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11.
Galvanostatic steady state current potential measurements were carried out for oxidation of a series of aliphatic alcohols having varying number of hydroxyl groups. The anodically deposited layer of MnO2 on platinum was used as the electrode material. The deposit was characterised by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX) and electrode potential measurements. The catalytic role of MnO2 in the electro-oxidation of alcohols was indicated by the chronopotentiograms and the cyclic voltammograms. An analysis of the electrochemical data indicated a catalytic EC mechanism in which Mn (V) is generated electrochemically and consumed chemically in succession. Based on this and the hydrogen bonding interaction between alcoholic hydroxyl groups and MnO2 layer, a mechanism was proposed which accounts for the variation in the observed electrochemical reaction orders. Tafel behaviour was found to be followed only approximately. Current efficiency of the electrochemical oxidation of polyols was studied. Replacement of platinum by carbon as current collector was found to leave the electrocatalytic activity of the MnO2 deposit practically unaltered.  相似文献   
12.
The electrooxidation of phenylethanolamine (2-amino-1-phenylethanol) at a gold electrode in alkaline electrolyte has been studied. Measurement of the differential capacitance of the electric double layer versus the electrode potential has shown that the adsorption of phenylethanolamine at the gold-solution interface plays a significant role in the oxidation mechanism. The effect of amine concentration, electrolyte pH and potential scan rate on the electrooxidation is analysed.  相似文献   
13.
14.
The reaction of NH3 decomposition was studied on Ag in a proton conducting double chamber cell-reactor. The proton conductor was a strontia-ceria-ytterbia (SCY) perovskite of the form SrCe0.95Yb0.05O3−α. The reaction was studied at 350–700 °C and atmospheric total pressure. The proton transference number (PTN) was calculated by simultaneous measurement of the imposed current and the proton flux and it was found to vary between 0.5 and 0.7. The effects of imposed current, temperature and inlet gas composition on the reaction rate and the PTN, were examined. Although the faradaic efficiency (Λ) remained near unity in all experiments, reaction rate enhancements (ρ) as high as 57 were achieved. An up to 90% decrease in the activation energy of the reaction was observed when protons were electrochemically “pumped” away from the catalyst.  相似文献   
15.
惠志林  高云  李明  崔舜  余成洲 《稀有金属》2003,27(6):734-737
介绍了一种复合金属多孔体的制备及其方法,首先以泡沫塑料为芯膜,经过导电化处理使其具有导电性,其次进行电沉积金属铁,再进行电沉积金属镍,经过热处理后可制备出复合金属多孔体。该复合金属多孔体用铁取代金属镍,其抗拉性能优于单质泡沫镍,同时可以降低制造成本,主要用于载体如电池电极。  相似文献   
16.
在近几年的InAs/GaAs自组织量子点的研究中,如何荻得1.3~1.55μm。长波长量子点材料是一个很热门的课题。本文综述了各种延长自组织InAs/GaAs量子点发光波长的方法,并提出了实用化的最佳途径。  相似文献   
17.
J.-C.  H.-H.  C.-T.  D.-M.  A.S.  J.-M.   《Sensors and actuators. B, Chemical》2005,110(2):364-369
We report here a non-enzymatic detecting electrode strip for fast monitoring of uric acid in human whole blood. A single-use amperometric uric acid sensor strip, incorporating a three-electrode configuration, has been fabricated on a polypropylene substrate using low cost screen-printing (thick-film) technology. Both the working and counter electrodes were prepared by screen-printing commercial carbon ink. The integration on the same support of pseudo-reference electrode was obtained by screen-printing a commercial silver ink and subsequent electrochemical pretreatment. Simply by placing a 20 μl human whole blood drop on the strip is enough for uric acid analysis by square-wave voltammetry. Real human whole blood samples were analyzed by this method and compared to the phosphotungstic acid clinical test procedure with satisfactory results.  相似文献   
18.
Abstract— Among various barrier‐rib manufacturing processes, the mold‐pattern‐transfer method has potential to reduce processing cost as well as the manufacture of high‐resolution pixels. In this study, the effects of major processing variables of the mold‐pattern‐transfer process on the formation of air‐trapped pores within barrier ribs were examined. The results indicated that with an optimum combination of the processing variables, barrier ribs without trapped defects can be produced, demonstrating the possibility of reducing the number of processing steps and costs of barrier ribs.  相似文献   
19.
孙德辉 《福建分析测试》2002,11(4):1658-1659
采用微波高压制样技术,快速提取饲料中的氟元素,结合氟离子选择性电极标准添加和电位极差测试方法,能够快速、准确地测试饲料中的含氟量  相似文献   
20.
Abstract— A low‐voltage (~10 Vrms) and high‐transmittance (~90%) polymer‐stabilized blue‐phase liquid‐crystal (BPLC) device with a slanted‐electrodes structure is proposed. Unlike the vertical‐field‐switching (VFS) mode in which oblique incident light and a vertical field are employed, the proposed device utilizes normal incident light and an oblique field. The slanted electrodes generate a strong and uniform oblique electric field, which contributes in obtaining low voltage and high transmittance. Moreover, no couple films or prism sheets are needed, which helps to enhance the optical efficiency and simplify of the device structure. This device has great potential application for emerging BPLC displays and photonic devices.  相似文献   
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