A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal‐ and Photostability

The authors have designed and synthesized a family of high‐performance inorganic–organic hybrid phosphor materials composed of extended and robust networks of one, two, and three dimensions. Following a bottom‐up solution‐based synthetic approach, these structures are constructed by connecting highly emissive Cu₄I₄ cubic clusters via carefully selected ligands that form strong Cu? N bonds. They emit intensive yellow‐orange light with high luminescence quantum efficiency, coupled with large Stokes shift, which greatly reduces self‐absorption. They also demonstrate exceptionally high framework‐ and photostability, comparable to those of commercial phosphors. The high stabilities are the result of significantly enhanced Cu? N bonds, as confirmed by the density functional theory (DFT) binding energy and electron density calculations. Possible emission mechanisms are analyzed based on the results of theoretical calculations and optical experiments. Two‐component white phosphors obtained by blending blue and yellow emitters reach an internal quantum yield as high as 82% and correlated color temperature as low as 2534 K. The performance level of this subfamily exceeds all other types of Cu–I based hybrid systems. The combined advantages make them excellent candidates as alternative rare‐earth element‐free phosphors for possible use in energy‐efficient lighting devices.     

A simplified exact expression of SEP for cross QAM in AWGN channel from M × N rectangular QAM and its usefulness in Nakagami-m fading channel

This paper derives a simple exact expression of symbol error probability (SEP) for general order cross QAM constellation in the presence of additive white Gaussian noise (AWGN) channel. The key idea is to obtain this novel expression from a simple analysis of the corresponding rectangular QAM. The analysis of the expression involves simple one dimensional Gaussian Q functions unlike other complex SEP expressions. A simple tight bound approximation of the proposed exact SEP is also given, which provides performance improvement over the existing SEP approximations, particularly for low signal to noise ratios (SNRs). Also, with the help of simulation results, we show that the proposed approximation is in excellent agreement with the exact SEP curve. Moreover, the proposed expressions prove to be useful for accurate estimation of the SEP in Nakagami-m fading channel, including the special case of Rayleigh fading (m = 1).     

基于Hessian矩阵的黑白棋盘格角点检测

针对棋盘格角点的检测,提出了一种运算速度快、定位精度高的Hessian矩阵子像素角点检测算法。简述了Hessian矩阵的原理、算法的执行流程和黑白棋盘格子像素坐标提取的基本方法。通过实验检测出了黑白棋盘格中的角点,得到了角点坐标,并利用二阶泰勒展开式得到了角点的子像素坐标。最后,在不同的噪声水平下,与Harris算法作比较,计算出提取误差与提取时间。实验证明,Hessian矩阵对黑白棋盘格角点检测的更加精确。该实验结果可应用于摄像相标定中。     

基于累加法的高斯白噪声性能分析

基于中心极限定理的累加法,提出了一种新的产生高斯白噪声的方法.首先分析了高斯白噪声的特点,用均匀分布随机序列累加产生高斯分布随机序列,分析其时域和频域特征,并与用 Matlab 里的 randn 函数产生的高斯分布随机序列进行对比.最后用2χ检验法对由累加法产生的高斯分布随机序列进行检验.实验结果表明,累加法产生的随机数十分近似于高斯分布白噪声.     

光纤双折射对光纤环保偏能力影响的实验研究

为了研究光纤双折射对陀螺光纤环保偏能力的影响,选用三种不同型号的光纤采用相同的绕制方法制作相同规格的光纤环.采用白光干涉仪测试光纤环的偏振耦合分布,并利用光纤环两端尾纤与白光干涉仪尾纤的熔点引起的偏振耦合干涉峰计算绕环光纤的双折射.通过不同光纤环测试结果的比较,分析绕环光纤双折射对光纤环保偏能力的影响.测试结果表明,三...     

一种低复杂度信道模拟器的设计

针对TD-LTE射频一致性测试系统专项的需求及通用信道模拟器设计周期长、复杂度高的现状,研究了影响无线信道特性的路径损耗、阴影衰落、多径多普勒效应和高斯白噪声等因素,并相应提出了一种新的计算正余弦函数方法和高斯白噪声产生方法。通过信道理论建模、Matlab链路搭建进行模型优化分析以及基于Xilinx公司Virtex-6芯片的模型FPGA实现,得到了一种简单有效的信道模拟器。实验表明,用TD-LTE基带信号作为激励,该信道冲激响应与Matlab理论值误差在2‰之内,且模型不涉及SCM、WINNER等模型天线方向图、多链路等高复杂度模块,说明该信道模拟器具有简便性和可靠性。     

OLED背光源技术研究进展

有机电致发光二极管(OLED)因其白光材料的多样性、制程的简单性和成本低廉性,特别是其面光源的属性,相较于电致发光二极管(LED)的点光源,更有望成为未来液晶显示器件背光源的主角。介绍了OLED背光源关键技术的最新进展,分别阐述了白光OLED发光效率的提升,OLED器件稳定性和寿命的提高,OLED制备的最新工艺,偏极化的OLED技术,OLED背光源与液晶显示面板匹配技术,还介绍OLED背光源产业发展及发展现状,并对OLED背光源技术的发展趋势进行了展望。     

柴油加氢生产轻质白油技术的开发及工业应用

介绍了中国石化大连石油化工研究院开发的柴油高压加氢工艺生产轻质白油技术。试验以柴油为原料,在小型加氢反应装置采用加氢工艺生产低硫、低芳烃的轻质白油。工业应用结果表明,在氢分压为15.0 MPa、氢油体积比为800、加氢精制反应温度为（基准＋60） ℃、体积空速为基准的条件下,所得160～185 ℃馏分的芳烃质量分数为0.004%,185～215 ℃馏分的芳烃质量分数为0.007%,215～245 ℃馏分的芳烃质量分数为0.015%,245～280 ℃馏分的芳烃质量分数为0.021%,280～310 ℃馏分的芳烃质量分数为0.046%,均满足行业标准NB/SH/T 0913-2015中轻质白油（Ⅱ）指标要求;所得大于310 ℃馏分的倾点为－9 ℃,赛氏颜色为＋30,满足行业标准NB/SH/T 0006-2017对工业白油（Ⅱ）的指标要求。     

硫磺回收装置尾气超低排放处理的设计和运行

国内某炼油厂硫磺回收装置首次应用专有气液混合器,通过钠碱湿法烟气脱硫工艺实现尾气超低排放,排放烟气中SO2的浓度为10～25 mg/m3（标准状况）,脱硫率大于95%,烟气流量操作范围为0～120%,满足硫磺回收装置各种工况下的尾气超低排放。在国内硫磺尾气超低排放处理中首次采用气气换热提升烟气温度,有效减少了冒白烟现象,且解决了烟气管道和设备的硫露点腐蚀问题,同时节能4 950 MJ/h,节水和减排0.64 t/h。     

用于白光LED的掺杂Ce-YAG荧光玻璃的研制

制备并测试了一种新的用于白光LED的掺杂Ce-YAG荧光玻璃。分别在1 300~1 500℃的空气和氮气中制备出Ce-YAG荧光玻璃。在对不同工艺条件下制得的样品进行了对比和分析的基础上,得到了较理想的制备工艺。结果表明,制得的Ce-YAG荧光玻璃被波长为465 nm(蓝色LED的波长)的光波激发,于550 nm处出现发射峰,表明该样品可应用于白光LED的封装。