Enhanced Photoelectrochemistry in CdS/Au Nanoparticle Bilayers

Three different configurations of Au‐nanoparticle/CdS‐nanoparticle arrays are organized on Au/quartz electrodes for enhanced photocurrent generation. In one configuration, Au‐nanoparticles are covalently linked to the electrode and the CdS‐nanoparticles are covalently linked to the bare Au‐nanoparticle assembly. The resulting photocurrent, φ = 7.5 %, is ca. 9‐fold higher than the photocurrent originating from a CdS‐nanoparticle layer that lacks the Au‐nanoparticles, φ = 0.8 %. The enhanced photocurrent in the Au/CdS nanoparticle array is attributed to effective charge separation of the electron–hole pair by the injection of conduction‐band electrons from the CdS‐ to the Au‐nanoparticles. Two other configurations involving electrostatically stabilized bipyridinium‐crosslinked Au/CdS or CdS/Au nanoparticle arrays were assembled on the Au/quartz crystal. The photocurrent quantum yields in the two systems are φ = 10 % and φ = 5 %, respectively. The photocurrents in control systems that include electrostatically bridged Au/CdS or CdS/Au nanoparticles by oligocationic units that lack electron‐acceptor units are substantially lower than the values observed in the analogous bipyridinium‐bridged systems. The enhanced photocurrents in the bipyridinium‐crosslinked systems is attributed to the stepwise electron transfer of conduction‐band electrons to the Au‐nanoparticles by the bipyridinium relay bridge, a process that stabilizes the electron–hole pair against recombination and leads to effective charge separation.     

变形介质中宾汉稠油驱替特征

通过建立变形介质中考虑启动压力梯度的一维两相宾汉稠油驱替的数学模型,并进行了数值求解,分析了地层变形以及启动压力梯度对水驱稠油的影响,分析表明:介质变形对含水饱和度的分布没有影响,而对地层压力的影响是非常显著的,随着变形介质弹性的增加,地层压力越来越低,并且越靠近注入端,地层压力下降越快;原油的启动压力梯度同时影响含水饱和度和地层压力的分布,在其它条件一定时,启动压力梯度的存在,造成地层压力的增加和平均含水饱和度的降低。在油田开发实际中,应考虑地层变形和启动压力梯度的影响,以提高原油采收率。     

洼60-H26水平井套铣打捞技术

洼60-H26井是一口中曲率水平井,设计井深1 922 m,由于地面条件的限制,设计采用三维井眼轨道。该井水平段在钻至井深1 801 m时,发生卡钻事故。在卡钻事故处理过程中,采用测卡、爆炸松扣技术取出上部钻具后,应用了不同规格的套铣管对被卡钻具进行套铣,采用间歇式套铣方式实现了大斜度井段(45°-90°)的安全套铣,采用短套铣管完成了时水平井段内φ215．0 mm稳定器的套铣,采用φ228．6 mm套铣管成功套铣水平井段被卡LWD仪器,最后通过震击器震击成功解卡。详细介绍了洼60-H26水平井卡钻事故的处理过程,分析了在水平段处理卡钻事故的难点。该井处理卡钻事故的经验,对以后水平井施工中处理井下事故、打捞贵重仪器具有借鉴价值。     

可拓知识空间和可拓知识网格模型(Ⅱ):可拓知识网格

第1部分中已介绍了可拓知识空间定义和相关操作，以及可拓知识空间关联函数计算方法。这一部分进一步建立可拓知识空间语义网、可拓知识网格和可拓知识网格服务，并给出实例和相关的分析讨论。     

目标RCS动态数据的分布特征研究

复杂目标在不同视向的RCS分布特征是不同的，传统模型对此都没有给出详细的结果。文中以某歼击机和直升机为对象，应用X^2。分布、对数正态分布和瑞利分布模型，以及Kolmogomv拟合优度检验方法，研究其RCS动态测量数据的统计分布特征，得到了在一定显著性水平下，两种目标在不同视向角下对三种模型的拟合效果，同时得到应用X^2。分布拟合时模型半自由度随视向角的分布情况。在显著性水平为0．05时，对于在较短时间内录得的复杂目标动态RCS数据，应用X^2分布可以取得较好的拟合效果。文中结果精确地描述了目标RCS的起伏特征，能够为目标回波的精确模拟与检测提供可靠的依据。     

井下注剂用小直径管起下装置的研制

针对目前国内小直径管井下注剂设备配套工具不完整,不能满足现场使用要求的情况,研制了井下注剂用小直径管起下装置。该装置采用可正反向旋转的液马达驱动主轴的方案,通过同步齿轮带动链条,夹紧机构使链条上的夹块夹住小直径管,由液压系统实现整个操作与控制,从而使装置上下运动。井场模拟试验表明,井下注剂用小直径管起下装置可完全满足小直径管起下作业的要求,且可避免小直径管管体的变形和损坏。     

Finite element piezothermoelasticity analysis and the active control of FGM plates with integrated piezoelectric sensors and actuators

 An efficient finite element model is presented for the static and dynamic piezothermoelastic analysis and control of FGM plates under temperature gradient environments using integrated piezoelectric sensor/actuator layers. The properties of an FGM plate are functionally graded in the thickness direction according to a volume fraction power law distribution. A constant displacement-cum-velocity feedback control algorithm that couples the direct and inverse piezoelectric effects is applied to provide active feedback control of the integrated FGM plate in a closed loop system. Numerical results for the static and dynamic control are presented for the FGM plate, which consists of zirconia and aluminum. The effects of the constituent volume fractions and the influence of feedback control gain on the static and dynamic responses of the FGM plates are examined. Received: 13 March 2002 / Accepted: 5 March 2003 The work described in this paper was supported by a grant awarded by the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No. CityU 1024/01E).     

A three-dimensional FE analysis of large deformations for impact loadings using tetrahedral elements

 A three-dimensional dynamic program for the anaysis of large deformations in contact-penetration problems is developed using the finite element Lagrangian method with explicit time integration. By incorporating a tetrahedral element, which allows a single-point integration without a special hourglass control scheme, this program can be more effective to the present problem. The position code algorithm is used to search contact surface. Eroding surfaces are also considered. The defense node algorithm was slightly modified for the calculation of contact forces. A study of obliquity effects on metallic plate perforation and ricochet processes in thin plates impacted by a sphere was conducted. It is well simulated that on separation of two parts of the sphere, the portion still within the crater tends to perforate, while the portion in contact with the plate surface ricochets. This deformation pattern is observed in experiments, especially at high obliquities. A long rod that impacts an oblique steel plate at high impact velocity was also simulated in order to study the dynamics of the rod caused by the three dimensional asymmetric contact. The agreement between simulated and experimental results is quite good. Fracture phenomena occuring at high obliquity deserves further investigations. Received: 20 February 2002 / Accepted: 20 September 2002     

黄海地质构造与油气资源

针对以往黄海油气勘探在找油思路、勘探深度、勘探领域、勘探部署和勘探技术等方面存在的问题 ,概述了南、北黄海地质构造、盆地演化、油气地质特征及成藏条件 ,并在此基础上 ,提出了对黄海油气资源远景的几点认识