Structure and properties of polyimide‐bonded magnets processed from prepolymers based on diacetyl derivatives of aromatic diamines and dianhydrides

We report a novel method of polyimide (PI) synthesis from prepolymers based on dianhydrides and diacetyl derivatives of aromatic diamines that facilitate the preparation of a melt processable mixture at 300 ± 10°C of the prepolymer and magnetic Nd‐Fe‐B alloy to provide PI‐bonded magnets with enhanced properties. It is shown that chemical structure of the prepolymers strongly influences viscosity behavior via crystallization of the oligoimide in the melt, leading to formation of PI with rigid‐rod like structure. This structural ordering of the prepolymers based on diacetyl derivative of diamine used in this study, if not controlled, leads to exponential increase of melt viscosity with time, making it practically impossible to prepare melt processable mixture of the magnetic particles and the PI prepolymers at elevated temperatures. The results obtained demonstrate that appropriate dianhydrides and diacetyl derivatives of diamines that do not lead to crystallization of oligoimides in prepolymer mixture can be used under controlled processing conditions to prepare melt‐processable PI‐bonded magnets containing rigid‐rod like PI structure that significantly increases thermal stability of the magnets. The temperature dependencies of the magnetic properties of the PI‐bonded magnets under conditions that they are likely to encounter during their service life were found to be remarkably similar to that of commercial thermoplastic magnets such as injection‐molded nylon magnets. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 478–485, 2006     

一种融合多帧ICP和图优化的算法研究

当前基于迭代最近点拼接的同时定位与建图算法,存在误差积累、无法满足大范围定位精度的缺陷。为此,提出一种融合多帧迭代最近点和图优化的算法。在时域上处理点云拼接问题,将单帧迭代最近点算法推广到多帧进行最近点迭代,提取同一地点在不同时刻的数据特征,形成多个封闭循环,再运用基于最小二乘的图优化方法对点云拼接后的全网数据进行全局优化,消除累计误差,提升整体的定位精度。采用鲁巷和密歇根的数据进行测试,结果表明,该方法在一定程度上减少了匹配误差,平均误差为1.0m,最小误差为0.2m,可以满足大范围同步定位与建图的精度需求。     

我国LLDPE产需及装置建设现状

我国现有５套ＬＬＤＰＥ生产装置，合计生产能力为３８．５万ｔ／ａ。“八五”期间，我国又引进６套ＬＬＤＰＥ生产装置，合计生产能力为６４万ｔ／ａ。到“八五”后期，我国ＬＬＤＰＥ生产能力将超过１００万ｔ／ａ，其中７５％是采用美国ＵＣＣ技术生产的。建议我国跟踪世界新技术，并适应市场需求。     

改性膨润土对甲基橙的吸附

在用Cu^2 A‘^3 Fe^3 对膨润土改性中，Fe^3 改性的膨润土对甲基橙的吸附性能最好，在振荡20分钟后即可达到吸附平衡。pH=3～7、用量为3g／L、25℃时对甲基橙的吸附量达到最大，在pH=7及常温条件下，铁基膨润土的用量为11g／L时，对浓度为250mg／L甲基橙的吸附量和去除率分别为22.2mg／g98．6％；对浓度为40mg／L的甲基橙去除率达97.1％。     

基于多渐消因子强跟踪UKF 和约束AR模型的故障估计与预测

针对非线性系统中不可观测故障参数估计和预测问题, 提出一种基于多重渐消因子强跟踪无迹卡尔曼滤波(MSTUKF) 的状态和参数联合估计法, 通过引入多重渐消因子增强了对变化函数未知的故障参数的跟踪能力. 对于得到的故障参数估计值, 利用递推最小二乘法更新约束AR预测模型, 从而实现故障参数的在线估计与预测. 仿真结果表明, MSTUKF方法在故障参数估计精度上优于UKF 和单渐消因子强跟踪UKF, 约束AR模型的预测精度高于无约束条件下的预测精度.

     

开关柜智能监控装置的设计与实现

文中的开关柜智能监控装置是针对电力开关柜开发设计的一种新型的多功能智能化模拟动态指示装置。该方案以ARM处理器NUC950为控制核心,它集一次回路模拟图、断路器状态、手车位置、接地刀闸位置、弹簧储能状态、隔离开关状态、高压带电显示及闭锁、自动(手动)加热除湿控制、加热器故障报警、超温报警指示、语音防误提示、网络通信等多功能于一体,提高了开关柜状态监测和控制的集成度和智能化。     

圆弧齿轮的解析法设计计算

本文对目前在仪器仪表中采用的圆弧齿轮进行了分析,在图解法设计的基础上,推出了一套解析法设计计算方案。     

实时数据仓库中一种改进的数据流更新算法

为实现数据仓库中数据的高效集成,针对数据偏斜分布现象,提出一种改进的数据流更新算法EH-JOIN。该算法对传统散列连接方法进行改进,利用索引将部分频繁使用的主数据存储在内存中,解决了高速数据流下的磁盘频繁访问问题。实验结果表明,与MESHJOIN算法和R-MESHJOIN算法相比,EH-JOIN算法的服务速率在磁盘存储关系集保持适当大小时分别提高了96%和81%,在内存大小不同时提高了57%和48%。     

Development of soft sensor by incorporating the delayed infrequent and irregular measurements

Originated from challenging industrial applications, this paper addresses a soft sensor development problem for linear systems with two types of measurements. One is fast, regular and delay-free measurements. The other is infrequent, irregular measurements with time-varying delays. The approach to be taken is based on the Kalman filter and data fusion technique, avoiding running the full augmented state Kalman filter, and leading to a considerably lower implementation cost. Although it is suboptimal, the loss in performance is minor compared to the optimal filter. Two simulation examples demonstrate the advantages of the proposed approach. An industrial soft sensor application example is also used to demonstrate its practicality.     

一步法硅烷接枝交联改性聚丙烯的研究

采用反应挤出法一步实现聚丙烯（PP）的硅烷接枝和交联改性，制备出了具有部分交联结构的高熔体强度PP。通过改性前后红外光谱、熔体流动性能、凝胶含量、结晶行为、力学性能和发泡性能的变化考察了改性对材料性能的影响。结果表明，一步法改性后PP大分子中引入了硅烷接枝交联结构，使熔体强度、熔体黏度提高，熔体流动速率显著降低，并且体系中出现了高达48％的凝胶；交联结构的引入使PP的结晶速率减缓；改性后材料的力学性能有所提高，而发泡性能大大改善，可以获得高质量的泡沫塑料。