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81.
82.
灰色关联分析在腐蚀非晶态镍基合金中的应用 总被引:4,自引:3,他引:1
用灰色关联分析方法取代传统的数理统计方法,对非晶态镍基合金在FeCl_3溶液中的腐蚀速率与影响因素之间的相互关系进行处理,确定各影响因子之间的主次关系。结果表明溶液流速是最关键因子,次关键因子为溶液pH值,其次为溶液温度和溶液浓度,并根据分析结果提出实际应用时的相应对策。 相似文献
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84.
用电化学方法测定砂浆试件中钢筋的极化电阻,并测定了砂浆的孔隙率,结果发现:砂浆的孔隙率、孔径分布与钢筋极化电阻大小有良好的对应关系。电化学方法能可靠、快速测定砂浆配合比、添加剂对钢筋腐蚀速度的影响。 相似文献
85.
低压铝箔交流腐蚀研究 总被引:4,自引:2,他引:2
在30Hz频率下,通过铝箔在HCl+H2SO4+HNO3+H3PO4体系中的交流腐蚀,研究腐蚀液组成中腐蚀主体及缓蚀剂对铝箔腐蚀的作用,探讨腐蚀过程中电源频率、腐蚀液温度、电流密度及腐蚀时间对铝箔腐蚀的影响。腐蚀液组成的配比恰当,有利于比容的提高。在特定的频率下采用合适的腐蚀液温度、适宜的电流密度和腐蚀时间可以提高铝箔的静电容量。 相似文献
86.
几种高强度钢腐蚀疲劳裂纹扩展行为的研究 总被引:2,自引:0,他引:2
本文研究了GC-4,30CrMnSiNi2A和300M超高强钢的腐蚀疲劳裂纹扩展行为。考虑了环境,热处理制度,应力比和频率对裂纹扩展的影响。研究结果表明:腐蚀环境和热处理制度对疲劳裂纹扩展有显著影响。在侵蚀性环境中随频率降低,裂纹扩展大幅度上升,随应力比提高,环境影响加剧。利用扫描电镜对试样断口形貌进行了分析,并讨论了高强钢的腐蚀疲劳机理。 相似文献
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88.
In industrial systems, the formation of biofilms can cause many problems, such as an increase in the flow resistance of pipelines, energy losses in fluid transport and heat exchangers, product contamination, materials deterioration, and biocorrosion. As a result, biofilms contribute substantially to economic losses in the industry. Corrosion is particularly an issue in the petroleum industry and its implications range from down-hole completion through petroleum processing units. Much of this corrosion is attributed to microbial activities. This paper proposes a mathematical model for predicting substrate concentration for such microbial growth. Substrate concentrations in the system and near the biofilm surface are one of the parameters that has a great effect in determining the extent of the problems associated with biofilms. In this study, a convective-diffusion model under various flow conditions (stagnant, laminar, and turbulent) has been solved using the finite difference technique, employing the alternating direction implicit (ADI) method. The model assumes that a liquid containing substrate and bacteria is flowing in a pipeline with known concentrations at the inlet and then predicts the variation of the transient (as a function of time) substrate concentration along the pipeline and as a function of the pipe radius. The model is then used to predict and estimate the substrate concentration profiles on the biofilm surface under different environmental conditions. A parametric study was also conducted to study the effect of the different parameters influencing the substrate concentration profiles in the system and on the biofilm surface. 相似文献
89.
Xueyuan ZhangWenle He Inger Odnevall Wallinder Jinshan PanChristofer Leygraf 《Corrosion Science》2002,44(9):2131-2151
Instantaneous corrosion rates of naturally patinated copper of varying age (16 months, 138 and 145 years) have been determined during continuous rain events in the laboratory with electrochemical impedance spectroscopy using a two-electrode cell. The two-electrode cell was found to yield the same information in bulk rainwater as a conventional three-electrode cell.Relatively constant corrosion rates, between 0.2 and 0.6 μm/y, were determined for samples having a two-layer structure with an inner brownish layer of cuprous oxide and an outer greenish layer of basic copper salts (138, 145 years). Samples with cuprous oxide as the dominating phase of the patina (16 months) showed higher and somewhat increasing corrosion rates during a rain event (from 0.6 to 1.2 μm/y). During a continuous rain event, corrosion rates were found to be approximately 10 (brownish patina) and 25 times (greenish patina) lower than corresponding instantaneous runoff rates. The first flush phenomena of the runoff process, with an increased concentration during first flush and a relatively constant concentration during steady state, was indirectly seen as an increase in solution conductivity during the first rain volume followed by relative constant value. The contribution of the concentration in the first flush to the total annual runoff rate was significant for panels having a greenish layer (138, 145 years) whereas it was negligible for panels having a brownish layer (16 months). 相似文献
90.
In this work, the filiform corrosion behaviour of powder painted aluminium profiles was studied, and the coating barrier properties together with adhesion to the substrate were analysed. Samples coated with a traditional painting procedure (one powder layer application followed by curing), and other samples coated using a special cycle to obtain wood grain effect were compared using accelerated filiform corrosion tests. Moreover, in order to better understand the degradation mechanisms of painted metal substrates, thermal stresses were applied to accelerate the natural weathering. The effects of the thermal aging were analysed by electrochemical impedance spectroscopy. 相似文献