SAC105焊锡膏的开发与评价

采用低银化焊料合金是无铅化电子组装提高性价比的发展趋势。开发了采用SAC105低银焊料合金的SUPER105系列焊锡膏,抗氧化、表面绝缘电阻、印刷性能、BGA空洞率、焊点推力等测试结果表明,SUPER105焊锡膏完全适用于消费类电子产品组装。     

无铅石墨导电浆料的制备和性能

以导电石墨粉、低熔无铅玻璃和乙基纤维素松油醇溶液制备了无铅石墨导电浆料。分析了浆料中玻璃粉含量对烧结膜表面电阻、威氏硬度和附着力的影响,给出了石墨导电浆料的配方。研究了浆料的流变性、触变性和粘弹性。用玻璃转变温度为476℃的无铅低熔玻璃配制的浆料在520~580℃烧结后,外观致密光洁;当烧结膜厚度为(25±3)μm时,方阻为80~135?/□,硬度为12.3 N/mm2,附着力为45.6 N。     

无机添加剂对多层陶瓷电容器钯银内电极浆料的影响

为了满足多层陶瓷电容器陶瓷介质与钯银内电极浆料烧结一致性要求,研究了无机添加剂纳米BaTiO3和纳米ZrO2对钯银内电极浆料的烧结过程产生的影响。结果表明所用添加剂使MLCC烧结过程中钯银内电极浆料的收缩与陶瓷介质的收缩保持一致。     

镍电极MLCC内电极浆料与介质烧成收缩匹配性的研究

文章通过实验,阐述了电容器用镍内电极浆料中,有机固含量的大小、无机添加剂的类型、镍/无机添加剂比例对镍内电极浆料烧成收缩曲线,以获镰浆所形成电极层与介质层在烧成过程中收缩率匹配性能的影响。     

QFN焊盘设计及工艺组装

随着电子产品向更轻、更薄、更小、高密度化和高可靠性的发展,QFN（方形扁平无引脚）封装由于具有良好的电和热性能、体积小、质量轻,在电子产品中被越来越广泛的推广和应用。文章对QFN器件的焊盘设计,网板设计及组装工艺作了详细的介绍。     

304不锈钢基片用绝缘介质浆料的研制

选用BaO-Al2O3-SiO2体系微晶玻璃为主要成分,研制出适用于304不锈钢基片的介质浆料。通过丝网印刷、烘干和烧结,能够为304不锈钢基片提供可靠的介质层。介质层厚度达到70 mm以上时,其击穿电压不低于2 100 V,完全满足大功率厚膜电路对基片绝缘性能的要求。     

键盘式薄膜开关的制造工艺研究

讨论了制造薄膜开关的材料性能与网印工艺条件,通过金相显微镜观察并分析了印刷层的厚度与均匀性关系,研究了薄膜开关导电银浆线路的电阻性能。选择恰当的印刷工艺参数,如括板压力0.3～0.4MPa、移动速度0.2～0.3m/s等,制造出厚度均匀、与电阻匹配的薄膜开关,其导电银浆各处线路的参数均匀,方阻为28.01mμ/□,厚度为4.33μm,锯齿边缘的平均深度约为23.53μm,且外观无明显色差,实现了薄膜开关的低成本与高可靠快速制造。     

Sn42Bi57Ag1无铅焊膏用活性剂的优化设计

针对Sn42Bi57Ag1无铅焊料开发出一种低温无铅焊锡膏,着重研究助焊剂中活性剂对焊锡膏润湿性能的影响。以铺展性能作为主要评价指标,通过回流焊接实验,对用于助焊剂的7种有机酸进行了筛选。最终选取了性能较好的甲基丁二酸、己二酸、水杨酸与丁二酸四种有机酸进行正交试验,通过量化分析选取正交试验水平,根据方差分析确定助焊剂中活性剂的最佳组合。结果表明:有机酸的复配能显著改善焊点铺展情况,当甲基丁二酸、己二酸、水杨酸与丁二酸质量比为2∶3∶5∶2时,Sn42Bi57Ag1无铅焊膏的润湿性能优异,焊点铺展率达86.52%。     

Encapsulation of lead-free Sn/Zn/Bi solder alloy particles by coating with wax powder for improving oxidation resistance

An encapsulation treatment of lead-free Sn/Zn/Bi solder powder was investigated for improving the oxidation resistance. Sn-8mass%Zn-3mass%Bi alloy particles were coated with a wax (12-hydroxystearic acid) powder by means of a dry mechanical treatment method using a ball mill. In order to determine the optimum operating conditions of the ball mill in the wax-coating treatments, the compressive energy required for deforming a single Sn/Zn/Bi alloy particle was measured with an unconfined compression tester and the mechanical energy applied to the alloy particles in the ball mill was estimated using the results of the compression test. The optimum operating conditions were determined based on both the applied energy and the flowability of solder pastes, and the wax-coated alloy particles maintaining the spherical shape were obtained under the conditions. The wettability test and the solder balling test for the solder pastes containing the wax-coated alloy particles stored at room temperature in air were carried out to evaluate the oxidation resistance performance. The wax-coated alloy particles had an excellent wettability compared with the original alloy particles, and the oxidation resistance of the Sn/Zn/Bi solder powder was improved by the encapsulation treatment.     

玻璃基板用电子浆料

钠钙视窗玻璃电气性能与氧化铝陶瓷相当 ,成本低 ,是厚膜基片廉价材料。用 Ru2 Pb2 O6 和 Ru2 Bi2 O7作导电相 ,硼硅酸铅系添加碳酸钠作玻璃料配制的钌系电阻浆料 ,与钠钙玻璃有较好的匹配性。烧成条件 6 0 0℃ ,45 min,峰值温度保温 9min。方阻为 2 0 Ω～ 1MΩ,稳定性良好 ,阻值变化 ΔRS/ RS<1%。