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排序方式: 共有4538条查询结果,搜索用时 31 毫秒
81.
Mariana G. Figueiro Brittany Wood Barbara Plitnick Mark S. Rea 《Journal of the Society for Information Display》2013,21(10):417-421
Self‐luminous electronic devices emit optical radiation at short wavelengths, close to the peak sensitivity of melatonin suppression. The present paper investigated if light from a 178‐cm (70 in.) television suppressed melatonin. Results showed that light from televisions does not impact melatonin levels in the evening. 相似文献
82.
83.
Masoud Alahbakhshi Aditya Mishra Grigorii Verkhogliadov Emigdio E. Turner Ross Haroldson Austen C. Adams Qing Gu Jeffrey J. Rack Jason D. Slinker Anvar A. Zakhidov 《Advanced functional materials》2023,33(28):2214315
Perovskite light-emitting diodes (PeLEDs) are advancing because of their superior external quantum efficiencies (EQEs) and color purity. Still, additional work is needed for blue PeLEDs to achieve the same benchmarks as the other visible colors. This study demonstrates an extremely efficient blue PeLED with a 488 nm peak emission, a maximum luminance of 8600 cd m−2, and a maximum EQE of 12.2% by incorporating the double-sided ethane-1,2-diammonium bromide (EDBr2) ligand salt along with the long-chain ligand methylphenylammonium chloride (MeCl). The EDBr2 successfully improves the interaction between 2D perovskite layers by reducing the weak van der Waals interaction and creating a Dion–Jacobson (DJ) structure. Whereas the pristine sample (without EDBr2) is inhibited by small stacking number (n) 2D phases with nonradiative recombination regions that diminish the PeLED performance, adding EDBr2 successfully enables better energy transfer from small n phases to larger n phases. As evidenced by photoluminescence (PL), scanning electron microscopy (SEM), and atomic force microscopy (AFM) characterization, EDBr2 improves the morphology by reduction of pinholes and passivation of defects, subsequently improving the efficiencies and operational lifetimes of quasi-2D blue PeLEDs. 相似文献
84.
Xiaoyu Dong Zhiwei Li Derong Luo Kangsheng Huang Hui Dou Xiaogang Zhang 《Advanced functional materials》2023,33(11):2210473
Proton batteries have been considered as an innovative energy storage technology owing to their high safety and cost-effectiveness. However, the development of fast-charging proton batteries with high energy/power density is greatly limited by feasible material selection. Here, the pre-protonated vanadium hexacyanoferrate (H-VHCF) is developed as a proton cathode material to alleviate the capacity loss of proton-free electrode materials during electrochemical tests. The pre-protonation process realizes fast and long-distance transport of protons by shortening diffusion path and reducing migration barriers. Benefitting from the enhanced hydrogen bonding network combined with dual redox reactions of V and Fe in protonated H-VHCF cathode, a high energy density of 74 Wh kg−1 at 1.1 kW kg−1, and a maximum power density of 54 kW kg−1 at 65 Wh kg−1 is achieved for the asymmetric proton batteries coupling with MoO3/MXene anode. Proton transport and double oxidation-reduction center are verified by theoretical calculations and ex situ experimental measurements. Considering the anti-freezing availability of proton batteries, 82.5% of its initial capacity is maintained after 10000 cycles under −40 °C at 0.5 A g−1. As a proof-of-concept, flexible device fabricated by optimized electrodes and hydrogel electrolytes can power up a light-emitting diode even under a bent state. 相似文献
85.
Xingwen Tong Zhennan Zhao Lei Hua Yuzhuo Zhang Bowei Xu Yuchao Liu Shouke Yan Zhongjie Ren 《Advanced functional materials》2023,33(43):2305324
Blue conjugated polymers-based OLEDs with both high efficiency and low efficiency roll-off are under big challenge. Herein, a strategy of local conjugation is proposed to construct high-efficiency blue-emitting conjugated polymers, in which the conjugation degree of polymeric backbones is adjusted by inserting different spacers. In this way, the energy level of triplet state and the energy transfer direction of the polymeric main-chains can be effectively regulated. Benefiting from such fine regulation, the prepared alternative copolymers Alt-PB36 with local conjugated main-chains can better suppress the accumulation of long-lived triplet excitons comparing with the complete conjugated polymers. The higher PLQY of Alt-PB36 also verifies the effective energy transfer from the polymeric main-chains to the TADF units. Accordingly, Alt-PB36 based solution-processed OLEDs achieve an EQEmax of 11.6% and a very low efficiency roll-off of 2.8% at 100 cd m−2 and 15.2% at 500 cd m−2. This result represents the best efficiency among blue light-emitting conjugated polymer-based OLEDs so far under high luminance. 相似文献
86.
Crystallization‐Induced Emission Enhancement of a Deep‐Blue Luminescence Material with Tunable Mechano‐ and Thermochromism
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Zhen Wu Shenzhong Mo Lina Tan Bing Fang Zhiqiang Su Yantu Zhang Meizhen Yin 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(40)
Organic luminescent materials with the ability to reversibly switch the luminescence when subjected to external stimuli have attracted considerable interest in recent years. However, the examples of luminescent materials that exhibit multiresponsive properties are rarely reported. In this work, a new stimuli‐responsive dye P1 is designed and synthesized with two identical chromophores of naphthalimide, one at each side of an amidoamine‐based spacer. This amide‐rich molecule offers many possibilities for forming intra‐ and intermolecular hydrogen bond interactions. Particularly, P1 has an intrinsic property of cocrystallizing with methanol. Compared with the pristine P1 sample, the as‐prepared two‐component cocrystalline material displays an exceptive deep‐blue emission, which is extremely rare among naphthalimide‐based molecules in the solid state. Furthermore, the target material exhibits an obvious mechanochromic fluorescent behavior and a large spectral shift under force stimuli. On the other hand, the cocrystalline material shows an unusual “turn off” thermochromic luminescence accompanied by solvent evaporation. Moreover, using external stimuli to reversibly manipulate fluorescent quantum yields is rarely reported to date. The results demonstrate the feasibility of a new design strategy for solid‐state luminescence switching materials: the incorporation of solvents into organic compounds by cocrystallization to obtain a crystalline state luminescence system. 相似文献
87.
目的 探究不同处理对贮藏0~60 d期间蓝靛果实贮藏品质及活性氧(ROS)代谢的影响,为蓝靛果贮藏保鲜提供技术依据。方法 以蓝靛果为实验材料,采后将其装入保鲜箱中,用1−甲基环丙烯(1-MCP)、乙烯吸收剂(EA)、1-MCP+EA进行处理,在(−0.5±0.3)℃下贮藏60 d,每隔15 d取样观察果实的感官品质,并测定其营养、生理及活性氧代谢相关指标。结果 与对照组相比,3种处理方式均能保持果实较好的感官特性,延缓果实抗坏血酸、花色苷、总酚和黄酮等含量的流失,以及果实的软化;在贮藏60 d时,处理组果实的呼吸强度分别比对照组果实的呼吸强度低22.73、12.92、34.04 mg/(kg.h),乙烯生成速率分别比对照组果实的低6.38、3.98、10.11 μL/(kg.h);可抑制超氧阴离子(O2−.)活性、过氧化氢(H2O2)含量、丙二醛含量及相对电导率的升高,保持较高的超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、过氧化物酶(POD)、抗坏血酸过氧化物酶(APX)活性。通过SPSS分析可知,综合得分顺序为CK<EA<1-MCP<1-MCP+EA,表明1-MCP+EA处理的效果最好。结论 1-MCP+EA处理对蓝靛果贮藏60 d的保鲜效果最好,可更好地保留果实的外观和内在品质,利于运输和销售。 相似文献
88.
为研究纳米CdS/ZnS@rGA复合材料在可见光下的光催化性能,采用一步溶剂热法合成了以ZnS为壳的CdS/ZnS核壳纳米粒子,将CdS/ZnS核壳纳米粒子附着在rGO纳米片上,并组装成CdS/ZnS@rGA复合气凝胶,用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)等对样品进行了表征,通过亚甲基蓝(MB)的光催化降解实验表明:CdS/ZnS@rGA复合气凝胶的形成不仅可以提高CdS的光稳定性,还可以增强对MB吸附能力,同时对MB的降解有明显的促进作用。可见光反应90 min, 50 mg的CdS/ZnS@rGA对100 mL 20 mg/L MB的去除率最高达到99%。经过5次循环实验,该材料仍具有较好的可重复利用性。 相似文献
89.
Musun Kwak Jungwoo Park Jongho Jeon Kyoungri Kim Yoonseon Yi Donsik Choi Youngseok Choi Kyongdeuk Jeong 《Journal of the Society for Information Display》2011,19(9):576-582
Abstract— To understand the mechanism of the disclination defect of the liquid‐crystal (LC) phase, this study was conducted to directly analyze the polymer‐network (PN) structure of polymer‐stabilized blue phase (PSBP), which is minutely formed on all LC layers. The PN was examined after first removing the glass decap and then the LC. Important to note is that the removal of the glass decap did not affect or damage the PN structure. The PN was determined to be a stable structure without any change to the thickness of the layer. When removing the LC, both hexane and acetone solutions were used. Moreover, there was no structural deformation to the PN when using the hexane solution. The results of the study show that the actual size of the polymer chain is in fact 50–60 nm, five times larger than previous theories which estimated the size to be only 10 nm. In addition, this study confirmed that the pores between the PN are 100–200 nm. The PN structure was shown to be susceptible to change based on different heating temperatures. In summation, now that defect lines of a LC display (LCD) could be directly measured, further progress and development in the theoretical interpretations of the Kerr effect on PSBP can be realized. 相似文献
90.
This paper presents a multivariable nonlinear model predictive control (NMPC) scheme for the regulation of a low-density polyethylene (LDPE) autoclave reactor. A detailed mechanistic process model developed previously was used to describe the dynamics of the LDPE reactor and the properties of the polymer product. Closed-loop simulations are used to demonstrate the disturbance rejection and tracking performance of the NMPC algorithm for control of reactor temperature and weight-averaged molecular weight (WAMW). In addition, the effect of parametric uncertainty in the kinetic rate constants of the LDPE reactor model on closed-loop performance is discussed. The unscented Kalman filtering (UKF) algorithm is employed to estimate plant states and disturbances. All control simulations were performed under conditions of noisy process measurements and structural plant–model mismatch. Where appropriate, the performance of the NMPC algorithm is contrasted with that of linear model predictive control (LMPC). It is shown that for this application the closed-loop performance of the UKF based NMPC scheme is very good and is superior to that of the linear predictive controller. 相似文献