草酸改进铁/铜微电解体系降解活性艳蓝KN-R

在铸铁上负载铜的铁/铜催化微电解体系中加入草酸后,质量浓度为100 mg/L活性艳蓝KN-R溶液迅速脱色,化学需氧量明显降低,改善了微电解体系对废水处理时间长、化学需氧量去除效果低等缺点.实验结果表明:在pH为3.28(加入草酸后)、草酸投加量为5 mg/L、催化剂投加量为10 g/L的条件下,对质量浓度为100 mg...     

微电解-混凝沉淀-生化法处理松脂加工废水

介绍了采用微电解-混凝沉淀-生化法处理松脂加工废水的调试操作．在微电解处理过程中,当进水CODcr为976～2012mg／L时,出水CODcr为262～296mg／L,CODcr的平均去除率为79．3％;在生化处理过程中,当进水CODcr为342—415mg／L时,出水CODr,控制在100mg／L以下,CODcr的平...     

离子膜车间杜邦膜监测工作总结

通过对杜邦膜NX2002TX和旭硝子公司的F-893膜在第1年应用中运行数据的比较。证明在使用第1年内，NX2002TX膜的性能高于F-893膜。     

泡沫铝填充在轿车B柱中的侧面耐撞性研究

为了提高轿车侧面耐撞性,设计耐撞性能强的B柱成为主要课题之一.目前的优化方法很难将B柱侵入量和侵入速度同时控制在理想范围内.因此,提出泡沫铝材料填充在汽车B柱内代替B柱加强板的方法,缓冲侧面碰撞冲击.通过建立泡沫铝有限元模型与材料特性分析,确定仿真泡沫铝主要材料参数.进而根据中国新车评价规程C-NCAP要求,建立轿车整车侧面碰撞有限元模型,采用LS-DYNA软件进行仿真分析.结果表明,泡沫铝填充后的B柱侵入量和侵入速度都有明显降低.泡沫铝材料塑性变形和整体弯曲变形能够吸收1.51kJ的能量,是B柱加强板的3倍.填充泡沫铝前后仿真结果表明,轿车B柱填充泡沫铝是一种提高轿车侧面耐撞性的方法.     

含稀土合金活性阴极的研究

简明回顾了活性阴极的应用，介绍了用熔炼合金法制取含稀土合金阴极的电催化性能、抗反电流性能，指出了该种电极克服现行镀层电极寿命短的缺点，在氯碱工业及水电解工业中具有广阔的应用前景。     

Kinetics and mechanism of ?-caprolactone and l,l-lactide polymerization coinitiated with zinc octoate or aluminum acetylacetonate: The next proofs for the general alkoxide mechanism and synthetic applications

Following our previous papers on mechanism of cyclic esters' polymerization coinitiated by tin(II) octoate [tin(II) bis-(2-ethylhexanoate), (Sn(Oct)₂)] in the presence of either the low molar mass coinitiator (an alcohol, hydroxy acid, or H₂O) or a macromolecule fitted with a hydroxy end group (ROH), the present work deals with ?-caprolactone (CL) and l,l-lactide (LA) polymerizations coinitiated with zinc octoate (Zn(Oct)₂) or aluminum acetylacetonate (Al(Acac)₃). A series of kinetic measurements revealed that similarly as in the Sn(Oct)₂ coinitiated process, these polymerizations proceed by simple monomer insertion into the …Mt-OR bond, reversibly formed in the reaction -Mt-L + ROH ? …-Mt-OR + LH (where Mt = Sn, Zn or Al; L = Oct or Acac), taking place throughout the whole polymerization process. MtL_n itself does not play an active role in the polymerization. Applicability of the commercially available Zn(Oct)₂ or Al(Acac)₃ for the aliphatic polyester (10³ ≤ M_n ≤ 4 × 10⁵) synthesis is also discussed.     

间羟基二乙基苯胺生产废水预处理研究

间羟基二乙基苯胺是一种染料中间体,其生产废水CODCr高,成分复杂。应用曝气吹脱 电解法对其高盐废水预处理工艺进行了可行性的研究,建立了曝气吹脱 电解法预处理方案。曝气吹脱与电解法的CODCr去除率分别可达20%与80%,提高了可生化性,便于后接生化处理。经实验优选最佳工艺参数为:曝气吹脱pH值4 0,曝气吹脱时间90min;电解进水pH值7 0左右,电解外加电压7V,电解停留时间120min,电极板间距3cm。     

LC4铝合金高温变形规律的探讨

研究LC4铝合金的高温变形规律 ,拟合出具有较高精度的高温本构模型。并应用所开发的一套数值模拟软件系统 ,对LC4铝合金的高温压缩规律及压缩过程进行了分析。     

Use of acoustic emission technique for the early detection of aluminum alloys exfoliation corrosion

Exfoliation corrosion of aluminum alloys is a form of localized corrosion which affects many industries, specially aeronautics. The study of this corrosion mode using only electrochemical techniques is not fully efficient for the detection and control on line of this phenomenon. Therefore, we developed a non-destructive testing technique based on the acoustic emission recordings in order to follow-up this form of corrosion on aluminum alloys. Indeed, recent works have shown the interest of the acoustic emission for the detection, the monitoring and the localization of pitting corrosion on aluminum alloys. This pitting corrosion phenomenon is currently well understood and the experimental methodology acquired during that study is transposed to the study of exfoliation corrosion of aluminum alloys.The present study is conducted on two aluminum alloys: (Al 2024 T3, and Al 7449 T6 and T7). Samples are immersed 4 days in the modified ASTM STP 1134 saline solution. Observations of the structures after tests show that the exfoliation corrosion sensitivity of alloy 7449 T6 is more important than for alloy 7449 T7 which exhibits only the presence of small and non-occluded pits. Very severe exfoliation corrosion was also observed on Al 2024 T3, but after a longer immersion time or in a more acid solution.The recording of the acoustic emission activity shows evident links between this activity and the exfoliation corrosion rate. The analysis of the signal's characteristics reveals a population corresponding to the release of hydrogen bubbles. A few more energetic signals have also been observed. Their source can be either, the cracking resulting from the separation of sheets of metal, or the development and evolution of hydrogen bubbles formed inside blisters during exfoliation corrosion.     

压铸模与铝合金金属间化合物的形成与分解

为了研究压铸模与铝合金金属间化合物的形成与分解过程，进行了热浸铝试验。试验结果表明金属间化合物的形成与分解是一个连续不断的循环过程，两者之间的相互关系导致了钢基的失效以及体积的减少。