铸铁表面化学镀Ni-P合金络合剂的研究

针对化学Ni-P镀过程中镀液稳定性差、使用寿命短、沉积速率低和pH范围窄等问题,采用对比实验和正交实验方法,以镀速、孔隙率、稳定性和镀层硬度为评价指标,研究了乳酸、苹果酸、柠檬酸和丁二酸络合剂及复合络合剂对镀液和镀层性能的影响.研究得到最优的铸铁表面Ni-P镀的复合络合剂配方为:乳酸20ml/L,苹果酸9g/L,丁二酸6g/L.此复合络合剂配方配制化学镀镍液可使镀速达到14.5μm/h,孔隙率降至0.45个/cm2,稳定性提高到3500s,硬度达620HV.     

用于铸铝模具的中硅耐热铸铁的研制

某铝厂要求制备良好的耐热性及综合力学性能的模具，并尽量降低制造成本，为此进行了试验研究。试验通过添加一定量的Cr、Al、Cu等合金元素制备耐热球墨铸铁，并在此基础上不断调整碳硅含量，使其在一定范围内性价比达到最优。最终得到制备铸铝用模具的优良材料，其配比为（质量分数）：2．7％C，5．0％Si，0．7％Cr，0．6％Ca，0．5％Al。     

耐热铸造镁合金的研究现状及其发展趋势

耐热铸造镁合金在航空航天以及汽车工业等领域得到了广泛应用。本文主要介绍了Mg-Al系、Mg-Zn系和Mg—RE系耐热铸造镁合金的研究现状；对新型高性能耐热镁合金的发展趋势提出了一些见解，指出，合金化方法作为解决镁合金高温性能不足的最有效的手段之一，应该进一步通过优化合金元素组合，进行有效的合金设计，解决铸造镁合金在耐高温、抗蠕变等方面存在的问题。     

覆膜砂离心铸造球墨铸铁管性能的研究

论述了以覆膜砂离心铸造和用含锰及微量元素含量较高的再生铁进行球化处理浇注球铁管的方法，研究了模内孕育，随流孕育和金属铋孕育对铸态球铁管塑性的影响，考察了锰，硅和碳当量及衬砂层厚度对铸态球铁管塑性的影响规律。     

球墨铸铁Dg75阀体消失模近净型铸造

介绍消失模工艺生产Dg75闸阀阀体铸件的铸造工艺，生产过程中铸件重要装配尺寸精度的保证，铸件表面粗糙度、铸件表面碳夹杂缺陷及表面皱皮现象控制等试验情况。通过模具结构设计、成型工艺及参数的调整、浇注工艺的调整、陶瓷成型浇道的应用等措施，使铸件表面质量及尺寸精度符合客户验收标准。同时使铸件表面因轻微缺陷的返修率由试验初期的90％下降到10％以内，产品合格率达到99％。     

Influence of chromium on the local structure and morphology of ferric oxyhydroxides

The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO₆ octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM.     

数值模拟在消除球墨铸铁轮毂缩孔中的应用

采用华铸CAE软件对球墨铸铁轮毂的凝固过程进行了模拟。通过模拟优化了铸造工艺，成功地消除了轮毂铸造过程中产生的缩孔、缩松缺陷。模拟结果与实际生产情况符合较好。结果表明：计算机模拟能为工艺方案的评价和改进提供有效的参考依据。     

Wear Mechanism when Machining Compacted Graphite Iron

The industrial application of compacted graphite iron in the automotive industry is taking a rather long time due to its uneconomic machinability, because of a significant decrease in tool life. After six years of holistic research of the PTW in cooperation with foundries, manufactures and material scientists, the wear mechanism was understood and clarified: Sulphur in the microstructure of compacted graphite iron has direct influence on the formation of a manganese-sulphur layer on the cutting edge. For machining gray cast iron this layer protects the cutting edge against abrasive wear. Therefore the design of cutting tools for the machining of CGI must consider the absence of manganese-sulphur layer.     

Preparation of a two-dimensional polymer film on passivated iron by modification of a carboxylate ion self-assembled monolayer with alkyltriethoxysilanes for preventing passive film breakdown

The effect of an ultrathin, regularly arranged polymer film on prevention of passive film breakdown on iron in the presence of chloride ion was investigated. The film of two-dimensional polymer was prepared by modification of a 16-hydroxyhexadecanoate ion self-assembled monolayer adsorbed on a passivated iron electrode with 1,2-bis(triethoxysilyl)ethane(C₂H₅O)₃Si(CH₂)₂Si(OC₂H₅)₃ and octyltriethoxysilane C₈H₁₇Si(OC₂H₅)₃. The pitting potentials of the passivated electrodes bare and covered with the polymer film were determined by anodic polarization measurements in a borate buffer solution containing 0.1 M of Cl⁻. The pitting potential of the coated electrode was higher than that of the uncoated one, indicating prevention of passive film breakdown. No breakdown was observed over the potential range in the passive and transpassive regions by covering the passive film with the well-arranged two-dimensional polymer film. The film was characterized by X-ray photoelectron and FTIR reflection spectroscopies and measurement of the contact angle with a drop of water.     

消失模铸铁件表面渗Cr工艺研究

在泡沫模表面涂覆富铬涂层，利用液态铸铁浇铸时的高温和液态铁水的作用，使涂层被烧结成合金层，同时，涂层中的铬渗入铸铁基体组织中，形成渗铬层。该工艺可以使铬渗入到铸铁基体中达100μm以上，合金化层与基体具有良好的冶金结合。由外向内，表层显微组织依次为烧结层、合金化层和基体层。烧结层是熔解了一定量合金元素的铁素体，合金化层为珠光体，基体层是珠光体＋片状石墨。沿着试样深度方向，显微硬度变化逐渐升高后再缓慢下降．显微硬度变化在250-350HV之间。