新型铜锰复合通风瓦斯甲烷氧化催化剂制备与活性研究

为降低低浓度甲烷催化氧化温度,提高催化剂的反应活性,以溶胶-凝胶法合成的具有介孔和三维交联通透型微米级大孔的新型Al2O3为载体,Zr为助剂,采用浸渍法制备得到一种新型Cu-Mn/Zr/Al2O3催化剂.在微型固定床反应器上测试了甲烷催化氧化的转化率,应用XRD和SEM分析了Cu-Mn/Zr/Al2O3催化剂的物相组成和形貌.结果表明:所合成的新型Cu-Mn/Zr/Al2O3催化剂具有良好的低温活性,低浓度甲烷在0.5M Cu-Mn/Al2O3催化剂上的完全转化温度T90为518℃.在一定的实验条件下,甲烷氧化的催化活性随着活性组分浸渍液中金属离子浓度的增大而升高,Cu-Mn浸渍液的最佳浓度为0.5M;随着助剂负载量的增大,CH4的转化率逐渐升高,助剂Zr的最佳负载量为5%.     

Effect of curing conditions on the hydration and performance of CFBC ash cementitious system

Circulating fluidized bed combustion （CFBC） ash can be used as supplementary cementitious material for concrete production for its high pozzolanic activity. We investigated the effect of curing conditions on the hydration and performance of CFBC ash-Portland cement system （30： 70, by mass） including hydration products, paste microstructure, linear expansion ratio, chemically combined water content and compressive strength. The results show that tobermorite rather than ettringite is generated under the condition of autoclaved curing. The expansion and mortar strength of the system cured in water is higher than those cured in air at a given age, and the strength and bulk volume may retract under the condition of air curing. In addition, autoclaved curing facilitates the increase of strength gain at early curing ages （the increase rate lowers down in the following ages） and the improvement of system volume stability. It is suggested that sufficient water is necessary for the curing of CFBC ash cementitious system, and autoclaved curing may be considered where volume stability is a primary concern.     

库车拗陷东部侏罗系“连续型”致密砂岩气成藏条件分析

有利的成藏条件是"连续型"致密砂岩气大规模聚集成藏的重要基础,明确成藏条件对于致密砂岩气藏理论研究和勘探实践具有重要意义.文中讨论库车拗陷侏罗系阿合组"连续型"致密砂岩气藏形成所需要的烃源岩、致密砂岩储层、盖层条件及构造条件.结果表明:下伏三叠系烃源岩为致密砂岩气藏的形成提供充足的气源,广泛分布的致密砂岩储层控制致密砂岩气藏在时间和空间的分布范围,致密储层上覆煤系地层与下伏泥岩为致密砂岩气成藏提供保护作用;后期的强烈构造活动,一方面促进地层快速沉降,有利于烃源岩快速演化,另一方面对致密砂岩气藏具有调整改造的作用,构造裂缝改善储层的物性,同时形成天然气散失的通道.因此,有利的源岩、储层、源储配置关系、盖层及构造活动是库车拗陷东部侏罗系"连续型"致密砂岩气藏形成的有利条件.     

A Novel Fluorescence Probe 9-（4-（1,2-diamine）benzeneN 1-phenyl）acridine for Nitric Oxide Determination

A novel fluorescent probe 9-(4-(1,2-diamine)benzene-N1-phenyl)acridine(DABPA) was synthesized for the detection of nitric oxide(NO) and characterized by IR, 1H-NMR and EI-MS spectroscopy. Based on a photoelectron transfer mechanism, the fl uorescence intensities of DABPA were investigated with the different concentrations of NO. Under the optimal experimental conditions, the fl uorescence intensity of DABPA had a good linear relationship(R2=0.9977) with NO concentration in the range from 1×10-7 to 1.5×10-6 mol/L with a detection limit of 1×10-8 mol/L. The cytotoxicity induced by DABPA was evaluated by the MTT(3-(4,5-dimethylthiazol-2-yl)-2,5diphenyl tetrazolium bromide) assay for biological application. Furthermore, the probe DABPA had also been successfully applied to real-time image NO produced in PC12 cells in the presence of L-arginine.     

纤维堆囊菌产埃博霉素B的发酵条件优化

埃博霉素B是由纤维堆囊菌产生的具有抗癌作用的大环内酯类化合物,是一种新型的抗肿瘤谱广、作用性强的抗肿瘤药物.以纤维堆囊菌SoF5-76为供试菌株,采用单因素试验和正交试验设计,对其产埃博霉素B的发酵条件进行了优化,确定了最优发酵条件为:初始pH 7.4,装液量50/250mL,转速200r/min,种龄60h,接种量10%,温度30℃,发酵周期6d.在此最优发酵条件下,埃博霉素B的产量为35.24mg/L,比优化前提高了17.67%.     

改良型腰果酚醛树脂废气治理的研究

改良型腰果酚醛树脂应用到铸件等浸渍、粘合、烘干等过程中会产生恶臭,排放前需要降解处理。研究采用低温等离子体技术结合吸收方法处理改良型腰果酚醛树脂废气,考察了处理工程中峰值电压、停留时间、吸收液pH值对废气去除率的影响。实验室小试改良型腰果酚醛树脂废气进口浓度85 ppm,停留时间1.2 s时,去除率可达92%;工业扩大示范工程去除率最高可达80%,排气口出气平均恶臭浓度1 239.5(无量纲),满足《恶臭污染物排放标准》(GB14554-93)中相关规定。     

Effects of various fillers on sintering,microstructures and properties of Ca-Ba-Al-B-Si-O glass/ceramic composites简

Low-temperature sintering and properties of LTCC （low temperature co-fired ceramics） materials based on CaO-BaO-Al2O3-B2O3-SiO2 glass and various fillers such as Al2O3, silica glass, christobalite, AlN, ZrO2, MgO-SiO2, TiO2 were investigated. The results show that densification, crystallization, microstructures and dielectric properties of the composites are found to strongly depend on the type of filler. The densification process of glass/ceramic composites with various fillers is mainly from 600 ℃ to 925 ℃, and the initial compacting temperature of samples is 600 ℃. The initial rapid densification of samples starts at its glass softening temperature. LTCC compositions containing Al2O3, silica glass, AlN and MgO-SiO2 fillers start to have the crystallization peaks at 890, 903, 869 and 844 ℃, respectively. The crystallization peaks are believed as correlated to the crystallization of CaAl2SiO8, β-SiO2, Ca2Al2SiO7 and β-SiO2. The composite ceramic with Al2O3, silica glass and TiO2 ceramic have a better dense structure and better smooth fracture surface. Sample for Al2O3 has the lowest dielectric loss tanδ value of 0.00091, whereas the sample for MgO.SiO, has the highest dielectric loss tanδ value of 0.02576. The sample for TiO2 has the highest dielectric constant value of 14.46, whereas the sample for AIN has the lowest dielectric constant value of 4.61.     

风险度量与风险管理的新工具ES

采用资产组合损失变量描述风险,并基于损失分布的α-(上)分位数给出"期望巨额损失值"ES(expected shortfall)和"条件风险价值"CVaR(conditional value at risk)的定义。在一般损失分布下,通过直接计算说明了任一资产组合损失变量的"期望巨额损失值"ES的定义与α-(上)分位数的选取无关;而且也通过直接计算证明了ES与CVaR两者的等价关系;进而通过构造出ES的概率测度族表示证明了ES是一致性风险度量方法。此外,还就相关问题,例如分位数、一致性风险度量、尾部条件期望TCE等,给出了一些有价值的注记。     

不同混凝剂处理低温低浊水的对比应用研究

在我国北方进入冬季,松花江水处于长达4~5月的低温低浊期,温度一般维持在3~6℃,浊度一般在6~13NTU之间.本文利用聚合氯化铝(PAC)、聚合氯化铝铁(PAFC),通过经验数据法和正交试验等方法确定最佳投药量,使剩余浊度基本上降到0.5NTU以下,并且进一步考察水中其他因素,如氨氮、硬度、COD、电导率和pH的去除情况,其中COD随着混凝剂的投加有明显的去除效果,剩余含量在0.8mg/L左右,而氨氮在0.5 mg/L上下浮动.     

Ni掺杂对DOC催化剂Pt/Ce-Zr的改性研究

采用浸渍法制备了一系列Ni改性的Pt/Ce-Zr-O柴油机氧化催化剂(DOC催化剂),考察其催化氧化柴油机模拟尾气时的活性和抗硫性.活性测试结果表明:掺杂Ni以后的催化剂具有较好的低温活性,且以质量分数3%的Ni掺杂量为最佳,其催化氧化丙烯(C3H6)和CO的T50分别降低了约30℃和20℃.抗硫性测试发现,掺杂Ni后可抑制硫酸盐在催化剂表面的聚集,使催化剂的抗硫性能得到提高.