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21.
The effects of α‐form and β‐form nuclei on polymorphic morphology of poly(butylene adipate) (PBA) upon recrystallization from the molten state up to various Tmax values were examined by differential scanning calorimetry (DSC), wide‐angle X‐ray diffraction (WAXD) and polarized light microscopy (PLM). In this study, PBA with complex melting and polymorphism behaviour was used as a model for examining different types and extents of residual nuclei. As the PBA initially containing the sole α‐crystal was brought to a molten state of various Tmax, the extents of trace α‐form crystal nuclei varied and were dependent on Tmax. Furthermore, it did not matter whether, initially, the PBA contained α‐ or β‐form crystals (or both) because only a single type of α‐nuclei could be left upon treatment to the molten liquid state at Tmax. Therefore, only the α‐crystal in PBA had ‘memory capacity’ in the molten liquid state while the β‐crystal did not. This was so because the latter had been completely transformed into the solid state prior to being heated into a liquid. PBA crystallized before α‐nuclei could be packed into α‐crystal, regardless of the crystallization temperature (Tc). For recrystallization from molten PBA without any nuclei, the crystalline polymorphism was correspondingly influenced by Tc. Copyright © 2005 Society of Chemical Industry 相似文献
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Yu. S. Yakovlev 《Cybernetics and Systems Analysis》2003,39(5):765-776
Distinctive features of architectural-structural organization and use of memory networks are considered with the aim of choosing an optimal configuration in designing distributed computer systems. 相似文献
25.
J.H Xiang 《Corrosion Science》2004,46(8):2025-2039
The oxidation of the ternary alloys Ni-45Cu-10Al and Ni-30Cu-10Al has been studied at 800-900 °C under 1 atm O2. The presence of 10 at.% Al reduces significantly the oxidation rate of the corresponding Cu-Ni alloys during the initial oxidation stages, even before the establishment of a complete Al2O3 layer. The weight of individual sample of the two ternary Ni-Cu-10Al alloys at 800 °C increases more rapidly than at 900 °C during the initial oxidation stage. As oxidation proceeds, the weight gain at 800 °C slows down to a degree that the total weight gain after 24 h oxidation at 800 °C is less than that at 900 °C. Due to a faster formation of the Al2O3 layer, which suppresses earlier the further oxidation of Cu and Ni, the external region of the scales grown on Ni-45Cu-10Al contain much less Cu and Ni oxides than those grown on Ni-30Cu-10Al. The transition from the internal oxidation to the selective external oxidation of the most reactive component Al in Ni-Cu-Al alloys is favored by higher values of the Al content, of temperature and of the Cu/Ni ratio. 相似文献
26.
沈国金 《武汉理工大学学报(信息与管理工程版)》2006,28(8):139-142
针对目前大学生职业规划效果不佳的现状,分析了导致大学生职业规划效果不佳的原因,提出了增强大学生职业规划效果的宏观对策。 相似文献
27.
An analytical method is presented for calculating the resonant frequency andQ-factor of a superconducting dielectric disk resonator operating in millimeter-wave regime with whispering-gallery mode. Resonant frequency shift due to the optical generation of quasi-particles in superconducting film is investigated as a function of photon flux. An optically tunable resonant frequency of about 500 MHz is estimated, and good agreement is found between numerical results and experimental ones. 相似文献
28.
《Drying Technology》2007,25(3):475-481
A method to minimize twist has been investigated; i.e., drying the boards in a pre-twisted position. It has been found that Norway spruce boards can be deformed toward straightness by this method. The force exerted by a board on its holders during drying in a pre-twisted position has been measured. When the variation in torsional stiffness as a function of temperature and moisture content is accounted for, it is found that a creep deformation of the board occurs both during the drying phase and the cooling phase. In addition to mechano-sorptive creep, a deformation released by a change in temperature also seems to occur. 相似文献
29.
对不同能量、不同质量数、不同初始条件的入射束和有无空间电荷效应的离子束流在高梯度加速管中的传输进行了计算,并讨论了一些影响加速管聚焦作用的主要因素,计算结果与实际情况相符。 相似文献
30.
A modified CIECAM02 colour appearance model, named CIECAM02‐m2, is proposed to enable CIECAM02 to predict the simultaneous contrast effect. The structure of the CIECAM02‐m2 is a development from CIECAM02, and contains two different procedures for modifying the reference white; one is for lightness and the other is for hue. The model was tested using a data set accumulated in this study and the LUTCHI data. The CV values for three colour attributes between predictions and experimental data were used to evaluate the accuracy of the model. The low CV values obtained show the performance of the CIECAM02‐m2 model to predict the simultaneous contrast effect satisfactorily. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 121 – 129, 2007 相似文献