An effective rhodium catalyst system on the synthesis of acetic acid from methyl formate

Rh/Lil/SnR₄ is an effective catalyst system for the conversion of methyl formate to acetic acid under carbon monoxide pressure. The effects of solvent and initial CO partial pressure on the turnover rate of the reaction were investigated. The possibility of replacing some of the iodide promoters by tin compounds has been probed.     

回顶法灌注混凝土浆成桩工艺

探讨了回顶法灌注混凝土浆的成桩工艺，分析了影响混凝土浆灌注质量的主要因素，并给出了相应的技术参数和措施。     

高镁瓷工艺特性研究和应用

本文总结了ＭｇＯ－ＳｉＯ２－Ａｌ２Ｏ３系的高镁瓷配方、增塑及烧成工艺特性的研究过程与应用结果；介绍了适应大生产的高镁瓷制作工艺。     

On the boundary-layer control through momentum injection: Studies with applications

The concept of moving surface boundary-layer control, as applied to a Joukowsky airfoil, is investigated through a planned experimental programme complemented by numerical studies. The moving surface was provided by rotating cylinders located at the leading edge and/or trailing edge as well as top surface of the airfoil. Results suggest that the concept is quite promising, leading to a substantial increase in lift and a delay in stall. Depending on the performance desired, appropriate combinations of cylinder geometry, location and speed can be selected to obtain favourable results over a wide range of angle of attack. Next, effectiveness of the concept in reducing drag of bluff bodies such as a two-dimensional flat plate at large angles of attack, rectangular prisms and three-dimensional models of trucks is assessed through an extensive wind tunnel test-programme. Results show that injection of momentum through moving surfaces, achieved here by introduction of bearing-mounted, motordriven, hollow cylinders, can significantly delay separation of the boundary-layer and reduce the pressure drag. The momentum injection procedure also proved effective in arresting wind-induced vortex resonance and galloping type of instabilities. A flow visualization study, conducted in a closed-circuit water tunnel using slit lighting and polyvinyl choride tracer particles, adds to the wind-tunnel and numerical investigations. It shows, rather dramatically, the effectiveness of the moving surface boundary-layer control (MSBC). The Sabita Chaudhury Memorial Lecture The models were fabricated in the Mechanical Engineering Workshop. The assistance of M/s E Abell, P Hurren and D Camp in the design and construction of the models is gratefully acknowledged. The investigation was supported by the Natural Sciences and Engineering Research Council of Canada, Grant No. A-2181.     

ON THE MODELLING OF PARTICLE-BODY INTERACTIONS IN STOKES FLOWS INVOLVING A SPHERE AND CIRCULAR DISC OR A TORUS AND CIRCULAR CYLINDER USING POINT SINGULARITIES

Few exact solutions of the Stokes equations are known, even for steady or quasi-steady flows, involving finite sized bodies, and numerical techniques generally have to be resorted to for finding solutions. However, quite effective modelling of flows involving complicated boundary geometries is possible using the three-dimensional Stokeslet and rotlet point singularities. Two problems are studied in detail. In the first example, exact solutions for the three-dimensional Stokeslet and rotlet placed axisymmetrically along the axis of a circular disc are found and combined with Brenner's first order interaction formulae to determine the effect of the presence of the disc on the force and torque acting on a particle whose dimensions are small compared with its distance from the disc. The results are compared with those of a full numerical integration of the Stokes equations for a sphere translating towards a disc. In the second example, Brenner's first order wall correction theory is applied to the motion of a particle in a circular cylinder using the exact solutions for a torus translating or rotating in isolation. The theoretical predictions for the drag on a torus settling symmetrically in a circular cylinder are compared with those determined experimentally.     

蝶阀加工及装配工艺的研究

传统工艺加工阀体、活门时，对机床的性能要求较高，一般为数控镗床。介绍了一种采用普通镗床加工阀体、活门的工艺方法及蝶阀在厂内装配的工艺方法。     

网格曲面中孔洞的光滑填充算法研究

三角网格模型是几何描述的一种重要形式，有着广泛的应用。但三角网络模型常常会存在孔洞缺陷。这些孔洞的存在一方面影响视觉效果，另一方面会影响许多后续的操作，如快速原型制造、有限元分析等，因此有必要对这些孔洞进行修补。目前绝大多数孔洞填充算法是将网格模型中的孔洞提取成空间多边形，并对孔洞多边形进行三角化。这种处理方法的主要缺陷是没有考虑网格曲面在孔洞附近的几何形态，因而填充部分不能与整个曲面光滑地融为一体。笔者提出了一种三角网格曲面中孔洞的光滑填充算法。该算法根据孔洞周围网格曲面的几何信息来增加孔洞内部的采样点，然后再对增加的采样点进行三角化，较好地解决了填充部分与整体曲面光滑连接的问题。     

化学复合镀Ni-P-TiO_2光催化降解次甲基蓝

以钛酸丁酯为原料通过溶胶 凝胶法制备出粒径 30nm左右的纳米TiO2 ,利用化学复合镀在钢铁基底上形成Ni P 纳米TiO2 复合镀层 ,该复合镀层对次甲基蓝有较好的光催化降解作用 ,其催化性能与粉末状纳米TiO2 的催化性能大致相当。     

内管注水泥固井工具的研究与分析

内管注水泥技术是针对大尺寸套管和表层套管固井的特点及特殊要求而采用的一种固井技术，具有省时、替量少等特点，在现场得到大量推广应用。内管注水泥器是内管固井技术的关键工具，其性能好坏直接影响到固井质量。对各种内管注水泥固井工具的结构及特点分别进行了分析研究，并就其发展方向提出建议。     

改进的第三代相干算法及应用

在讨论相干技术发展及三代相干算法优缺点的基础上，介绍了改进的第三代相干算法。应用自行开发的相干软件对多个油气勘探和开发区块的三维地震资料进行处理、分析，对相干时窗长度、相关道数等参数对算法效果的影响及相干体对断层、异常地质体的识别，以及解释方法进行了探讨。应用实例证明，改进的第三代相干算法抗干扰能力强，横向分辨率高，不仅适用于倾斜地层，而且对断层尤其对小断层、异常地质体具有较高的检测能力，是油气勘探和开发的一项有效和实用的技术。