搪玻璃反应釜流场特征的数值模拟

为了研究化工行业中常用的搪玻璃反应釜内的流场特征,用UG(Unigraphics)建立实际搅拌釜的三维简化模型,然后导入Gambit中进行网格划分,最后应用Fluent数值模拟,得到了不同转速、流体介质和搅拌形式下反应釜的流场特征并进行对比分析。结果表明:转速改变,流体的速度和压力分布情况相同,仅仅是数值上有所改变,转速的增加使得搪玻璃温度计套表面所受压力增加;不同流体介质下,流体的流场有所差别,粘性较大的流体介质流场速度扩散相对要差,搪玻璃温度计套所受压力较小;对比3种不同搅拌形式(桨式、叶轮式和框式)下的流场发现,叶轮式搅拌器比桨式的流体速度扩散要好,框式搅拌器的流体速度分布最均匀,但是框式搅拌釜流场中搪玻璃温度计套所受压力也最大。     

Compatibility and thermal properties of poly(acrylonitrile–butadiene–styrene) copolymer blends with poly(methyl methacrylate) and poly(styrene‐co‐acrylonitrile)

The mechanical and heat‐resistant properties of acrylonitrile–butadiene–styrene (ABS) binary and ternary blends were investigated. The relationship of compatibility and properties was discussed. The results show that poly(methyl methacrylate) (PMMA) and styrene–maleic anhydride (SMA) can improve the thermal properties of conventional ABS. The Izod impact property of ABS/PMMA blends increases significantly with the addition of PMMA, whereas that of ABS/SMA blends decreases significantly with the addition of SMA. Blends mixed with high‐viscosity PMMA are characterized by higher heat‐distortion temperature (HDT), and their heat resistance is similar to that of blends mixed with SMA. For high‐viscosity PMMA, from 10 to 20%, it is clear that blends appear at the brittle–ductile transition, which is related to the compatibility of the two phases. TEM micrographs show low‐content and high‐viscosity PMMA in large, abnormally shaped forms in the matrix. Compatibility between PMMA and ABS is dependent on both the amount and the viscosity of PMMA. When the amount of high‐viscosity PMMA varied from 10 to 20 wt %, the morphology of the ABS binary blends varied from poor to satisfactory compatibility. As the viscosity of PMMA decreases, the critical amount of PMMA needed for the compatibility of the two phases also decreases. SMA, as a compatibilizer, improved the interfacial adhesiveness of ABS and PMMA, which results in PMMA having good dispersion in the matrix. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2652–2660, 2002     

An iterative two‐step sequential phase partition (ITSPP) method for batch process modeling and online monitoring

Operating at different manufacturing steps, multiphase modeling and analysis of the batch process are advantageous to improving monitoring performance and understanding manufacturing processes. Although many phase partition algorithms have been proposed, they have some disadvantages and cause problems: (1) time sequence disorder, which requires elaborate post‐treatments; (2) a lack of quantitative index to indicate transition patterns; and (3) tunable parameters that cannot be quantitatively determined. To effectively overcome these problems, an iterative two‐step sequential phase partition algorithm is proposed in the present work. In the first step, initial phase partition results are obtained by checking changes of the control limit of squared prediction error. Sequentially, the fast search and find of density peaks clustering algorithm is employed to adjust the degradation degree and update the phase partition results. These two steps are iteratively executed until a proper degradation degree is found for the first phase. Then, the remaining phases are processed one by one using the same procedure. Moreover, a statistical index is quantitatively defined based on density and distance analysis to judge whether a process has transitions, and when the transition regions begin and end. In this way, the phases and transition patterns are quantitatively determined without ambiguity from the perspective of monitoring performance. The effectiveness of the proposed method is illustrated by a numerical example and a typical industrial case. Several typical phase partition algorithms are also employed for comprehensive comparisons with the proposed method. © 2016 American Institute of Chemical Engineers AIChE J, 62: 2358–2373, 2016     

Lennard-Jones流体固液相变的分子动力学模拟

采用等温等容分子动力学模拟方法，研究了ＬｅｎｎａｒｄＪｏｎｅｓ流体从固相到液相体系结构和性质的变化。均方位移，径向分布函数，平动序参数等结构和性质的模拟表明体系经历了固液相变。在对比密度为０．８４，０．８６，０．８８和０．９时，体系熔点分别为０．６６～０．６７，０．７１～０．７２，０．８２～０．８３和０．９０～０．９１。     

模拟高放废液碱矿渣水泥固化体稳定性的研究

本文主要研究了碱矿渣水泥固化体的热力学稳定性、热稳定性和在地下水中的稳定性.研究结果表明,水化到28天时,固化体中处于介稳态的矿渣玻璃体基本消失,转化为稳定的水化产物,固化体的热力学稳定性良好;固化体在500℃的高温下仍具有足够的强度,热稳定性良好;同时,在地下水中,固化体也具有良好的稳定性.     

Bi2O3-ZnO-Nb2O3(BZN)系复相陶瓷的相转变

重新讨论了ＢＺＮ系（α＋ β） 复相陶瓷中α相与β相之间的相转变． 研究表明：ＢＺＮ系α相与β相是有一定固溶范围的三元化合物,α相的固溶范围受温度的影响较大,β相的固溶范围受温度的影响较小． 复相（α＋ β） 的相组成因此受温度的影响,随温度升高,α相的固溶范围变大,对β相的固溶度增加,复相中β相减少,α相增加． 随温度降低,α相的固溶范围变小,对β相的固溶度减小,β相从α相中脱溶,复相中α相减少,β相增加．     

产品造型设计与工程实现的对接研究

虽然造型设计日益成为企业提升产品价值的重要手段,但是它的魅力却无法通过工程技术在产品中完全体现,归根到底是产品造型设计与工程实现两个环节的对接不够合理造成.文章通过对设计对接过程进行较为全面的分析,找出传统设计程序与工程实现中不利于对接的因素,探索造型设计与工程实现之间合理对接的方式,以期能促进设计创意向现实产品顺利转...     

两相区部分奥氏体化对连续退火双相钢相变过程的影响

将连续退火双相钢部分奥氏体化与完全奥氏体化后的CCT曲线进行对比分析,讨论了部分奥氏体化的影响。结果表明:部分奥氏体化后,该钢铁素体和贝氏体转变区的范围扩大,珠光体转变受到抑制且晶粒尺寸减小,马氏体转变的开始温度从368℃下降到349℃;部分奥氏体化时马氏体的转变温度区域大于完全奥氏体化时的。     

基于虚拟技术的形状误差数据处理方法

通过在虚拟空间中重构被测实际要素,依据对应项目形状公差带定义构造包容实际要素的理想要素,利用虚拟技术的碰撞检测理论使理想要素包容区域运次逼近对应形状误差的理论最小区域,从而得到精度在给定步长范围内的形状误差值;该方法符合最小条件原则,无需建立复杂的数学模型,计算结果精度已知,并可实现对所有的形状误差的计算,思想统一,便于理解与应用.