Aging and mechanical properties of NR/BR blends

The mechanical properties and post-thermal aging properties of natural rubber (NR) and polybutadiene rubber (BR) blends at different blending ratios are investigated herein. The experimental results show that both tensile and tear strengths of NR/BR blends increase with increasing NR content. BR has a higher compression stiffness than NR. The deformation of BR is less than that of NR under the same load conditions. With regard to aging properties, both tensile stress and strain of NR/BR blends decrease after prolonged aging. In addition, the stress loss of BR is lower than that of NR, meaning that the aging resistance property of BR is superior to that of NR. Furthermore, accumulated thermal history has shifted the glass transition temperature (T _g) of NR/BR blends toward lower temperatures while the loss tangent (tan δ) value increases with prolonged thermal aging.     

25Cr3Mo3NiNb二次硬化钢冲击性能的研究

研究了二次硬化钢25Cr3Mo3NiNb的冲击韧度随回火温度和试验温度的变化.结果发现,试验钢在200℃回火时冲击韧度较高,300～600℃回火时冲击韧度值较低,600℃以上回火时冲击韧度值迅速升高,640℃回火时冲击韧度达到最高值55J/cm2,640℃以上回火时冲击韧度值有所降低.640℃回火后试验钢的冷脆转变温度为10℃,屈服强度为960MPa,可以满足兵器特种结构件高强度高韧性的要求.     

化合物TbMn6Sn6的磁性和磁相变

采用分子场理论模型对稀土-过渡族金属间化合物的磁性、自旋重取向相变和场诱导的一级磁相变进行了研究.从理论上计算了TbMn6Sn6的易磁化方向随温度的变化以及不同温度时的磁化曲线,描述了自旋重取向相变和场诱导的一级磁相变.基于单离子模型计算了Tb离子和化合物的一阶和二阶磁晶各向异性常数及其随温度的变化,得到了和实验数据基本一致的结果.结果表明:Mn次晶格和Tb次晶格磁晶各向异性能之间的相互竞争是导致自旋重取向相变的物理机制,而稀土离子的四阶晶场项对场诱导的一级磁相变产生很大的影响.     

Dose and dose rate effects on coherent-to-incoherent transition of precipitates upon irradiation

A typical precipitation hardened alloy, Cu-Co dilute alloy was selected to study the precipitation behavior and irradiation effect on precipitates. It is found that the principal effect of ion irradiation on the coherent precipitates is loss of coherency, and TEM cross-section observations show that the fraction of the incoherent precipitates is dependent on dose but not on dose rate during heavy ion irradiation.     

STRAIN INDUCED STRUCTURAL TRANSITION OF INTERFACES AND TWINS IN A HOT－DEFORMED DUAL－PHASE TIAL ALLOY

ＳＴＲＡＩＮＩＮＤＵＣＥＤＳＴＲＵＣＴＵＲＡＬＴＲＡＮＳＩＴＩＯＮＯＦＩＮＴＥＲＦＡＣＥＳＡＮＤＴＷＩＮＳＩＮＡＨＯＴ－ＤＥＦＯＲＭＥＤＤＵＡＬ－ＰＨＡＳＥＴＩＡＬＡＬＬＯＹＣＨＥＮＧｕｏＦｉａｎｇ；ＷＡＮＧＪｉｎｇｕｏ；ＺＨＡＮＧＬｉｃｈｕｎａｎｄ...     

高温W/Re流口复合界面上的扩散层

W/Re流口在高温下使用时,复合界面处会发生反应扩散而形成一个由固溶体(W),双相σ,双相x,固溶体(Re)4个相组成的过渡层。并作出了不同反应扩散时间的浓度分布曲线,及浓度突变形成的双相区,从而确定了各相成份组成。对经反应扩散后的复合界面进行微观观察发现x相、σ相内有许多间隔式微裂纹,据此认为高温下W/Re流口失效原因是使用过程中上述两x,σ相内裂纹扩散,熔体渗入所致。     

不等厚板过渡削薄对接焊缝的超声波探伤

不等厚板经过渡削薄处理后的对接焊缝,由于厚度的不均匀,射线穿透时的衰减不一样,对射线检测带来很大的麻烦。常用的超声波探伤方法在定位和定级方面比较困难,本文给出利用现在先进的数字式超声波探伤仪进行准确探伤的方法。     

Recent Advances in Conjugated Transition Metal-containing Polymers and Materials

Metal-containing conjugated oligomers and polymers are reviewed, focusing on the work carried out by the author and coworkers since 1995. The synthesis of model systems, electropolymerizable monomers and polymer films are discussed, along with the electronic and spectroscopic properties of these systems. The application of phosphino-oligothiophene ligands as an entry to conjugated metallopolymers is described.     

用直接纺丝法制芳纶短纤维

研究了直接纺丝制取芳纶短纤维的新方法。讨论了纤维长度、直径及力学性能与纺丝条件的关系。发现影响纤维长度的主要因素是空气层高度和喷丝速度,影响纤维直径的主要因素为喷口直径及喷丝速度。此外,还用PPTA短纤维制成了均匀的PPTA"浆粕"纤维。     

（Nb_yTi_（1－y））C_x单晶体制备及其结构研究

用熔剂法制备了（Ｎｂ＿ｙ．Ｔｉ＿（１－ｙ））Ｃ＿ｒ单晶体，用Ｄｅｂｙｅ照相法及四圆衍射仪对其晶体结构进行了研究。实验结果表明，（Ｎｂ＿ｙＴｉ￣（１－ｙ）Ｃ＿ｘ中存在类似于作化学计量化合物ＴｉＣ＿ｘ及ＮｂＣ＿ｘ的有序一无序转变现象，转变温度随其化学成份改变在１１７５～１２８０Ｋ范围内变化。高温型（Ｎｂ＿ｙＴｉ￣（１－ｙ））Ｃ＿ｘ的晶体结构属ＮａＣｌ型结构，碳空位呈随机分布；低温型（Ｎｂ＿ｙＴｉ￣（１－ｙ））Ｃ＿ｘ的晶体中碳空位呈短程有序分布，可用Ｖ＿６Ｃ＿５晶体结构模型进行描述。