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61.
62.
Ruojun Lao Lihua Wang Ying Wan Jiong Zhang Shiping Song Zhizhou Zhang Chunhai Fan Lin He 《International journal of molecular sciences》2007,8(2):136-144
In this work, we reported the investigation on the interaction between DNA strands self-assembled at gold electrodes and an electron transfer protein, cytochrome c. We observed that cytochrome c exhibited well-defined electrochemistry in both double-stranded and single-stranded DNA films. This suggested that the electron transfer reaction of cytochrome c arose possibly due to the electron hopping along DNA strands rather than wiring along the double helix. We also compared the heterogeneous electron transfer rate of cytochrome c with that of a ruthenium complex, which further confirmed this mechanism. 相似文献
63.
矿山开采过程中采空区地表往往会发生形变,研究其最大下沉值对安全生产具有重要意义,现有的开采最大下沉估算方法还有提升的空间。基于岩移数据决策与极限训练机(Extreme learning machine,ELM)算法,提出了一种估计最大下沉的新方法。该方法将采厚、倾角、平均采深、走向长度、倾向长度和覆岩岩性确定为最大下沉值影响因素;应用以Sigmoid方程为核函数、隐含层神经元个数为114的ELM模型对最大下沉值进行了估算。通过案例分析,ELM模型得到了优于传统算法如CHAID、Boosted Tree、ANN、BPNN和SVM的RMSE、MAE、MAPE、最大残差及秩相关系数,故认为该模型是一种有效的矿山开采最大下沉估算方法。 相似文献
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65.
贵州省磷化工现状及发展前景 总被引:3,自引:0,他引:3
阐述贵州磷资源、煤炭、电力基本情况及在全国的地位和我省发展磷化工的重要意义。介绍我省磷化工生产现状、生产能力、实际产量、产品出口等情况。对世界磷化工产品市场需求,我国和我省的磷化工到2000年的发展情况,达到的目标进行初步援测和构想,并对我省磷化工发展对策进行探讨,提出几点建设性意见。 相似文献
66.
Thiosulfate has been considered as one of the most promising of the non-toxic alternatives to cyanide for the leaching of gold and much work has been carried out with the aim of understanding and improving the ammoniacal thiosulfate leaching process. In particular the behaviour of gold in thiosulfate solutions containing copper in the absence of ammonia has received little attention. It has been shown in this study involving electrochemical and leaching tests that copper ions catalyze not only the oxidation of thiosulfate but also the dissolution of gold in alkaline thiosulfate solutions. Electrochemical studies have shown that copper has a positive effect on the anodic dissolution of gold with increasing concentrations of copper resulting in higher dissolution rates of gold at a potential of 0.3V. Studies on the dissolution of gold powder in alkaline oxygenated thiosulfate solutions containing low concentrations of copper have shown that the role of copper in enhancing the dissolution rate of gold is possibly associated with the formation of a copper–thiosulfate–oxygen intermediate which is more reactive in terms of cathodic reduction than dissolved oxygen. The electrochemical experiments have been complemented by a leaching study which has shown that milling of gold powder in the presence of copper (added as ions, metal, or oxide) assists with the dissolution of gold in thiosulfate solutions. 相似文献
67.
Rock phosphate fractions were examined for their porous structure by nitrogen adsorption. The pore size distribution and the shape of pores does not seem to depend on the particle size. The specific surface area values present two regions, one above and one below that of the particles with 125 μrn diameter. Particles of a given size were leached with dilute phosphoric acid (1.5 mass% P2O5) at 25°C. It was observed that there is a widening of the initial pores during leaching. The particles collected at the initial period of the reaction are pitted and those collected at the final period are disintegrated. 相似文献
68.
铜及其合金电解仿金着色工艺 总被引:1,自引:0,他引:1
详细介绍了一种铜及铜合金阴极还原着仿金色工艺及其配方。探讨了该工艺的着色原理、电流密度的影响及所得着色膜层的性能。结果表明,该工艺所得的膜层呈金黄色,结晶致密,耐蚀性好。 相似文献
69.
Daizo Kunii 《Chemical engineering science》1980,35(9):1887-1911
A general procedure is proposed for innovative research and development of gas-solid reactor systems, with a brief explanation of the significance of each step in the procedureBased upon the contacting mode between gas and solid phases, as well as the ways of supplying thermal energy to the reacting regions, various types of gas-solid reactor systems are classified by using tables of so called “matrix” form, for thermal cracking and gasification of heavy oils, gasification of coal, gasification of solid waste, calcination of limestone, clinkering of cement and reduction of iron ore.The importance of fundamental concepts is emphasized for successful research and development by presenting several examples; namely, calcination of limestone, thermal cracking of heavy oils and gasification of solid waste materials.In connection with the direction in which fundamental research should be oriented, four primary ways of thinking are proposed, which can be applied to obtain innovative ideas for further research and development in this field.One example of the author's practical experience was selected to show the role of the fundamental research in the course of large scale development. Finally the author outlines the role of chemical reaction engineering to innovate the novel gas-solid reactor systems which may be inevitable for simultaneous solution of the three big E's; namely, Energy, Environment and Economy. 相似文献
70.