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21.
ˮ�ཬ������������Ƽ�����Ľ�������о� 总被引:2,自引:1,他引:1
解决注水泥作业的防气窜问题,是提高固井质量,保护油气层的关键技术。现有预测和防止水泥浆气管理的方法虽然较多,但应用于现场却有一定困难,主要表现在所考虑的因素比较单一,有些高温、高压下的水泥浆性能参数难以测定。文章在分析国内外预测和防止气窜方法的基础上,应用水泥浆浆体在环空的组成,GFP系数、水泥浆稠度阻力系数(A)及多凝水泥和环空加压等措施,拟定出一套提高水泥浆顶替效率,保证水泥浆动态和静态过程压力平衡关系的具体设计方法。 相似文献
22.
本文给出轴对称问题线元上高次分布源和偶极在无界域中的诱导速度势和诱导速度的计算公式,可供用分布奇点法求解轴对称势流问题时参考. 相似文献
23.
Adsorption and inhibitive properties of benzimidazole derivatives in acid mild steel corrosion 总被引:1,自引:0,他引:1
Eight diazoles were investigated as corrosion inhibitors of mild steel in 1 M hydrochloric acid using gravimetric and polarization techniques. It was found that the inhibition efficiency increased with the increase of organic substrate concentration, while the adsorption followed the Frumkin isotherm. A correlation between the electronic parameters (induction and mesomeric effects of the substituents, ionization potential values) as well as those of the chemical structure (molecular area) of diazoles molecules and their inhibiting properties was looked for. The results obtained show that a definite interdependence exists but it is not as simple and straightforward as might be expected. 相似文献
24.
Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a water‐miscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020–3025, 2003 相似文献
25.
Hamid Javaherian Naghash Ahmad Reza Momeni Hamid Alian Ahmad Reza Massah Shahla Ataie 《Polymer International》2005,54(11):1564-1571
Poly(methyl methacrylate) (PMMA) gels with varying amounts of silicone and solvent and constant amounts of crosslinker were prepared by solution free radical crosslinking copolymerization of methyl methacrylate (MMA), ethylene glycol dimethacrylate (EGDM), tetraethoxysilane (TEOS) and vinyltriethoxysilane (VTES) comonomer systems. They were then studied in benzene at a total monomer concentration of 3.5 mol L?1 and 70 °C. The conversion of monomer, volume swelling ratio, weight fraction and gel point were measured as a function of the reaction time, silicone concentration and benzene content up to the onset of macrogelation. Structural characteristics of the gels were examined by using equilibrium swelling in benzene, gel fraction and Fourier‐transform infrared (FTIR) analysis. The morphology of the copolymers was also investigated by SEM. Based on the obtained results, it was concluded that the FTIR data did not have the capacity to show the presence of the VTES or TEOS moiety in these kinds of copolymers. On the other hand, the variation of weight fraction of gel, Wg, and its equilibrium volume swelling ratio in benzene, qv, exhibited the same behaviour as that of MMA/EGDM copolymers. Also, the dilution of the monomer mixture resulted in an increase in the gel point and swelling degree and a decrease in the percent of conversion and gel fraction. Finally, TEOS is not an ideal silicone compound for reaction in the MMA/EGDM copolymerization system, whereas VTES is a suitable silicone comonomer for this system and it has been proved useful. Copyright © 2005 Society of Chemical Industry 相似文献
26.
准噶尔盆地三台-北三台地区第三系勘探潜力分析 总被引:1,自引:0,他引:1
从沉积及储层组合、油气运移系统等方面全面剖析了准噶尔盆地三台-北三台地区第三系油气成藏条件,建立了成藏模式,对未钻探区勘探潜力进行了预测;通过分析,认为该区第三系储层物性主体差,断裂更多地表现为封闭性,导致沟通深部油气源的运移体系不畅,致使第三系圈闭不能有效捕获和储集油气。圈闭又比较匮乏,主体勘探潜力不大。北25井西背斜紧邻多期活动的甘诃子北断裂,第三系可能发育较好的储层,相对有利,北25井西背斜应是钻探第三系的首选目标。 相似文献
27.
In this study, the diffusion of various types of solvent in oil palm empty fruit bunch/polyurethane composites, produced from chemically modified empty fruit bunches, was investigated. The solubility parameters and polymer–solvent interaction parameters of the produced composites were determined. The void contents of the composites were also determined before swelling tests to eliminate the free solvent present in the system. From the results obtained, we found that the diffusion of the solvents was dependent on the compatible group available and the voids present in the system. The solubility parameters of the empty fruit bunch/polyurethane composites with different degrees of chemical modification were 11.6 and 11.7 (cal/cm?3)1/2. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
28.
The swelling kinetics curves of structurally defined poly(acrylic acid) hydrogel in bidistilled water at temperatures: 25, 30, 35, 40, and 45°C were determined. The possibility of kinetically explaining the isothermal swelling process by applying the following models: reaction controlled by diffusion, first order chemical reaction kinetics, and second order chemical reaction kinetics, was investigated. It was found that kinetically explaining the swelling process using these methods was limited to only certain parts of the process. The swelling process in bidistilled water was described in full range assuming that the hydrogel's swelling rate was a kinetically controlled reaction by the rate of the movement of reactive interface of hydrogel. Based on that model, the kinetic parameters, activation energy (Ea) and preexponential factor (A), of the swelling process were determined to be Ea = 35 kJ/mol and lnA = 8.6. A possible mechanism of the investigated swelling process was discussed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
29.
Han‐Lang Wu Chen‐Chi M. Ma Chun‐Chieh Lin Yie‐Chan Chiu Chih‐Yuan Chen Chin‐Lung Chiang 《应用聚合物科学杂志》2008,107(5):3236-3243
Poly(arylene ether benzonitrile) (PAEBN) was synthesized with 2,6‐dichlorobenzonitrile and biphenol. PAEBNs with various molecular weights (MWs), 1,640,000 and 185,000 g/mol, were synthesized by control of the stoichiometry of the monomers and were blended with sulfonated poly(ether ether ketone) (SPEEK). The effects of MW on the water uptake, swelling, methanol permeability, and proton conductivity of the SPEEK/PAEBN blend membranes were investigated. The molecular mobility of the SPEEK/PAEBN blends was also examined in this study. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
30.
Rinkenauer Gerhard; Osman Allen; Ulrich Rolf; Müller-Gethmann Hiltraut; Mattes Stefan 《Canadian Metallurgical Quarterly》2004,133(2):261
Lateralized readiness potentials (LRPs) were used to determine the stage(s) of reaction time (RT) responsible for speed-accuracy trade-offs (SATs). Speeded decisions based on several types of information were examined in 3 experiments, involving, respectively, a line discrimination task, lexical decisions, and an Erikson flanker task. Three levels of SAT were obtained in each experiment by adjusting response deadlines with an adaptive tracking algorithm. Speed stress affected the duration of RT stages both before and after the start of the LRP in all experiments. The latter effect cannot be explained by guessing strategies, by variations in response force, or as an indirect consequence of the pre-LRP effect. Contrary to most models, it suggests that SAT can occur at a late postdecisional stage. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献