Electron beam irradiation of ethylene‐propylene terpolymer: Evaluation of trimethylol propane trimethacrylate as a crosslink promoter

The effect of electron beam irradiation on ethylene‐propylene terpolymer (EPDM) was investigated. A 50‐part oil‐extended EPDM with high termonomer (ENB) content (iodine number of base polymer) 19, was selected for this study. An increase in irradiation dose from 0 to 200 kGy resulted in increased crosslinking, measured by an increase in gel contents and better swelling resistance. The effect of the multifunctional monomer trimethylol propane trimethacrylate (TMPTMA) as a crosslink promoter was studied using IR spectroscopy. The IR studies revealed enhanced peak absorbances at 1725, 1257, and 1023 cm^?1 as a result of the increased concentration of C = O and C‐O‐C groups and reduced absorbance at 1630 cm^?1 due decreased concentration of C = C groups with TMPTMA level in the irradiated samples. The presence of TMPTMA increased the level of crosslinking at a given irradiation dose, which was manifested by improvement in tensile properties. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 968–975, 2005     

低熔点合金填充聚合物材料断口形貌研究

研究了合金元素、加工温度、金属含量、第三组分对低熔点金属填充聚合物材料断口形貌的影响。实验结果表明:不同的合金对体系的影响很大,低分子量、低结晶性聚合物,高的成型加工温度可提高材料的相容性。     

多CPU控制器在大功率整流控制系统中的应用

介绍了利用多CPU来设计整流控制器，解决大功率整流装置产生的磁场对整流计算机控制系统产生的干扰。     

Influence of untreated and novel electron‐beam‐modified surface‐coated silica filler on the thermorheological properties of ethylene–octene copolymer

We developed surface‐modified silica fillers by coating these with an acrylate monomer, trimethylolpropane triacrylate, or a silane coupling agent, triethoxyvinyl silane, followed by electron‐beam irradiation at room temperature. These were incorporated in an ethylene–octene copolymer rubber. Thermorheological studies of the unvulcanized ethylene–octene copolymer and its untreated and modified silica‐filled composites were done with a shear dynamic oscillating rheometer. Modification of the silica filler, especially via the silanization process followed by electron beam treatment, significantly reduced filler–filler networking as revealed from the log–log plots of storage modulus and complex shear viscosity, and its real component. The rheological complexity of the compositions was analyzed from a double logarithmic plot of the storage modulus and loss modulus. The results obtained from the master curves constructed on the basis of the time–temperature superposition principle and the activation energy calculated from the Arrhenius equation for the flow of above these compounds further supported these findings. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2453–2459, 2003     

我公司进行热电联产的可行性分析

大压差减温减压是能的严重贬值。根据公司供热现状，分析了热电联产的可行性，利用蒸汽余压发电后，再供生产系统各热用户，这样既节约了能源又缓解了集团公司用电紧张的局面，而且有相当可观的经济效益。     

大型常压锥顶贮罐的设计

以工程实例为依据，论述国内以往较少采用的大型梁柱式支承锥顶贮罐的结构，介绍了国内外相关设计标准，给出了贮罐的典型结构－斜椽，横梁和立柱的计算公式，并用Excel电子表格编制了计算书。     

Molecular motions of non-crystalline poly(aryl ether-ether-ketone) PEEK and influence of elecron beam irradiation

The dynamic mechanical relaxation of non-crystalline poly(aryl ether-ether-ketone) PEEK and the one irradiated with electron beam were studied. The three distinct γ, β, α′ relaxation maxima were observed in unirradiated PEEK from low to high temperature. It was revealed from the study on the irradiation effects that three different molecular processes are overlapped in γ relaxation peak, i.e., molecular motion of water bound to main chain (peak temperature; at ?100°C), local motion of main chain (at ?80°C), and local mode of the aligned and/or oriented moiety (at ?40°C). The β relaxation connected with the glass transition occurred at 150°C and it shifted to higher temperature by irradiation. The α′ relaxation which can be attributed to rearrangement of molecular chain due to crystallization was observed in unirradiated PEEK ～ 180°C and its magnitude decreased with the increase in irradiation dose. This effect indicates the formation of structures inhibiting crystallization such as crosslinking and/or short branching during irradiation. A new relaxation, β′, appeared in the temperature range of 40° to 100°C by irradiation and its magnitude increased with dose. This relaxation was attributed to rearrangement of molecular chain from loosened packing around chain ends, which were introduced into the non-crystalline region by chain scission under irradiation, to more rigid molecular packing, From these observations, we proposed that deterioration in mechanical properties of non-crystalline PEEK by high energy electron beam was brought about not only by chain scission but structural changes such as crosslinking and/or branching in the main chain.     

双向搜索多约束路由启发式计算方法

为提高大型通信网络中搜索满足多约束条件路由的速度,提出一种双向搜索路由的计算方法.首先从源和目的节点同时出发,计算到达各中间节点的可达路径.然后在各可达路径中进行路径的筛选.可达路径是采用邻接矩阵变换方式获得的,筛选路径是根据非线性开销函数,采用启发方式择优选取.当两方向搜索的节点数累计达到n-2后,对接合并两方向到达中间节点的路径,从中再选择最佳路径作为路由输出.通过算例详细介绍了可达路径计算及启发式选优方法.阐述了算法的正确性及特点,分析了最大时间杂性.通过仿真实验评估,不仅更进一步验证了新算法的正确性,而且表明新算法在搜索路由速度上要优于其他算法.     

双洞口配筋砌块砌体框支墙梁试验

为研究双洞口配筋砌块砌体框支墙梁地震前后的受力模式,在拟动力子试验前后进行了底层框架配筋砌块短肢砌体剪力墙结构三层足尺模型的竖向力静载试验.试验结果表明:托梁与上部墙体表现出良好的协同工作能力,其工作模式为拉杆拱.通过对其在拟动力试验前后的受力模式进行了比较,可知带洞口配筋砌块砌体框支墙梁结构体系在墙体受到一定损伤时,并不会使墙梁的受力机理发生明显改变.     

CFRP加固钢筋混凝土梁滞后应变计算方法

为了系统研究从零负载状态到满负载状态各个阶段CFRP片材加固梁滞后应变的计算方法,在充分考虑加固梁不同负载状态及受压区混凝土非线性本构关系的基础上,分别建立了不同负载贴片加固梁考虑混凝土抗拉作用时的滞后应变计算公式及不考虑混凝土抗拉作用时的简化计算公式.试验数据和对比分析结果表明:"考虑混凝土抗拉作用"公式的计算结果与试验数据吻合良好,计算误差<8%,明显优于现有文献的计算方法;"不考虑受拉区混凝土抗拉作用"公式的计算结果在混凝土开裂前和试验值相差较大,但对已裂加固梁的计算误差与"考虑混凝土抗拉作用"公式的计算误差接近.为简化计算,对未裂和已裂混凝土梁贴片加固时的滞后应变可分别采用"换算截面"公式和"不考虑混凝土抗拉作用"公式进行计算,两种简化方法的误差均不会超过10%.