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181.
简要介绍了我国铝电解工业的发展现状,指出了我国预焙铝电解槽寿命短的弊端;并分析了电解槽早期破损的原因和采用TiB2阴极涂层技术提高电解槽寿命的机理;叙述了新一代常温固化TiB2阴极涂层的特点,并强调应用新一代常温固化TiB2阴极涂层技术,提高电解槽寿命,是符合我国国情且行之有效的措施。 相似文献
182.
在对非正常阳极效应进行分析的基础上,提出和研究了非阳极效应的判断和处理方法,可有效地预防非正常效应的发生,减少效应系数,使效应能够按照设定的间隔发生,维持电解槽的高效平稳运行,从而达到提高铝厂经济效益,减少环境污染的效果. 相似文献
183.
NiFe2O4基金属陶瓷的电导率 总被引:1,自引:2,他引:1
制备了铝电解用NiFe2O4基金属陶瓷惰性阳极,研究了环境温度及材料成分对电导率的影响.实验结果表明NiFe2O4基金属陶瓷的电导率主要受温度、陶瓷基体电导率、金属成分及金属相在陶瓷相中分散度的影响;当温度从573 K升至1 233 K时,NiFe2O4陶瓷的电导率由0.099 S/cm提高到2.105 S/em;与NiFe2O4陶瓷相比,金属陶瓷的电导率有极大的提高,但二者随温度的变化趋势是一致的;1 233 K时,金属含量为5%Ni,5%Cu和4.25%Cu+0.75%Ni的NiFe2O4基金属陶瓷的电导率分别为20.576 S/cm,14.970 S/cm和18.797 S/cm,用作铝电解惰性阳极已能满足要求,但与当前铝电解碳素阳极材料相比还存在很大距离. 相似文献
184.
185.
利用有限元软件ANSYS,建立了包含摇篮架在内的铝电解槽完整的有限元模型。针对沈阳铝镁设计研究院设计的300kA铝电解槽,进行了三维电热场耦合分析。模拟结果说明所建模型是正确的,为电解槽的优化设计和改造提供参考。 相似文献
186.
针对电解铝生产中出现的含镁电解质体系性质进行了探讨。对生产中出现的操作问题,系统的分析了原因,并结合生产实际找出了应对措施。 相似文献
187.
The current aqueous cleaning step in the surface preparation of aluminum nitride (AlN) prior to metallization causes performance and reliability issues for the substrates used for microelectronic packaging due to surface reactions. These issues limit the use of AlN and its replacing of BeO, an environmentally hazardous material currently used. The aim of this investigation was to determine the effects of different solutions on the surface of AlN substrates under varying conditions at times up to 2419.2 ks (28 days). Concentration of the solutions, temperature, and immersion time were varied for the AlN samples in the solutions. Both elevated temperatures (50°C and 90°C) and low temperatures (5°C) were investigated.
Four general types of behavior were observed: minor changes in average surface roughness and microstructure, linear change in average surface roughness and pitted grains, nonlinear change in average surface roughness and product formation on AlN surface, and miscellaneous change in average surface roughness with surface product formation.
The surface roughening kinetics were very complex due to changes in both the reaction product morphology and reaction mechanism with temperature, solvent, and pH for a specific solvent. Minor changes in average surface roughness and microstructure were observed for HCl pH = 5, H2 SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, deionized water and Alfred tap water at 5°C, HCl pH = 3 and oleic acid at 50°C and citric acid and oleic acid at 90°C. Linear changes in average surface roughness and pitted grains were observed for HCl pH = 2 and H2SO4 pH = 3 at 50°C and HCl pH = 2, H2SO4 pH = 3, and deionized water at 90°C. Non-linear change in average surface roughness and product formation on AlN surface was observed for HCl pH = 5, NaOH pH = 8 and Alfred tap water at 50°C and HCl pH = 5 and H2SO4 pH = 2 at 90°C. Miscellaneous changes in average surface roughness with surface product formation were observed for H2SO4 pH = 2, H2SO4 pH = 5, NaOH pH = 10, NaOH pH = 12, citric acid, Micro-90 and deionized water at 50°C and HCl pH = 3, H2SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, Micro-90 and Alfred tap water at 90°C. 相似文献
Four general types of behavior were observed: minor changes in average surface roughness and microstructure, linear change in average surface roughness and pitted grains, nonlinear change in average surface roughness and product formation on AlN surface, and miscellaneous change in average surface roughness with surface product formation.
The surface roughening kinetics were very complex due to changes in both the reaction product morphology and reaction mechanism with temperature, solvent, and pH for a specific solvent. Minor changes in average surface roughness and microstructure were observed for HCl pH = 5, H2 SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, deionized water and Alfred tap water at 5°C, HCl pH = 3 and oleic acid at 50°C and citric acid and oleic acid at 90°C. Linear changes in average surface roughness and pitted grains were observed for HCl pH = 2 and H2SO4 pH = 3 at 50°C and HCl pH = 2, H2SO4 pH = 3, and deionized water at 90°C. Non-linear change in average surface roughness and product formation on AlN surface was observed for HCl pH = 5, NaOH pH = 8 and Alfred tap water at 50°C and HCl pH = 5 and H2SO4 pH = 2 at 90°C. Miscellaneous changes in average surface roughness with surface product formation were observed for H2SO4 pH = 2, H2SO4 pH = 5, NaOH pH = 10, NaOH pH = 12, citric acid, Micro-90 and deionized water at 50°C and HCl pH = 3, H2SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, Micro-90 and Alfred tap water at 90°C. 相似文献
188.
189.
S. Garcia A. Amrouche G. Mesmacque X. Decoopman C. Rubio 《International Journal of Fatigue》2005,27(10-12):1347
Fatigue damage accumulation of cold expanded hole in aluminum alloys used in land transportation components was investigated. Tests were carried out using pre-cracked SENT specimens and inserting an expanded hole at the crack tip. The degree of the cold expansion was chosen equal to 4.3%. Tests were performed in two and four block loading under constant amplitude. Two sequences were compared.The increasing and the decreasing magnitude were compared. The experimental results were compared to the damage calculated by the Miner's rule and a new simple fatigue damage indicator. This comparison shows that the ‘model of the damage stress’, which take into account of the loading history, yields a good estimation of the experimental results. Moreover, the error is minimized in comparison to the Miner's model. 相似文献
190.
隔膜电解法净化再生镀锌钝化液的研究 总被引:4,自引:0,他引:4
采用隔膜电解法净化再生国营159厂的镀锌钝化液,结果表明,此法具有设备简单,技术可行,经济合理,不需要化学药品,没有二次污染等优点,其最佳工艺条件是;电流密度6A/dm^2,槽电压4.5V,温度40℃,电解时间为8小时。通过方法可以使废钝化液净化再生直接回用于钝化槽。 相似文献