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981.
Using chloroform/dimethylformamide (CF/DMF) co-solvent, electrospinning of poly[(R)-3-hydroxybutyrate] (PHB) solutions was carried out at ambient temperature. The effects of the applied voltage (V), flow-rate (Q), and solution viscoelastic properties on the Taylor cone, electrified jet, and fiber morphology were investigated. In addition, the electric field developed by the needle-plate electrode configuration was calculated using a finite element analysis to reveal the tip-to-collector (H) effect. Among the processing parameters (V, Q and H), it was found that Q played a key role in determining the jet diameter (dj) and electrospun fiber diameter (df), and scaling laws existed between them, i.e., dj-Q0.61 and df-Q0.33. The diameter reduction ratios of Do/dj (Do is the needle diameter) and dj/df were measured as 50-120 and 5-10, respectively; it suggested that major jet stretching took place in the straight electrified jet region, and further chain orientation could be gained by the subsequent process of jet whipping. By changing PHB concentrations from 5 to 15 wt%, the solution viscosity (ηo) was increased from 100 to 4900 cP, whereas the surface tension and solution conductivity remained unchanged; it provided a good model solution to exclusively reveal the ηo effect on the electrospinning process. Our results showed that the ηo-dependence of dj and df also followed simple scaling laws: dj-ηo0.06, and df-ηo0.39, with a prefactor depending on the processing variables, mainly the flow-rate. Regardless of the PHB concentrations used, the obtained PHB fibers showed a similar crystallinity fraction of ca. 0.63 and possession of major α-crystals together with a small amount of β-crystals with zigzag chain conformation. 相似文献
982.
Reda Karoum Antonio de Lucas-Consuegra Fernando Dorado Jose Luis Valverde Alain Billard Philippe Vernoux 《Journal of Applied Electrochemistry》2008,38(8):1083-1088
The electrochemical promotion of catalysis (EPOC) of propene combustion was investigated using Pt sputtered thin film on an
O2− conductor, 8 mol% Y2O3-stabilized-ZrO2 (YSZ). In order to separate the influence of the thermal migration of the O2− oxide ions from the electrolyte to the catalyst surface and the impact of an electrical polarization on the catalytic activity,
several light-off experiments (cool down and heat up procedures) were successively performed under different polarizations,
i.e. OCV, +2 and −2 V. These experiments have clearly shown that the presence of O2− (thermally or electrochemically induced) inhibits the catalytic activity of the platinum for the propene deep oxidation.
These results demonstrate the importance to define a normalized rate enhancement ratio, ρ
n
, from a reference value of the catalytic rate corresponding to a Pt surface state free of O2− ions. 相似文献
983.
S. Zisekas G. Karagiannakis C. Kokkofitis M. Stoukides 《Journal of Applied Electrochemistry》2008,38(8):1143-1149
The reaction of NH3 decomposition was studied on Ag in a proton conducting double chamber cell-reactor. The proton conductor was a strontia-ceria-ytterbia
(SCY) perovskite of the form SrCe0.95Yb0.05O3−α. The reaction was studied at 350–700 °C and atmospheric total pressure. The proton transference number (PTN) was calculated
by simultaneous measurement of the imposed current and the proton flux and it was found to vary between 0.5 and 0.7. The effects
of imposed current, temperature and inlet gas composition on the reaction rate and the PTN, were examined. Although the faradaic
efficiency (Λ) remained near unity in all experiments, reaction rate enhancements (ρ) as high as 57 were achieved. An up to
90% decrease in the activation energy of the reaction was observed when protons were electrochemically “pumped” away from
the catalyst. 相似文献
984.
985.
橡胶Mooney—Rivlin模型材料系数对轴向刚度影响分析 总被引:4,自引:0,他引:4
在橡胶小变形范围内,采用理论推断的方法,得到在相同硬度下橡胶Mooney—Rivlin模型材料系数由C2/C1决定的关系式。并采用ABAQUS有限元软件分析的方法,结合橡胶轴向刚度常规解,分析了C2/C1不同值对橡胶轴向刚度的影响进行,结果显示其影响呈现一定规律性。 相似文献
986.
介绍了windows环境下串行通信的核心,并以VC 为开发工具给出了I/O函数与API通信函数实现串行通信的具体编程步骤。 相似文献
987.
以脱硅锆、轻烧氧化镁、消石灰为原料,进行了MgO-ZrO2-CaO系原料的合成,研究了化学组成(包括ZrO2含量、CaO/ZrO2比),烧成温度,杂质等对合成料性能和组织结构的影响。 相似文献
988.
PbS-Sb2S3-FeS三元系在水蒸气气氛下的铅锑分离 总被引:1,自引:0,他引:1
在1073K下通过测定三硫化锑和硫化铅的挥发速度,研究了PbS-Sb_2S_3-FeS三元系在水蒸气气氛下的铅锑分离规律。X-射线衍射结果表明,焙砂由PbS、Fe_3O_4、FePb_4Sb_6S_(14)、Pb_5Sb_4S_(11)和FeSb_2O_4组成。当试样中FeS含量在5%~7%时,铅锑分离效果最好。当试样中FeS的含量≥10%时,铅锑分离效果较差,这时过量的FeS会与Sb_2S_3和PbS形成复杂的硫化物(FePb_4Sb_6S_(14)、Pb_5Sb_4S_(11))或被氧化成F4Sb_2O_4,使锑的挥发变得困难,导致残留在焙砂中的锑含量升高。 相似文献
989.
就当前我国正在运用的CAD/CAM软件特点做了归纳简介,提出使用我国自主版权的CAD/CAM系统软件已势在必行的观点,并认为其中的CAXA系列软件具有更多的优势,建议在科研、企业及高等职业技术教育中大力推广运用,以满足我国教学、科研和企业生产的发展需求。 相似文献
990.
综述了粉末冶金温压工艺的研究进展,概述了温压工艺的粉末原料、聚合物、温度、压力、烧结环节对温压工艺的影响和温压工艺的致密化机理。详细介绍了温压工艺的新进展—流动温压、高压温压等,并对其应用前景进行了展望。 相似文献