Engineering Field Effect Transistors with 2D Semiconducting Channels: Status and Prospects

The continuous miniaturization of field effect transistors (FETs) dictated by Moore's law has enabled continuous enhancement of their performance during the last four decades, allowing the fabrication of more powerful electronic products (e.g., computers and phones). However, as the size of FETs currently approaches interatomic distances, a general performance stagnation is expected, and new strategies to continue the performance enhancement trend are being thoroughly investigated. Among them, the use of 2D semiconducting materials as channels in FETs has raised a lot of interest in both academia and industry. However, after 15 years of intense research on 2D materials, there remain important limitations preventing their integration in solid‐state microelectronic devices. In this work, the main methods developed to fabricate FETs with 2D semiconducting channels are presented, and their scalability and compatibility with the requirements imposed by the semiconductor industry are discussed. The key factors that determine the performance of FETs with 2D semiconducting channels are carefully analyzed, and some recommendations to engineer them are proposed. This report presents a pathway for the integration of 2D semiconducting materials in FETs, and therefore, it may become a useful guide for materials scientists and engineers working in this field.     

In situ electrodeposition of nickel cobalt selenides on FTO as an efficient counter electrode for dye-sensitized solar cells

Construction of transition metal selenides with high electrocatalytic performance is of significant importance, but it is still a challenge to develop the corresponding counter electrodes (CEs) by an electrodeposition technique. In the present work, nickel cobalt selenide (Ni_xCo_ySe) films are prepared in situ on fluorine-doped tin oxide (FTO) glasses through a potential reversal electrodeposition technique. The morphology and electronic structure of Ni_xCo_ySe films can be tuned by controlling the Ni/Co molar ratio in electroplating solution. Specially, Ni_xCo_ySe-6 film (the Ni/Co molar ratio of 1:1) with the optimized interaction between the Ni and Co elements displays numerous particles composed of sheets attached with nanocrystals, resulting in the more electrocatalytic active sites. Benefiting from the unique morphology and optimized synergistic effect, Ni_xCo_ySe-6 CE exhibits superior electrocatalytic activity for the triiodide reduction. Then, the dye-sensitized solar cell (DSC) fabricated by Ni_xCo_ySe-6 CE has demonstrated a power conversion efficiency (PCE) over 7.40%, which is higher than that of platinum (Pt)-based device (6.32%). Furthermore, Ni_xCo_ySe-6 array CE is also prepared by using polystyrene array as template. The PCE of the DSC with Ni_xCo_ySe-6 array CE reaches its maximum value of 7.64% and 20.9% larger than that of Pt-based device.     

A study on the dust control effect of the dust extraction system in TBM construction tunnels based on CFD computer simulation technology

In order to control dust in a tunnel boring machine (TBM) construction tunnels, this paper, in combination with field measurements, applies CFD computer simulation technology to study the dust control effect of TBM construction tunnels under different dust extraction flow rates. Firstly, the dust extraction system is closed, and the result of the simulation show that the dust diffuses to the entire TBM working area within 181 s, indicating the necessity of having a dust extraction system in the tunnel. Secondly, the dust extraction system is open and under the original dust extraction flow rate of Q_e = 8 m³/s, the overall dust diffuses to the entire working area L_o = 130 m, and the full-face dust diffusion distance is L_f = 47.54 m. Then the study was carried out with the setting of 2 m³/s ≤ Q_e ≤ 14 m³/s. The results show that: when Q_e ≤ 8 m³/s, the full-face dust diffuses to 47.54–71.84 m; when Q_e > 8 m³/s, the full-face dust can be controlled at 42.81–46.34 m; and when Q_e = 8 m³/s, the full-face dust control effect is better, and the average dust concentration in the tunnel is as low as 12.25 mg/m³, indicating that the original dust extraction system has a better design. The field measurement results verify that the CFD computer simulation results are accurate.     

A new modification effect of eutectic Si in selective laser melted AlSi10Mg

A distinct modification of eutectic Si was observed in the selective laser melted AlSi10Mg. The eutectic Si particles were modified substantially and demonstrated a nanoscale size, a fibrous morphology with obvious ‘necking effect’. The modification mechanism and the influence of heat treatment on eutectic Si growth were explored. It was suspected that Si experienced the necking effect under a tensile environment due to the large temperature gradient and α-Al erosion during the SLM process. Upon heat treatment, the Si particles were spheroidised and distributed homogeneously. Under the synergistic action of Si crystal fragmentation and the continuous precipitation of saturated Si from the Al matrix, the coarsened and spheroidised eutectic Si were distributed homogeneously in the Al matrix.     

Torsional statics of two-dimensionally functionally graded microtubes

A size-dependent governing equation is derived to investigate the torsional static behaviors of two-dimensionally functionally graded microtubes based on the modified couple stress theory. The shear modulus is assumed to vary along the tube’s length direction according to an exponential distribute function, and varies along the tube’s radius direction according to a power-law function. A generalized differential quadrature method is developed to determine the rotational angle and shear stresses. Some illustrative examples are given to investigate the effects of applied torques, the length scale parameter and various material compositions on the torsional angle and shear stresses.     

Engineering the Structure of Mesoporous Bioactive Glass Microspheres by the Surface Effect of Inverse Opal Templates and Temperature

The interactions of ions and molecules with material surface are highly dependent on the surface properties of the material. Therefore, the distribution of ions or molecules near the material surface may be affected by the surface properties. This phenomenon can be significant enough for controlling the structure of a material synthesized in the sub‐micrometer scale confinement space of a template. This work confirms that inverse opals are perfect templates for offering confinement space, while their different surface properties can strongly affect ion and block copolymer distribution in the confinement space. This surface effect principle can be used for the controlled synthesis of colloids with complex composition. As an example, four kinds of mesoporous magnetic bioactive glass colloids with ordered mesopores, core–shell structure, open surface pores, or disordered mesopores are prepared by using polystyrene and carbon inverse opal templates. This work reveals that inverse opal templates possess great advantage in controlled synthesizing colloidal structures due to their surface effect on ions and molecules and confinement space.     

A mechanism based on finger-sliding behavior for designing radial menus

Human behavior about sliding their fingers on touch screens needs to be understood for the design of radial menus. For this purpose, data about the angles of finger sliding in performing radial pointing to eight predefined directions were collected. The optimal angle ranges and boundaries for these directions were then determined by the proposed mechanism. Consistent with previous research, results showed that the deviations of slide angles for the four diagonal directions were larger than that for the four orthogonal directions. Therefore, to reduce overall pointing errors, the angle ranges for the diagonal directions should be wider than that for the orthogonal directions. Based on the proposed mechanism, the total probability of pointing errors could be limited to 0.05%, compared to the error of 2.00% if the eight angle ranges were evenly divided by the radii of a regular octagon. Besides the angles, the lengths and starting points of the slides were reported and discussed along with the oblique effect, judder effect, and screen orientation. Possible applications of the proposed mechanism for dynamic and personalized radial menus are addressed. Further research would be worthwhile to examine the effects of screen orientation and the number of predefined directions on pointing performances. Moreover, extending the research to mid-air sliding gestures would be of interest and value in designing three-dimensional radial menus.Relevance to industryThe proposed mechanism could effectively enhance the accuracy of the selections through radial menus, and could be applied to the remote controls via smart handheld devices.     

Effect of strain waveform on creep-fatigue life for Sn–8Zn–3Bi solder

This paper describes the creep‐fatigue life of Sn–8Zn–3Bi under push–pull loading. Creep‐fatigue tests were carried out using Sn–8Zn–3Bi specimens in fast–fast, fast–slow, slow–fast, slow–slow and hold–time strain waveforms. Creep‐fatigue lives in the slow–slow and hold‐time waveforms showed a small reduction from the fast–fast lives but those in the slow–fast and fast–slow waveforms showed a significant reduction from the fast–fast lives. Conventional creep‐fatigue life prediction methods were applied to the experimental data and the applicability of the methods was discussed. Creep‐fatigue characteristics of Sn–8Zn–3Bi were compared with those of Sn–3.5Ag and Sn–37Pb.     

Rate effect of concrete strength under initial static loading

The dynamic strength enhancement of concrete under different initial static loadings is investigated in this paper. The mechanism of the influence of the inertia effect on the dynamic strength of concrete is discussed first by analyzing a single dimension of freedom system, which shows that the inertia effect only influences the dynamic loading part. The dynamic strength of concrete at initial static loading is calculated assuming a single crack model with consideration of free water viscosity using dynamic fracture mechanics. The dynamic stress intensity factor of the crack under linearly increasing loading on the basis of an initial static loading is achieved. The relationship between the dynamic strength increase factor and the static stress level is obtained. The comparison between the results by the model proposed in this paper and those by experiments in some available references indicates a good agreement.