河道淤泥气泡混合土微观构造及力学性质相关性

基于河道淤泥气泡混合土(FMLSS)的微观构造特征,通过微观构造观察和分析,评价了FMLSS的强度特性和破坏机理。试验结果表明,保持FMLSS含水量一定,随着气泡掺入量的增加,FMLSS的内部平均等效孔径和气孔面积百分比含量呈线性增大趋势、而随着水泥掺入量的增加呈减小趋势;随着气泡掺入量的增加,FMLSS的气孔大小分布的均匀性降低,气孔平均等效孔径增大。试验结果还表明,FMLSS的强度发挥及破坏机理与FMLSS的气孔分布的均匀性以及等效孔径等微观构造参数存在明显的相关性。     

硫酸铵侵蚀作用下水泥砂浆的抗压强度试验研究

为了研究硫酸铵作用下水泥砂浆受腐蚀劣化的力学性能变化规律,通过室内试验研究,分别探讨了在不同水灰比、不同浓度、不同腐蚀龄期下对水泥砂浆的外观形态、质量变化、应力应变关系和抗压强度的影响.结果表明:硫酸铵对水泥砂浆的侵蚀性比较明显,腐蚀后砂浆抗压强度先有所下降然后上升,再下降;随着腐蚀的进行,水泥砂浆试块表面先开裂、剥落,再失去棱角,最后因膨胀而破坏;而溶液浓度越大,水泥砂浆受腐蚀的程度越深;低水灰比的水泥砂浆抵抗硫酸铵溶液腐蚀的能力越强.     

矿渣微粉再生骨料混凝土力学性能试验研究

以矿渣微粉等量取代水泥和使用再生粗骨料等质量取代天然粗骨料2个因素作为变量,利用均匀设计法设计16组试验方案,配制强度等级为C35的再生混凝土,对其抗压强度和工作性能进行试验,研究不同配方下再生骨料混凝土性能的影响规律,找出满足工程技术要求的最佳再生混凝土配合比。研究认为水胶比为0.4,水泥标号为P.O 42.5,矿渣微粉掺量为50%,废混凝土取代率为100%时,再生骨料混凝土实测28 d的强度为40.0 MPa,60 d的强度为42.1 MPa。     

Effect of rubber particles on cement stabilized gravel system

The primary objective of this paper was to study the mechanical properties and durability of the cement stabilized gravel by different compact method. The influence of rubber particle content on mechanical properties of samples was studied by compaction tests and freezing thawing recycle tests. Pore structure and fractal characteristic of mixture were analyzed quantitatively using mercury intrusion porosimetry （MIP）. X-ray diffraction （XRD） was adopted to identify the composition phases. The morphology analysis in micro scale and elemental analysis of samples were carried out by scanning electron microscope （SEM）. The optimum compressive strengths of rubber cement stabilized gravel （RCSG） with static compaction method and with vibratory compaction method were obtained by controlling compaction degree and vibration time, respectively. From the compaction tests, the vibratory compaction method is preferred compared with the static compaction method as better compressive strength can be improved by about 340%-360%. Besides, test results also reveal that compressive strength of samples with vibratory compaction method or static compaction method will decrease with the rubber particle bulk content increasing. The freezing thawing recycle tests indicate that freezing thawing resistance has been improved （frozen stability coefficient K has been increased from 0.89 to 0.97） by the addition of rubber particles. MIP tests show that the mean pore diameter and porosity of mixture have been increased from 70 to 250 nm and 9% to 24% respectively, with the rubber particles content increasing. Component analysis shows that the calcium silicate hydrate （CSH） is the predominant hydrate product with or without the addition of rubber particles.     

Mechanical properties of silica aerogels prepared from a mixture of TEOS and organo-alkoxysilanes of type R1SiX3

Silica aerogels were prepared from a mixture of tetraethylorthosilicate and organo- alkoxysilanes. The effects of organo-alkoxysilanes on the mechanical properties of the silica aerogels were studied. The flexibility of silica aerogels was significantly improved by incorporation of organo-alkoxysilanes. When MTES and TEOS were combined as precursors of silica areogels, with the increased amount of MTES, the apparent elastic modulus and apparent compressive strength monotonously rose. At the same organo- alkoxysilanes to TEOS ratio, the size of alkyl groups of the organo-alkoxysilanes had little effect on the mechanical properties. In series of MTES and TEOS, the lowest elastic modulus of silica skeleton and the highest compressive strength of silica skeleton were observed at MTES to TEOS ratio of around 50：50. At a certain organo-alkoxysilanes to TEOS ratio, the elastic modulus of silica skeleton increased and the compressive strength of silica skeleton decreased with the size increase of the alkvl grouns.     

Effect of rubber particle modification on properties of rubberized concrete

To improve the combination of cement matrix and waste tire rubber particles in concrete, the rubber particles were treated with acrylic acid（ACA） and polyethylene glycol（PEG） for grafting hydrophilic groups on their surfaces. The X-Ray photoelectron spectroscopy（XPS） and surface contact angle were used to characterize the hydrophilicity and surface functional group of rubber particles. The effect of rubber particle modifi cation on fresh/hardened properties of rubberized concrete was studied. The experimental results show that the contact angle between rubber particle surface and water decreases when rubber particle is modifi ed. Compared with the unmodifi ed rubberized concrete（RC）, the unit weight of modifi ed rubberized concrete（MRC） changes slightly. However, the slump, air-entrainment, compressive strength, flexural strength, and impact performance of MRC are obviously improved. Under good condition of slump, the water-cement ratio of the MRC can be reduced from 0.4 to 0.38. And the compressive strength and fl exural strength of the MRC（10% rubber particle content） can be increased by 25.9% and 26.4%, respectively.     

基于试验二维随机骨料再生混凝土抗压强度研究

制作42个再生混凝土立方体试块并测试其立方体抗压强度,基于二维随机骨料理论推导符合试验用粗骨料级配的二维骨料分布曲线,生成二维随机骨料混凝土有限元模型模拟其抗压强度并与试验结果进行对比.结果表明：再生混凝土抗压强度总体上随再生粗骨料取代率的上升而降低,但再生粗骨料取代率为50%时,试验与有限元模拟结果均存在强度升高的变异现象.随着再生粗骨料取代率的上升,再生混凝土抗压强度峰值应力对应的平均应变有所延后.     

适用于聚羧酸减水剂的混凝土激发剂研究

提出一种适用于聚羧酸减水剂的复合矿物混凝土激发剂,研究了在不同养护条件、不同掺量下,激发剂对混凝土工作性能及各龄期强度的影响,结合XRD,SEM物相检测探讨了激发剂作用机理,并在连江可门港口泊位工程中试用,测试了掺激发剂混凝土的耐久性能.宏观测试结果表明所研激发剂I型对混凝土工作性能影响不大,能够提高混凝土早期强度,且对后期强度及长期耐久性能无不良影响;微观分析表明激发剂I型的掺入加速了C2S,C3S等矿物的水化,并激发了粉煤灰、矿粉的二次水化反应,混凝土强度发展拐点提前出现.     

混杂纤维混凝土抗压和抗拉性能试验研究

为了研究钢-聚丙烯混杂纤维混凝土的抗压、抗拉性能和增强机理,制备和易性良好、可以泵送施工的素混凝土(PC)、聚丙烯纤维混凝土(PFRC)、钢纤维混凝土(SFRC)和混杂纤维混凝土(HFRC),对设计强度为C50的4种材料进行立方体抗压和劈裂抗拉试验。结果表明:HFRC的立方体抗压强度分别比PC、PFRC和SFRC的增加6.5%、10.9%和1.8%。HFRC的劈裂抗拉强度分别比PC、PFRC和SFRC的增加12.59%、7.04%和1.56%。可见,混杂纤维对立方体抗压强度和劈裂抗拉强度增长效果显著。PC和PFRC在试验中均发生脆性破坏,而SFRC和HFRC均发生延性破坏。通过对比4种材料的抗压和抗拉性能,可为混杂纤维的增强机理研究提供基础。     

机制砂对不同强度等级商品混凝土性能的影响

采用机制砂分别按照0%、25%、50%、75%和100%等量替代天然河砂制备C25~C55不同强度等级的泵送混凝土,研究机制砂对混凝土工作性和抗压强度的影响。结果显示,对于C25~C40强度等级混凝土,机制砂替代天然砂比例低于50%时对工作性影响不大;对于粉料量较高的C40以上混凝土,机制砂替代比例可提高到75%仍不影响工作性;但完全采用机制砂替代天然砂则容易造成离析;机制砂替代天然砂比例低于50%时对各强度等级混凝土的强度均无影响,对于高强混凝土则能够在低于75%的代砂率条件下强度都略提高,但完全采用机制砂替代天然砂则对各强度等级的混凝土抗压强度都不利。