M8011H16铝合金防盗盖板生产工艺研究

研究了元素含量变化对8011铝合金防盗盖板综合性能的影响，在8011合金中改变Cu、Mn元素含量后可提高防盗盖板的强度，同时研究了烘烤处理后的强度变化问题。本文研究出了8011铝合金防盗盖板新的生产工艺制度。     

基于TiNi合金的超弹性对其相关磨损机制的FEM研究

本文在重点考虑TiNi合金高弹性变形量的前提下，采用等向强化模型，对不锈钢和超弹TiNi合金在法向接触载荷作用下的六种模型进行了有限元(FEM)分析。结果表明：在相同载荷条件下，超弹TiNi合金产生的von Mises弹性应变要高于不锈钢，但其von Mises应力和塑性应变却恰恰相反，在同一载荷下该合金发生塑性变形的区域要小于不锈钢；此外，超弹TiNi合金发生塑性变形要比不锈钢困难，所需的临界载荷值随其最大弹性变形量(屈服点处的应变值)的增加而增加。最后，基于本文的有限元计算结果对超弹TiNi合金的蘑粒磨损和疲劳磨损机制进行了讨论。     

不同磁场作用对AZ31镁合金的凝固组织的影响

镁合金是具有优越性能的金属材料,镁合金的加工是目前国内外正在深入进行研究的新课题.实验发现在镁合金的凝固过程中施加低频或静态磁场都能细化晶粒,但静磁场得到的细化效果要优于低频交流磁场,同时随磁感应强度的增加,静磁场细化晶粒的效果明显提高;在静磁场条件下晶界共晶体组织的厚度明显减小,同时在晶内出现了大量细小块状化合物,这有利于改善镁合金的综合性能.     

Kinetic Studies of the Thermal Decomposition of C60H2 in Solution

Thermal decomposition of C₆₀H₂ in C₆D₄Cl₂ solution at 236°C for 2 hours was shown to produce hydrogen as a product, the hydrogen production was successfully followed by NMR. In order to further explore the rule of thermal decomposition of C₆₀H₂, the dynamics of decomposition reaction was studied and the results showed this decomposition reaction accorded with first order reaction dynamical equation. The experiment temperature was ranged separately in 459K, 455K, 451K, and 446K.     

Crystalline Behavior and Magnetic Properties of Nd60Fe30-x Al10Cox（x = 0,5,10） Bulk Amorphous Alloys

Crystalline behavior and magnetic properties of Nd60Fe30-xAl10Cox( x = 0, 5, 10) bulk amorphous alloys were investigated by differential scanning calorimeter (DSC), X-ray diffraction (XRD) and the vibrating sample magnetometer (VSM). Neither glass transition nor supercooled liquid region before crystallization was observed for the as-cast Nd60Fe30-xAl10Cox ( x = 0,5,10) bulk amorphous alloys. The glass forming ability can be improved significantly by the addition of Co. The as-cast Nd60Fe30-xAl10Cox (x = 0,5,10) alloys show hard magnetic behavior. With the addition of Co content, intrinsic coercivity (iHc) increases while the saturation magnetization(σs) and remanence (σr) decrease. The Curie temperature for the as-cast Nd60Fe30-xAl10Cox alloys increases from 451 K for x =0 to 468 K for x = 10. Some pre-cipitation of crystalline phases does not affect the hard magnetic properties of Nd60Fe30-xAl10Cox(x = 0,5,10) alloys, while the hard magnetic behavior disappears quickly after the alloys being completely crystallized.     

Influence of Ni Interlayers on the Mechanical Properties of Ti6Al4V/(WC-Co) Friction Welds

Ni interlayers were introduced prior to dissimilar friction welding of Ti6Al4V base material to three cemented carbide substrates. The fracture strength of Ti6Al4V/(WC-6 wt% Co) welds were poor and were markedly improved when 20-µm thick Ni interlayers were introduced prior to dissimilar friction welding. These results were only produced when the (WC-6 wt% Co) cermet was electroplated prior to friction welding. When the Ti6Al4V alloy was electroplated prior to friction welding, fractured WC particles and cracking were observed in the (WC-Co) carbide substrate. The fracture strengths of Ti6Al4V/(WC-11 wt% Co) and Ti6Al4V/(WC-24 wt% Co) welds were not improved when 20-µm thick Ni interlayers were introduced prior to friction welding. During mechanical testing, the Ni layer retained at the dissimilar joint interface created a region of weakness.     

Two Isomers of C60F48: Computed Inter-isomeric Equilibrium

C₆₀F₄₈ has been known to exist in two isomeric forms of D₃ and S₆ symmetries. However, the quantum-chemical calculations have not agreed on their stability order though a near-isoenergetic picture is otherwise always encountered. In order to clarify the situation, the entropy effects are evaluated for synthetic temperatures of about 500K. The entropy evaluations suggest that the D₃ isomer should be more stable in the potential energy by 2.05-2.55 kcal/mol (to which term the ab initio data are closer than the semiempirical ones).     

W-Ni-Cu高比重合金注射成形烧结收缩及性能的研究

研究了W-Ni-Cu高比重合金注射成形工艺过程收缩率和性能。比较了模具尺寸、注射坯尺寸、烧结坯尺寸，及烧结阶段各方向收缩率的关系，发现实际收缩与理论预测收缩率较为一致，但在厚度方向存在与其他方向收缩不一致的情形，这与由重力作用产生的塑料流动有关；还探讨了烧结坯密度与烧结条件的关系，测定了烧结坯的力学性能及断口形貌、金相组织，烧结坯在1400℃，90min烧结达到了99％的相对密度，断裂强度600MPa以上。     

国内钛合金近几年学术研究进展

在钛合金研发受到高度重视的同时,相关钛合金的基础研究国内也较重视,取得了较好的成绩,如发展的近β锻造技术、准β锻造技术、三态组织、阻燃机理、低温变形机理、原子与空位的交互作用等等。本文综述了国内钛合金近几年的学术研究进展。     

Ti-45Al-10Nb合金的高温氧化行为

研究了Ti—45A1—10Nb(原子分数，％)合金在800-960℃在氧气和空气中的氧化行为．结果表明，该合金具有较好的高温抗氧化性能，其氧化增重速率与铁基耐热不锈钢相似或略优．与Ti—50A1合金相反，Ti-45A1-10Nb合金在空气中的氧化增重速率明显低于在纯氧中的氧化增重速率．X射线衍射与能谱分析表明，Ti-45Al一10Nb合金在氧气中的氧化产物主要有TiO2和Al2O3，但在空气中的氧化产物中有TiN相．这是降低氧化速率的主要原因，同时，合金元素Nb稳定了氧化层中的TiN相，因而提高了合金在空气中的抗氧化性能．