（集团）公司消防设计特点，并对设计中存在的主要问题进行了分析。     

Pruning Redundant Alarm Correlation Patterns

1　ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｓｔｉｃｋｉｎｇｐｏｉｎｔｏｆａｓｓｏｃｉａｔｉｏｎｒｕｌｅａｌｇｏｒｉｔｈｍｓｄｅｐｅｎｄｓｏｎｅｆｆｅｃｔｉｖｅｌｙｆｉｎｄｉｎｇａｌｌｃｏｒｒｅｌａｔｉｏｎｐａｔｔｅｒｎｓｔｈａｔｓａｔｉｓｆｙｖａｌｕｅｒｅｑｕｉｒｅｍｅｎｔｉｎｔｈｅｍａｇｎａｎｉｍｉｔｙｏｆｄａｔａ.Ｂｕｔｔｈｅａｌｇｏｒｉｔｈｍｓａｌｓｏｂｒｉｎｇａｎｅｇａｔｉｖｅｅｆ ｆｅｃｔ:ｔｈｅｎｕｍｂｅｒｏｆａｓｓｏｃｉａｔｉｏｎｒｕｌｅｓｉｓｖｅｒｙｌａｒｇｅ.Ａｌｓｏｉｎｆｏｒｍａｔｉｏｎ…     

A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry     

基于DMF捕获系统频率选择性信道下捕获性能的分析

对基于数字匹配滤波器(DMF)捕获系统在频率选择性信道下的捕获性能进行了深入讨论，利用状态转移图推导出单次驻留判决方式时平均捕获时间的表达式，对平均捕获时间与多径分量的关系进行了数字分析。得出的主要结论是：对于多径分量为非衰落信号时，多径分量之间的能量差别越大，系统捕获性能越好，多径分量的能量相等时，系统捕获性能最差，且随着可以分离的多径路数的增加下降；对于多径分量为慢衰落信号时，多径信道的捕获性能好于单径信道(非频率选择性衰落信道)，且多径分量之间的能量差别越大，系统捕获性能越差，当多径分量的能量相等时，捕获性能最好，这与非衰落信道的情形相反。因此在频率选择性衰落信道中，采用分集接收可以改善系统的捕获性能。     

VRDS装置常压分馏塔系统的问题分析

胜利炼油厂重油加氢 (VRDS)装置的常压分馏塔为填料塔 ,2 0 0 1年检修开工后该系统出现异常 ,经过查找分析 ,确定轻烃 /产品减压渣油换热器和柴油汽提塔重沸器内漏是装置异常的主要原因     

Preparation of glucose oxidase immobilized in different carriers using radiation polymerization

Glucose oxidase (EC 1.1.3.4) was immobilized on different polymeric materials using different immobilization techniques (entrapping by γ‐irradiation, and covalent binding using epichlorohydrin). Studies were carried out to increase the thermal stability of glucose oxidase (GOD) for different applications. The activity and stability of the resulting biopolymers have been compared with those of free GOD. The effect of different polyvinyl alcohol/polyacrylamide (PVA/PAAm) compositions of the copolymer carrier on the enzymatic activity of the immobilized GOD was studied. The maximum enzymatic activity was obtained with the composition ratio of PVA/PAAm of 60:40. The behaviour of the free and immobilized enzyme was analysed as a function of pH. A broadening in the pH profile (5.5–8) was observed for immobilized preparations. The activity and stability of the resulting biopolymers produced by immobilization of GOD onto different carriers have been compared, in both aqueous and organic media, with those of the free GOD. The enzyme's tolerance toward both heat and organic solvent was enhanced by immobilization onto polymers. The addition of different concentrations of organic solvents (10–50%, v/v) to the enzyme at higher temperature (60 °C) was found to stabilize the enzyme molecule. The strongest stabilizing effect on the enzymatic activity was achieved at a concentration of 10%. Copyright © 2005 Society of Chemical Industry     

Separation of di- and tripeptides with solvent extraction and an emulsion liquid membrane

The extraction equilibria of various di- and tripeptides with di-2-ethylhexylphosphoric acid (D2EHPA) were studied at low pH values. The complex extracted to organic phase consisted of one molecule of peptide and two molecules of D2EHPA dimer. The extraction constants of the peptides correlated well with the distribution coefficients of peptides between 1-octanol and water, which is a measure of hydrophobicity. The permeation rates of peptides through an emulsion liquid membrane were examined by using D2EHPA as a carrier, Span 80 as an emulsifier and kerosene as a diluent. The rates varied considerably with peptide type, depending upon the hydrophobicity.