Micro‐Nanostructured Interfaces Fabricated by the Use of Inorganic Block Copolymer Micellar Monolayers as Negative Resist for Electron‐Beam Lithography

This paper introduces an approach where the match of two different length scales, i.e., pattern from self‐assembly of block copolymer micelles (< 100 nm) and electron‐beam (e‐beam) writing (> 50 nm), allow the grouping of nanometer‐sized gold clusters in very small numbers in even aperiodic pattern and separation of these groups at length scales that are not accessible by pure self‐assembly. Thus, we could demonstrate the grouping of Au nanoclusters in different geometries such as squares, rings, or spheres.     

Melanin films on Au(1 1 1): Adsorption and molecular conductance

We have studied the adsorption and electronic properties of thin melanin films on Au(1 1 1) by scanning tunneling microscopy (STM), scanning tunneling spectroscopy (STS), and density functional (DF) calculations. We have found that the minimum melanin unit detected under different adsorption conditions is consistent with the structural model for eumelanin protomolecules based on tetramer macrocycles formed by four monomer units (hydroquinone, indolequinone and its tautomers) with an inner porphyrin ring. DF calculations reveal that the entire π structure of the tetramers is implied in the chemisorption process through its frontier orbitals (HOMO and LUMO), a fact that is reflected in the change of intramolecular bonds. Also van der Waals interactions give an important contribution to the adsorption energy (≈0.02 eV/Ų). Dried thin melanin films (1 monolayer in thickness) exhibit good electronic conductance due to the presence of localized states near the Fermi level while dried thicker films exhibit a semiconductor-like behavior. Illumination of the thicker films with white light results in significant photo-induced tunneling currents when the melanin-covered Au is made negative with respect to the tip.     

电镀镍金工艺渗金原因分析及改善

通过对采用贴干膜板进行电镀镍金工艺渗金造成批量报废的原因进行分析,采取多种试验方案寻找问题根源,使问题得到彻底解决。     

Inside Front Cover: Three‐Dimensionally Ordered Gold Nanocrystal/Silica Superlattice Thin Films Synthesized via Sol–Gel Self‐Assembly (Adv. Funct. Mater. 7/2006)

The synthesis of three‐dimensionally ordered, transparent gold‐nanocrystal (NC)/silica superlattice thin films using the self‐assembly (by spin‐coating) of water‐soluble gold nanocrystal micelles and soluble silica is reported by Fan and co‐workers on p. 891. The robust, 3D NC/silica superlattice films are of interest for the development of collective optical and electronic phenomena, and, importantly, for the integration of NC arrays into device architectures. Nanocrystals and their ordered arrays hold many important applications in fields such as catalysis, surface‐enhanced Raman spectroscopy based sensors, memory storage, and electronic and optical nanodevices. Herein, a simple and general method to synthesize ordered, three‐dimensional, transparent gold nanocrystal/silica superlattice thin films by self‐assembly of gold nanocrystal micelles with silica or organosilsesquioxane by spin‐coating is reported. The self‐assembly process is conducted under acidic sol–gel conditions (ca. pH 2), ensuring spin‐solution homogeneity and stability and facilitating the formation of ordered and transparent gold nanocrystal/silica films. The monodisperse nanocrystals are organized within inorganic host matrices as a face‐centered cubic mesostructure, and characterized by transmission electron spectroscopy and X‐ray diffraction.     

一种基于图像DC系数的多比特水印

提出了一种新的多比特水印算法。该算法把基于图像自身的水印信息嵌入到图像的DC系数中,通过视觉模型控制DC系数的改变程度,在保证水印不可见性的同时,提高了水印的鲁棒性。为实现水印的盲检测,采用Gold码序列对水印信息进行了扩频。在检测阶段,充分利用Gold序列良好的相关性恢复出水印。应用所提出算法,把水印信息嵌入到一幅512×512的灰度图像中。实验表明,该算法对常规信号处理攻击和几何攻击具有很强的鲁棒性。     

降低电镀镍/金印制板的不良率

随着电子工业的快速发展,高密度集成电路和BGA封装器件也广泛用于军用电子产品,新的器件和焊接工艺对印制电路板的表面可焊涂覆层提出了新的要求,其不但要求涂覆层有良好的可焊性,而且要求涂覆层平整,印制板电镀镍/金涂层不但表面平整,可焊性好而且具有较好的三防性能和较长的存放期,因此,电镀镍/金印制板正逐渐被应用于高密度的军用电子产品,本文就印制板电镀镍/金过程中出现的问题进行探讨和交流。     

ICP-AES法测定铅锌混合矿中的铁、铜、砷、锌、镉、汞

采用ICP-AES同时测定铅锌混合矿中铁、铜、砷、锌、镉、汞六种元素的含量,优化了实验条件,各元素的检出限为0.0069-0.07ug/mL,相对标准偏差为0.3%-4.72%,样品加标回收率为85.5%-112.8%。测试结果表明,该法测定铅锌矿的简单、准确、快速。     

Assembly of Nanoparticle Patterns with Single‐Particle Resolution Using DNA‐Mediated Charge Trapping Technique: Method and Applications

We report a unique approach for producing one‐dimensional gold‐nanoparticle patterns with single‐particle resolution in which the linewidth is only limited by the particle size. In this approach, a focused electron beam was first utilized to generate a positive charge layer on a SiO₂ surface. Biotinated DNA molecules attracted by these positive charges were subsequently used to grasp Au‐nanoparticles revealing the e‐beam exposure patterns. Due to repulsive force between Au colloidal particles, the particles in the single‐line patterns were orderly separated. We further show that the single‐line patterns hold potential in nano‐photonics and nano‐electronics. For the latter, we demonstrate that the line patterns can serve as a template for conductive nanowires of high or low resistance. While low resistance wires showed linear current–voltage characteristics with an extremely high maximum allowed current density, the high resistance wires exhibited charging effect with clear Coulomb oscillation behavior at low temperatures. This demonstrates that the technique is capable of producing interconnects as well as single‐electron‐transistors, and opens up possibilities for fabrication of integrated circuits.     

Gold序列互相关性的新证明及非最大Gold序列性质研究

Gold序列是通信中常用的伪随机序列。提供了一种Gold序列自相关性和互相关性的新的证明,不同于Kasami早先的用循环码理论的证明,本证明直接从Gold序列的定义出发,应用了有限域上迹函数性质和指数和的理论,比原证明更直观、简洁,并且直接推广到了非互素采样的情形---非最大Gold序列。随后讨论了非最大Gold序列的自相关性和互相关性,发现这时的相关函数取值为五值的,具有一定的应用价值。     

化学镍金生产中的问题探讨简

文章主要探讨了化学镍金生产中所遇到的问题,如渗镀、漏镀、金面粗糙问题,结合我公司实际情况,进行的解决和改善的过程,为化学镍金生产积累了宝贵的经验,提高了我公司化学镍金的生产水平。