Pore structure of bulk tungsten carbide powder catalysts

Bulk tungsten carbide catalysts are prepared by direct carburization/reduction of tungsten trioxide in methane-hydrogen mixtures. The catalytic properties of such catalysts have been studied by several authors. The porous structure of these catalysts is studied by adsorption of N₂, Kr, CF₄ and neohexane. Adsorption isotherms and hysteresis loops for the catalysts suggest the presence of a microporous structure made of parallel plates distant approximately by 20 Å. These results are compared to those obtained using such catalysts for hydrogen oxidation and where condensation in the porous structure was observed.     

大型常压锥顶贮罐的设计

以工程实例为依据，论述国内以往较少采用的大型梁柱式支承锥顶贮罐的结构，介绍了国内外相关设计标准，给出了贮罐的典型结构－斜椽，横梁和立柱的计算公式，并用Excel电子表格编制了计算书。     

层次约束结构的虚拟装配建模技术

为了解决虚拟环境下装配建模在信息完备性和模型复杂性等方面的问题,提出了一种基于层次约束结构的虚拟装配模型.该模型分为产品层、部件层、零件层、特征层、几何面层和面片层来表达,不同层元素之间存在层次映射关系,同一层元素之间存在约束关系.通过CAD系统和虚拟装配系统之间的数据转换,实现了虚拟装配模型的生成算法,并给出了根据虚拟装配模型生成的虚拟装配场景图的结构.基于层次约束结构的虚拟装配模型具有信息表达完备,信息集成度高,满足实时性要求等优点,同时还能与CAD系统和虚拟装配场景图实现集成.实例验证了虚拟装配建模的有效性.     

基于形状记忆合金的TMD半主动控制

针对建筑结构在随机荷载或风荷载作用下可能发生的频率不确定问题,特别是结构自振频率会随振幅的大小而发生漂移的非线性振动问题,提出性能可靠、构造简单的形状记忆合金SMA-TMD自适应半主动控制系统.从理论上探讨形状记忆合金在变刚度TMD控制装置中的应用,并进行相应的参数设计.同时,在研究随机荷载作用下TMD系统动力特性的基础上,结合短时傅里叶变换(STFT)设计出该系统的自适应半主动控制算法.算例表明,SMA-TMD自适应控制系统能较好地识别结构系统的时频特性,并进行有效的控制,具有性能可靠和自适应能力强等特点.该自适应控制系统较传统的TMD被动控制减震效果更好,鲁棒性更强.     

有侧移半刚性连接组合框架柱的稳定分析

为了研究有侧移半刚性连接组合框架的稳定性能,利用三柱子框架模型,考虑了梁端和柱远端不同约束情况对柱有效长度系数的影响,提出柱有效长度系数的简化方法.通过算例研究了节点的非线性弯矩-转角关系和荷载水平大小对柱有效长度系数的影响,比较了简化方法、Barakat-Chen方法与精确方法的计算结果.研究表明:简化方法比Barakat-Chen方法有更好的精确度,与精确方法计算结果接近.     

双洞口配筋砌块砌体框支墙梁试验

为研究双洞口配筋砌块砌体框支墙梁地震前后的受力模式,在拟动力子试验前后进行了底层框架配筋砌块短肢砌体剪力墙结构三层足尺模型的竖向力静载试验.试验结果表明:托梁与上部墙体表现出良好的协同工作能力,其工作模式为拉杆拱.通过对其在拟动力试验前后的受力模式进行了比较,可知带洞口配筋砌块砌体框支墙梁结构体系在墙体受到一定损伤时,并不会使墙梁的受力机理发生明显改变.     

等效剪切刚度的框架结构损伤识别方法

为研究有别于现有侧重于研究结构具体构件(梁、柱及支撑等)的建筑结构损伤识别方法,提出应直接从整体开展框架结构损伤识别方法.将框架结构转换成"等效剪切型"结构,数值分析表明,结构具体构件出现损伤(即刚度发生退化)时,会引起受影响层的等效剪切刚度发生变化,因此,可以采用层等效剪切刚度变化率与层抗侧刚度作为指标来进行结构损伤定位与损伤程度评定.通过大量的框架结构数值模拟计算,归纳出了一套能将损伤定位到结构层及从整体来评定结构损伤程度的方法.     

OFDM系统相关矩阵的分块结构及同步算法

根据载波加权可增强OFDM系统周期平稳性,实现系统盲同步的基本原理,分析了OFDM系统相关矩阵的分块结构,给出相应系统的盲同步算法.该方法通过检测相关矩阵的分块Toep litz矩阵结构,实现系统定时和载频偏差的估计.同时,在特定系统同步性能交换误码率的情况下通过分析载波加权、系统误码率和载频同步误差之间的互相制约关系,进一步给出了载波加权的确定方法.实验仿真结果表明,采用分块相关矩阵的同步方案与采用循环谱的同步方案相比,可获得更好的系统载频和定时同步效果.     

Application of ACO algorithm in protein structure prediction

The hydrophobic-polar (HP) lattice model is an important simplified model for studying protein folding. In this paper, we present an improved ACO algorithm for the protein structure prediction. In the algorithm, the "lone"ethod is applied to deal with the infeasible structures, and the "oint mutation and reconstruction"ethod is applied in local search phase. The empirical results show that the presented method is feasible and effective to solve the problem of protein structure prediction, and notable improvements in CPU time are obtained.     

Damage and deterioration mechanism and curing technique of concrete structure in main coal cleaning plants

Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Da-tun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the spe-cial natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.